A bulk permanent magnetic material may include between about 5 volume percent and about 40 volume percent Fe.sub.16N.sub.2 phase domains, a plurality of nonmagnetic atoms or molecules forming domain wall pinning sites, and a balance soft magnetic material, wherein at least some of the soft magnetic material is magnetically coupled to the Fe.sub.16N.sub.2 phase domains via exchange spring coupling. In some examples, a bulk permanent magnetic material may be formed by implanting N+ ions in an iron workpiece using ion implantation to form an iron nitride workpiece, pre-annealing the iron nitride workpiece to attach the iron nitride workpiece to a substrate, and post-annealing the iron nitride workpiece to form Fe.sub.16N.sub.2 phase domains within the iron nitride workpiece.

The present invention provides for polycrystalline superconducting permanent magnets which are synthesized of doped superconducting (AE) Fe.sub.2As.sub.2 compounds, where AE denotes an alkaline earth metal, such as Ba, Sr, Mg or Ca. The superconducting permanent magnets of the present invention can be magnetized in their superconducting state by induced currents, resulting in trapped magnetization that scales with the size of the bulk material. The magnitude of the trapped field has been demonstrated to be over 1 T and is predicted to be over 10 T if the technology is scaled, which is much higher than the capabilities of permanent magnets and other superconducting polycrystalline bulks currently known in the art.

The present invention provides for polycrystalline superconducting permanent magnets which are synthesized of doped superconducting (AE) Fe.sub.2As.sub.2 compounds, where AE denotes an alkaline earth metal, such as Ba, Sr, Mg or Ca. The superconducting permanent magnets of the present invention can be magnetized in their superconducting state by induced currents, resulting in trapped magnetization that scales with the size of the bulk material. The magnitude of the trapped field has been demonstrated to be over 1 T and is predicted to be over 10 T if the technology is scaled, which is much higher than the capabilities of permanent magnets and other superconducting polycrystalline bulks currently known in the art.

A field magnet manufacturing method where a bonded magnet's inner surface press-fitted in a yoke has a certain accuracy irrespective of the accuracy of the yoke's outer circumferential surface. A cylindrical bonded magnet from binding magnet particles with a thermosetting resin is fixed in a tubular yoke of magnetic material. The method includes reheating and softening the bonded magnet after thermal curing; and press-fitting in the bonded magnet after the softening step from a tapered portion on one end side of the yoke to press the bonded magnet's outer circumferential surface against the yoke's inner surface. The press-fitting includes feeding the bonded magnet relatively into the yoke while allowing a relative posture variation between the bonded magnet and the yoke so the bonded magnet's inner surface to be remolded into a shape along the inner surface of the yoke exhibits almost the same accuracy as the yoke's inner surface.

A sintered ferrite magnet having a composition of metal elements of Ca, R, A, Fe and Co, which is represented by the general formula of Ca.sub.1−x−yR.sub.xA.sub.yFe.sub.2n−zCo.sub.z, wherein R is at least one of rare earth elements indispensably including La; A is Sr and/or Ba; x, y, z and n represent the atomic ratios of Ca, R, A, Fe and Co; 2n represents a molar ratio expressed by 2n=(Fe+Co)/(Ca+R+A); and x, y, z and n meet the conditions of 0.15≤x≤0.35, 0.05≤y≤0.40, (1−x−y)>y, 0<z≤0.18, and 7.5≤(2n−z)<11.0.

Techniques are disclosed for milling an iron-containing raw material in the presence of a nitrogen source to generate anisotropically shaped particles that include iron nitride and have an aspect ratio of at least 1.4. Techniques for nitridizing an anisotropic particle including iron, and annealing an anisotropic particle including iron nitride to form at least one α″-Fe.sub.16N.sub.2 phase domain within the anisotropic particle including iron nitride also are disclosed. In addition, techniques for aligning and joining anisotropic particles to form a bulk material including iron nitride, such as a bulk permanent magnet including at least one α″-Fe.sub.16N.sub.2 phase domain, are described. Milling apparatuses utilizing elongated bars, an electric field, and a magnetic field also are disclosed.

A metal magnetic powder contains Co as a main component, and the metal magnetic powder includes metal nanoparticles having a mean particle size (D50) of 1 nm or more and 100 nm or less. Each of the metal nanoparticles includes hcp-Co as a main phase, and the metal magnetic powder includes fcc-Co and/or ε-Co as a sub-phase.

The present invention relates to ferrite particles for bonded magnets and a resin composition for bonded magnets which can provide a bonded magnet molded product capable of realizing a high magnetic force and a complicated multipolar waveform owing to such a feature that the ferrite particles are readily and highly oriented against an external magnetic field in a flowing resin upon injection molding, as well as a bonded magnet molded product obtained by injection-molding the above composition. According to the present invention, there are provided ferrite particles for bonded magnets which have a crystallite size of not less than 500 nm as measured in an oriented state by XRD, and an average particle diameter of not less than 1.30 μm as measured by Fisher method; a resin composition for bonded magnets; and a molded product obtained by injection-molding the composition.

Iron nitride nanoparticles and magnet materials made from iron nitride nanoparticles are described. The iron nitride nanoparticles have a core and a shell morphology. The shell is configured to provide a means to nitride the core. The magnetic materials are characterized as having an Msat greater than about 160 emu/g and a coercivity greater than about 700 Oe.

A field magnet manufacturing method where a bonded magnet's inner surface press-fitted in a yoke has a certain accuracy irrespective of the accuracy of the yoke's outer circumferential surface. A cylindrical bonded magnet from binding magnet particles with a thermosetting resin is fixed in a tubular yoke of magnetic material. The method includes reheating and softening the bonded magnet after thermal curing; and press-fitting in the bonded magnet after the softening step from a tapered portion on one end side of the yoke to press the bonded magnet's outer circumferential surface against the yoke's inner surface. The press-fitting includes feeding the bonded magnet relatively into the yoke while allowing a relative posture variation between the bonded magnet and the yoke so the bonded magnet's inner surface to be remolded into a shape along the inner surface of the yoke exhibits almost the same accuracy as the yoke's inner surface.