A proton-conductive solid electrolyte member has an electrolyte layer and an anode layer. The electrolyte layer contains a metal oxide having a perovskite crystal structure. The anode layer contains Fe.sub.2O.sub.3 and the metal oxide. The metal oxide is a metal oxide expressed by the following formula [1], or a mixture or a solid solution of a metal oxide expressed by the following formula [1]: A.sub.aB.sub.bM.sub.cO.sub.3-, where A denotes one element selected from the group consisting of Ba and Ca; B denotes one element selected from the group consisting of Ce and Zr; M denotes one element selected from the group consisting of Y, Yb, Er, Ho, Tm, Gd, In, and Sc; a is a number satisfying 0.85a1; b is a number satisfying 0.50b1; c is a number satisfying c=1b; and is an oxygen deficiency amount.

A positive electrode for a lithium-air battery includes a porous film, in which a carbon fiber composite, including an insulation coating layer formed on the outer surface of a tube-type carbon structure, is irregularly arranged. Therefore, it is possible to control the shape and size of a discharge product by inducing generation of the discharge product inside the tube-type carbon structure, thereby reducing overvoltage of a battery and improving the lifespan of the battery.

A topping cycle fuel cell unit includes a support plate having internal flow passages that extend to combustion outlets, a first electrode layer, an electrolyte layer, and a second electrode layer. The second electrode layer is configured to be coupled to another support plate of another fuel cell unit. The internal flow passages are configured to receive and direct air across the first electrolyte layer or the second electrolyte layer and to receive and direct fuel across another of the first electrolyte layer or the second electrolyte layer such that the first electrode layer, the electrolyte layer, and the second electrode layer create electric current. The internal flow passages are configured to direct at least some of the air and at least some of the fuel to the combustion outlets where the at least some air and the at least some fuel is combusted.

Described herein are bimetallic nanoframes and methods for producing bimetallic nanoframes. A method may include providing a solution including a plurality of nanoparticles dispersed in a solvent, and exposing the solution to oxygen to convert the plurality of nanoparticles into a plurality of nanoframes.

A layered cathode structure for a molten carbonate fuel cell is provided, along with methods of forming a layered cathode and operating a fuel cell including a layered cathode. The layered cathode can include at least a first cathode layer and a second cathode layer. The first cathode layer can correspond to a layer that is adjacent to the molten carbonate electrolyte during operation, while the second cathode layer can correspond to a layer that is adjacent to the cathode collector of the fuel cell. The first cathode layer can be formed by sintering a layer that includes a conventional precursor material for forming a cathode, such as nickel particles. The second cathode layer can be formed by sintering a layer that includes a mixture of particles of a conventional precursor material and 1.0 vol % to 30 vol % of particles of a lithium pore-forming compound. The resulting layered cathode structure can have an increased pore size adjacent to the cathode collector to facilitate diffusion of CO.sub.2 into the electrolyte interface, while also having a smaller pore size adjacent to the electrolyte to allow for improved electrical contact and/or reduced polarization at the interface between the electrolyte and the cathode.

Herein discussed is a method of making a fuel cell comprising (a) producing an anode using an additive manufacturing machine (AMM); (b) creating an electrolyte using the additive manufacturing machine; and (c) making a cathode using the additive manufacturing machine. In an embodiment, the anode, the electrolyte, and the cathode are assembled into a fuel cell utilizing the additive manufacturing machine. In an embodiment, the fuel cell is formed using only the additive manufacturing machine.

Herein disclosed is a method of treating a component of a fuel cell, which includes the step of exposing the component of the fuel cell to a source of electromagnetic radiation (EMR). The component comprises a first material. The EMR has a wavelength ranging from 10 to 1500 nm and the EMR has a minimum energy density of 0.1 Joule/cm2. Preferably, the treatment process has one or more of the following effects: heating, drying, curing, sintering, annealing, sealing, alloying, evaporating, restructuring, foaming. In an embodiment, the substrate is a component in a fuel cell. Such component comprises an anode, a cathode, an electrolyte, a catalyst, a barrier layer, a interconnect, a reformer, or reformer catalyst. In an embodiment, the substrate is a layer in a fuel cell or a portion of a layer in a fuel cell or a combination of layers in a fuel cell or a combination of partial layers in a fuel cell.

Herein disclosed is a method of making a fuel cell including forming an anode, a cathode, and an electrolyte using an additive manufacturing machine. The electrolyte is between the anode and the cathode. Preferably, electrical current flow is perpendicular to the electrolyte in the lateral direction when the fuel cell is in use. Preferably, the method comprises making an interconnect, a barrier layer, and a catalyst layer using the additive manufacturing machine.

A fuel cell includes: a solid oxide electrolyte layer having oxygen ion conductivity; a first electrode layer that is provided on a first face of the solid oxide electrolyte layer; and a second electrode layer that is provided on a second face of the solid oxide electrolyte layer, wherein a main component of a material having oxygen ion conductivity and a main component of a material having electron conductivity are common with each other between the first electrode layer and the second electrode layer.

A method of forming a solid oxide fuel cell. The method begins by tape casting an anode support. Next an anode functional layer slurry comprising of NiO and ScCeSZ ceramic powder is coated onto the anode support. The anode functional layer slurry is then dried to form an NiOScCeSZ anode functional layer on the anode support. A first electrolyte layer comprising of a ScCeSZ slurry is then coated onto the NiOScCeSZ functional layer. The first electrolyte layer is then dried to form a ScCeSZ electrolyte layer on the NiOScCeSZ functional layer. A second electrolyte layer comprising of a samarium doped CeO.sub.2 (SDC) slurry is then coated onto the ScCeSZ electrolyte layer. The second electrolyte layer is then dried to form a SDC electrolyte layer on the ScCeSZ electrolyte layer. The combined anode support, the NiOScCeSZ anode functional layer, the ScCeSZ electrolyte layer, and the SDC electrolyte layer is then sintered together. A cathode slurry is then coated onto the SDC electrolyte layer to form a cathode layer. A solid oxide fuel cell is then formed when the combined anode support, the NiOScCeSZ anode functional layer, the ScCeSZ electrolyte layer, the SDC electrolyte layer, and the cathode layer is then sintered together.