A new polyelectrolyte multilayer coated proton-exchange membrane for electrolysis and fuel cell applications has been developed for electrolysis and fuel cell applications. The polyelectrolyte multilayer coated proton-exchange membrane comprises: a cation exchange membrane, and a polyelectrolyte multilayer coating on one or both surfaces of the cation exchange membrane. The polyelectrolyte multilayer coating comprises alternating layers of a polycation polymer and a polyanion polymer. The polycation polymer layer is deposited on and is in contact with the cation exchange membrane. The top layer of the polyelectrolyte multilayer coating can be either a polycation polymer layer or a polyanion polymer layer.

A composite electrolyte membrane having a composite layer that is a composite of a hydrocarbon polymer electrolyte and a fluorine-containing polymer porous substrate, wherein a fractal dimension D exhibiting the distribution of the hydrocarbon polymer electrolyte and the fluorine-containing polymer porous substrate in the composite layer is 1.7 or more. An object of the present invention is to enable a composite electrolyte membrane composed of a hydrocarbon polymer electrolyte and a fluorine-containing polymer porous substrate to achieve high proton conduction ability and high mechanical durability.

There is provided a method of wetting a low surface energy substrate with a high surface tension liquid comprising at least the steps of providing a low surface energy substrate having a surface energy in the range of from 15 to 45 mN/m, a high surface tension liquid having a surface tension in the range of from greater than 25 to 70 mN/m and a low surface tension fluid having a surface tension in the range of from 10 to 25 mN/m; contacting the low surface energy substrate with the high surface tension liquid; contacting at least one of the low surface energy substrate and the high surface tension liquid with the low surface tension fluid vapour, either before, at the same time as or after the contacting of the low surface energy substrate with the high surface tension liquid; and removing the low surface tension fluid vapour from the low surface energy substrate. The high surface tension liquid can be used as a carrier liquid for a coating material, such as an ion exchange material, to be deposited on the substrate, such as ePTFE, in a method of coating. Also disclosed is a system for such coating methods.

There is provided a method of wetting a low surface energy substrate with a high surface tension liquid comprising at least the steps of providing a low surface energy substrate having a surface energy in the range of from 15 to 45 mN/m, a high surface tension liquid having a surface tension in the range of from greater than 25 to 70 mN/m and a low surface tension fluid having a surface tension in the range of from 10 to 25 mN/m; contacting the low surface energy substrate with the high surface tension liquid; contacting at least one of the low surface energy substrate and the high surface tension liquid with the low surface tension fluid vapour, either before, at the same time as or after the contacting of the low surface energy substrate with the high surface tension liquid; and removing the low surface tension fluid vapour from the low surface energy substrate. The high surface tension liquid can be used as a carrier liquid for a coating material, such as an ion exchange material, to be deposited on the substrate, such as ePTFE, in a method of coating. Also disclosed is a system for such coating methods.

Disclosed is a method of manufacturing an electrolyte membrane for fuel cells. The method includes preparing an electrolyte layer including one or more ion conductive polymers that form a proton movement channel, and permeating a gas from a first surface of the electrolyte layer to a second surface of the electrolyte layer.

Disclosed is a method of manufacturing an electrolyte membrane for fuel cells. The method includes preparing an electrolyte layer including one or more ion conductive polymers that form a proton movement channel, and permeating a gas from a first surface of the electrolyte layer to a second surface of the electrolyte layer.

A composite membrane and moisture adjustment module using the same is disclosed. The composite membrane includes a moisture-permeable resin layer interposed between porous membranes that constitute a pair; and the mean thickness of the moisture-permeable resin layer is 5 μm or less.

A composite membrane and moisture adjustment module using the same is disclosed. The composite membrane includes a moisture-permeable resin layer interposed between porous membranes that constitute a pair; and the mean thickness of the moisture-permeable resin layer is 5 μm or less.

Embodiments of the invention include fuel cells incorporating sheets and/or powders of silica fibers and methods for producing such devices. The silica fibers may be formed via electrospinning of a sol gel produced with a silicon alkoxide reagent, such as tetraethyl ortho silicate, alcohol solvent, and an acid catalyst.

A solid polymer electrolyte membrane having a first surface and a second surface opposite the first surface, where the solid polymer electrolyte membrane has a failure force greater than about 115 grams and comprises a composite membrane consisting essentially of (a) at least one expanded PTFE membrane having a porous microstructure of polymeric fibrils, and (b) at least one ion exchange material impregnated throughout the porous microstructure of the expanded PTFE membrane so as to render an interior volume of the expanded PTFE membrane substantially occlusive; (c) at least one substantially occlusive, electronically insulating first composite layer interposed between the expanded PTFE membrane and the first surface, the first composite layer comprising a plurality of first carbon particles supporting a catalyst comprising platinum and an ion exchange material, wherein a plurality of the first carbon particles has a particle size less than about 75 nm, or less than about 50 nm, or less than about 25 nm.