The present invention relates to a method for preparing a porous polyimide film, comprising reacting an aromatic dianhydride with one or more aromatic diamines in a suitable solvent to form poly(amic acid), adding a dehydrated agent of an acid anhydride and an organic base to the reaction mixture to convert the poly(amic acid) to a polyimide precursor, casting the reaction mixture comprising the polyimide precursor onto a solid support to form a film, coagulating the polyimide precursor in a coagulating bath comprising a mixture of a solvent and a non-solvent to develop a porous structure, and drying the coagulated polyimide precursor in air to form the porous polyimide film. A composite membrane comprising same and its use are also provided.

The present invention relates to a method for preparing a porous polyimide film, comprising reacting an aromatic dianhydride with one or more aromatic diamines in a suitable solvent to form poly(amic acid), adding a dehydrated agent of an acid anhydride and an organic base to the reaction mixture to convert the poly(amic acid) to a polyimide precursor, casting the reaction mixture comprising the polyimide precursor onto a solid support to form a film, coagulating the polyimide precursor in a coagulating bath comprising a mixture of a solvent and a non-solvent to develop a porous structure, and drying the coagulated polyimide precursor in air to form the porous polyimide film. A composite membrane comprising same and its use are also provided.

A substrate for a composite membrane includes a microporous polyolefin membrane for carrying a hydrophilic resin compound within the pores of the microporous membrane wherein: the average pore diameter is 1 nm to 50 nm; the porosity is 50% to 78%; the membrane thickness is 1 μm to 12 μm; and, when a mixed solution of ethanol and water (volume ratio ½) is dripped onto a surface of the microporous polyolefin membrane which has not undergone hydrophilization treatment, the contact angle θ1 between the droplet and the surface is 0 to 90 degrees 1 second after the dripping, and the contact angle θ2 between the droplet and the surface is 0 to 70 degrees 10 minutes after the dripping, and the rate of change of the contact angle ((θ1−θ2)/θ1×100) is 10 to 50%.

A substrate for a composite membrane includes a microporous polyolefin membrane for carrying a hydrophilic resin compound within the pores of the microporous membrane wherein: the average pore diameter is 1 nm to 50 nm; the porosity is 50% to 78%; the membrane thickness is 1 μm to 12 μm; and, when a mixed solution of ethanol and water (volume ratio ½) is dripped onto a surface of the microporous polyolefin membrane which has not undergone hydrophilization treatment, the contact angle θ1 between the droplet and the surface is 0 to 90 degrees 1 second after the dripping, and the contact angle θ2 between the droplet and the surface is 0 to 70 degrees 10 minutes after the dripping, and the rate of change of the contact angle ((θ1−θ2)/θ1×100) is 10 to 50%.

The present invention relates to a method for producing a polymer composite material, particularly an electrode (10) and/or a separator, for an electrochemical cell, particularly for a battery cell and/or fuel cell and/or electrolysis cell. In order to improve the production of polymer composite materials, in the form of electrodes and/or separators, for example, particularly for electrochemical cells, and the properties and/or functionality thereof, such as the specific energy density and/or electrical conductivity thereof, at least one swellable polymer (1) is mixed with a solvent quantity of at least one solvent (2), which can be absorbed completely in the at least one swellable polymer (1) by swelling the at least one swellable polymer (1) and which swells the at least one swellable polymer (1), and with at least one particulate material (3, 4). A polymer composite material, particularly an electrode (10) and/or a separator, for an electrochemical cell, particularly for a battery cell and/or fuel cell and/or electrolysis cell, is then formed from the mixture (1, 2, 3, 4).

The present invention relates to a method for producing a polymer composite material, particularly an electrode (10) and/or a separator, for an electrochemical cell, particularly for a battery cell and/or fuel cell and/or electrolysis cell. In order to improve the production of polymer composite materials, in the form of electrodes and/or separators, for example, particularly for electrochemical cells, and the properties and/or functionality thereof, such as the specific energy density and/or electrical conductivity thereof, at least one swellable polymer (1) is mixed with a solvent quantity of at least one solvent (2), which can be absorbed completely in the at least one swellable polymer (1) by swelling the at least one swellable polymer (1) and which swells the at least one swellable polymer (1), and with at least one particulate material (3, 4). A polymer composite material, particularly an electrode (10) and/or a separator, for an electrochemical cell, particularly for a battery cell and/or fuel cell and/or electrolysis cell, is then formed from the mixture (1, 2, 3, 4).

Disclosed is a fuel cell membrane electrode assembly (MEA) embodiment including an anode layer; at least one exchange membrane that is disposed on the anode layer as either a single-layered structure including one exchange membrane or a multi-layered structure including a plurality of exchange membranes, each exchange membrane of the at least one exchange membrane consisting of a film comprising hexagonal boron, and the at least one exchange membrane having a total thickness ranging from 0.3 to 3 nm; an interfacial binding layer that completely covers an exposed surface of one exchange membrane which is obverse to the anode layer and that consists of poly(methylmethacrylate) (PMMA) as a binder material; and a cathode layer formed on the interfacial binding layer. Alternately, a fuel cell membrane electrode embodiment may completely eliminate the interfacial binding layer and both embodiments provide superior fuel cell performance.

Disclosed is a fuel cell membrane electrode assembly (MEA) embodiment including an anode layer; at least one exchange membrane that is disposed on the anode layer as either a single-layered structure including one exchange membrane or a multi-layered structure including a plurality of exchange membranes, each exchange membrane of the at least one exchange membrane consisting of a film comprising hexagonal boron, and the at least one exchange membrane having a total thickness ranging from 0.3 to 3 nm; an interfacial binding layer that completely covers an exposed surface of one exchange membrane which is obverse to the anode layer and that consists of poly(methylmethacrylate) (PMMA) as a binder material; and a cathode layer formed on the interfacial binding layer. Alternately, a fuel cell membrane electrode embodiment may completely eliminate the interfacial binding layer and both embodiments provide superior fuel cell performance.

A zinc iodine flow battery includes a positive end plate, a positive current collector, a negative current collector, a positive electrode with a flow frame, a membrane, a negative electrode with a flow frame, a negative end plate. The negative electrolyte is circulated between the negative storage tank and the negative cavity by pump. The negative pipe is provided with a branch pipe for the positive electrolyte circulation. The porous membrane between the positive and negative electrodes can realize the conduction of supporting electrolyte and prevent the diffusion of I3− to the negative electrolyte. In a duel-flow battery system, same electrolyte serves as both the positive electrolyte and the negative electrolyte, which is a mixed aqueous solution containing iodized and zinc salt. The membrane is porous membrane does not contain ion exchange group. Both the positive and negative electrolyte are neutral solutions.

Disclosed herein are real time hydrogen self-supplied alkaline membrane fuel cell that operates with hydrogen produced in situ. The hydrogen self-supplied alkaline membrane fuel cell can comprise (i) a hydrogen generation reactor that provides continuous, on-demand supply of hydrogen, wherein the hydrogen generation reactor produces hydrogen by reacting metal particles with water in the presence of an alkaline catalyst, and (ii) a membrane electrode assembly adapted to receive an oxidant and a fuel stream containing hydrogen produced in the hydrogen generation reactor. The membrane electrode assembly comprises an electrolyte membrane and at least two electrodes. The electrolyte membrane can comprise cellulose and the electrolyte can comprise a base such as aqueous potassium hydroxide. Methods for operating an alkaline membrane fuel cell are also disclosed.