Electrochemical systems for distributed energy generation, comprising protonic ceramic fuel cells (PCFCs), are provided. The systems of the present invention allow for operation at lower stack temperatures than current solid oxide fuel cell (SOFC) systems. These systems can achieve various advantages and benefits over SOFC systems, such as higher fuel utilization, improved cell voltage, and air ratio optimization.

The present specification relates to a sheet laminate for a solid oxide fuel cell, a precursor for a solid oxide fuel cell including the same, an apparatus for manufacturing a sheet laminate for a solid oxide fuel cell, and a method for manufacturing a sheet laminate for a solid oxide fuel cell.

The present specification relates to a sheet laminate for a solid oxide fuel cell, a precursor for a solid oxide fuel cell including the same, an apparatus for manufacturing a sheet laminate for a solid oxide fuel cell, and a method for manufacturing a sheet laminate for a solid oxide fuel cell.

In various embodiments, a solid oxide fuel cell features a functional layer for reducing interfacial resistance between the cathode and the solid electrolyte.

In various embodiments, a solid oxide fuel cell features a functional layer for reducing interfacial resistance between the cathode and the solid electrolyte.

The present invention relates to a proton ceramic fuel cell which has a hydrogen-permeable film as an anode and in which an electrolyte material is BaZr.sub.xCe.sub.1-x-zY.sub.zO.sub.3 (x=0.1 to 0.8, z=0.1 to 0.25, x+z≤1.0) (BZCY). An electron-conducting oxide thin film having a film thickness of 1-100 nm is present between a cathode and an electrolyte comprising the material. The present invention also relates to a method for producing a proton ceramic fuel cell having a hydrogen-permeable film as an anode. The method comprises forming a thin film having a thickness of 1-100 nm between a cathode and an electrolyte comprising BZCY, the thin film comprising an electron-conducting oxide. The present invention provides a novel means for improving the output of a PCFC in which BZCY is used in an electrolyte material, and provides a PCFC having an output that exceeds a benchmark of 0.5 W cm.sup.−2 at 500° C.

The present invention relates to a proton ceramic fuel cell which has a hydrogen-permeable film as an anode and in which an electrolyte material is BaZr.sub.xCe.sub.1-x-zY.sub.zO.sub.3 (x=0.1 to 0.8, z=0.1 to 0.25, x+z≤1.0) (BZCY). An electron-conducting oxide thin film having a film thickness of 1-100 nm is present between a cathode and an electrolyte comprising the material. The present invention also relates to a method for producing a proton ceramic fuel cell having a hydrogen-permeable film as an anode. The method comprises forming a thin film having a thickness of 1-100 nm between a cathode and an electrolyte comprising BZCY, the thin film comprising an electron-conducting oxide. The present invention provides a novel means for improving the output of a PCFC in which BZCY is used in an electrolyte material, and provides a PCFC having an output that exceeds a benchmark of 0.5 W cm.sup.−2 at 500° C.

A solid oxide fuel cell including a hydrocarbon reforming catalyst and a method for forming the solid oxide fuel cell are provided. An exemplary solid oxide fuel cell includes a cell. The cell includes a filled metal substrate including holes substantially filled with a permeable material that includes a hydrocarbon reforming catalyst, wherein the filled metal substrate has a front facing a fuel flow and a back facing an electrochemical stack. A permeable layer is formed on the back of the filled metal substrate that is in contact with the permeable material of the filled holes. The cell includes an anode layer proximate to the permeable layer, an electrolyte layer proximate to the anode layer, a diffusion barrier proximate to the anode layer, and a cathode proximate to the diffusion barrier.

An oriented apatite-type oxide ion conductor includes a composite oxide expressed as A.sub.9.33+x[T.sub.6.00−yM.sub.y]O.sub.26.0+z, where A represents one or two or more elements selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Be, Mg, Ca, Sr, and Ba, T represents an element including Si or Ge or both, and M represents one or two or more elements selected from the group consisting of B, Ge, Zn, Sn, W, and Mo, and where x is from −1.00 to 1.00, y is from 0.40 to less than 1.00, and z is from −3.00 to 2.00.

A method for operating a solid oxide electrolysis cell which can suppress degradation of the hydrogen electrode, is provided. A method for operating a solid oxide electrolysis cell includes a hydrogen electrode, an oxygen electrode, and an electrolyte layer sandwiched between the hydrogen electrode and the oxygen electrode. The hydrogen electrode includes a catalyst layer structured with Ni-containing particles dispersed and supported on a porous mixed ionic and electronic conducting oxide. The method includes an alternating operation in which a water vapor electrolysis operation and a fuel cell operation are repeated alternately.