A solid oxide fuel cell comprising an anode layer, an electrolyte layer, and a two phased cathode layer. The two phased cathode layer comprises praseodymium and gadolinium-doped ceria. Additionally, the solid oxide fuel cell does not contain a barrier layer.

Some embodiments of the present invention provide solid oxide cells and components thereof having a metal oxide electrolyte that exhibits enhanced ionic conductivity. Certain of those embodiments have two materials, at least one of which is a metal oxide, disposed so that at least some interfaces between the domains of the materials orient in a direction substantially parallel to the desired ionic conductivity.

Set forth herein are processes for making lithium-stuffed garnet oxides (e.g., Li.sub.7La.sub.3Zr.sub.2O.sub.12, also known as LLZO) that have passivated surfaces comprising a fluorinate and/or an oxyfluorinate species. These surfaces resist the formation of oxides, carbonates, hydroxides, peroxides, and organics that spontaneously form on LLZO surfaces under ambient conditions. Also set forth herein are new materials made by these processes.

Embodiments of the present disclosure are directed to a diesel reformer system comprising: a diesel autothermal reforming unit; a post-reforming unit disposed downstream of the autothermal reforming unit; a heat exchanger disposed downstream of the post-reforming unit; and a desulfurization unit disposed downstream of the heat exchanger.

A redox ion exchange membrane may include an electrically-conductive material; and redox-active materials associated with that material, the redox-active materials having reversible oxidation and reduction properties. The redox-active materials may be inorganic nanostructures on the electrically-conductive material. A hydrogen production device and a fuel cell device may include such a redox ion exchange membrane positioned between the cathode and anode. A method of producing hydrogen gas may include providing a cathode, an anode, and a redox ion exchange membrane positioned between the cathode and the anode, and applying electrical power to the cathode and the anode; where that applying causes simultaneous reciprocal reduction and oxidation reactions on opposite sides of the redox ion exchange membrane, such that H+ is released on one side of the redox ion exchange membrane

The present invention inexpensively provides an electrode material for a fuel electrode, the electrode material having CO.sub.2 resistance and being capable of forming a fuel cell having high electricity generation performance. An electrode material for a fuel electrode, the electrode material constituting a fuel electrode of a fuel cell including a proton-conductive solid electrolyte layer, includes a perovskite-type solid electrolyte component and a nickel (Ni) catalyst component, in which the solid electrolyte component includes a barium component, a zirconium component, a cerium component, and a yttrium component, and the mixture ratio of the zirconium component to the cerium component in the solid electrolyte component is set to be 1:7 to 7:1 in terms of molar ratio.

A fuel cell module includes a first area where an exhaust gas combustor and a start-up combustor are provided, an annular second area around the first area where a heat exchanger is provided, an annular third area around the second area where a reformer is provided, an annular fourth area around the third area where an evaporator is provided. The heat exchanger includes heat exchange pipes connected to an oxygen-containing gas supply chamber and an oxygen-containing gas discharge chamber. A first circumscribed non-uniform flow suppression plate is provided along a minimum circumscribed circle which contacts outer surfaces of the heat exchange pipes.

The present invention includes a fuel cell system having a plurality of adjacent electrochemical cells formed of an anode layer, a cathode layer spaced apart from the anode layer, and an electrolyte layer disposed between the anode layer and the cathode layer. The fuel cell system also includes at least one interconnect, the interconnect being structured to conduct free electrons between adjacent electrochemical cells. Each interconnect includes a primary conductor embedded within the electrolyte layer and structured to conduct the free electrons.

An electrochemical cell according to an embodiment includes a hydrogen electrode, an electrolyte laminated on the hydrogen electrode, a barrier-layer laminated on the electrolyte, and an oxygen electrode laminated on the barrier-layer. The barrier-layer has a porous structure having a thickness of greater than 20 μm and a porosity of greater than 10%.

A process for the preparation of a membrane electrode assembly comprising providing, in the following layer order, (I) a green supporting electrode layer comprising a composite of a mixed metal oxide and Ni oxide; (IV) a green mixed metal oxide membrane layer; and (V) a green second electrode layer comprising a composite of a mixed metal oxide and Ni oxide; and sintering all three layers simultaneously.