The control method for a flow battery includes acquiring a current electrolyte capacity decay rate of the flow battery; comparing the current electrolyte capacity decay rate with a first preset decay rate and a second preset decay rate; when the current electrolyte capacity decay rate is greater than the first preset decay rate and less than the second preset decay rate, adjusting a liquid level of positive electrolyte and a liquid level of negative electrolyte, such that a difference between these two liquid levels is less than a preset value, a ratio of the total amount of vanadium in the positive electrolyte to the total amount of vanadium in the negative electrolyte remains in a first preset ratio range, or a ratio of a vanadium ion concentration in the positive electrolyte to a vanadium ion concentration in the negative electrolyte remains in a second preset ratio range.

Systems and methods for operating an electric energy storage device are described. The systems and methods may generate a state of charge estimate that is based on negative electrode plating. An overall state of charge may be determined from the state of charge estimate that is based on negative electrode plating and a state of charge estimate that is not based on negative electrode plating.

An operation mode of a secondary battery (BAT) is determined based on state of charge of BAT. A power generation provisional command value of fuel cell (FC) at time i is determined to maximize efficiency of FC based on system required power and state of charge of BAT at time i. An intermittent ON/OFF state at time i is determined such that switching of intermittent operation of FC is not continuous based on operation mode of BAT, the power generation provisional command value, and the system required power at time i, and an intermittent ON/OFF state at time (i−1). Further, when intermittent ON is determined at time i, the FC is stopped, and when intermittent OFF is determined at time i, a larger one is output, as the power generation command value for the FC at time i, between the power generation provisional command value and an intermittent OFF threshold.

Designs of redox flow battery arrays and methods for balancing state of charge within the arrays are disclosed. Flow battery unit strings in the arrays which comprise strings of flow battery units (in which units share a common electrolyte pair) are balanced by measuring the states of charge of the common electrolyte pairs and appropriately regulating flow in one or more of the associated anolyte and catholyte circuits so as to balance the state-of charge in the flow battery unit strings. The apparatus required, i.e. state-of-charge measuring device, flow regulator, and controller, represents a substantial simplification to state of the art approaches.

This document describes techniques and systems for in operando, non-invasive SOC monitoring of redox flow batteries. The described techniques and systems allow for accurate, inexpensive, portable, and real-time methods to measure the SOC of redox flow batteries. System operators can monitor the SOC by measuring an acoustic attenuation coefficient of the electrolyte in the redox flow battery. The acoustic attenuation coefficient is measured using an ultrasonic transducer attached to a probing cell, which is connected to an electrolyte flow of a redox flow battery. The acoustic attenuation coefficient provides an accurate, real-time SOC measurement that is generally insensitive to varying operational temperatures of the electrolyte solution.

A fuel cell system includes first and second fuel cells, first and second coolers cooling coolant, first and second coolant supply path from the coolers to the fuel cells, first and second coolant discharge paths from the fuel cells to the coolers, a detour path connecting the first coolant supply path and the first coolant discharge path bypassing the first cooler, an adjusting device adjusting a flow rate of coolant of the detour path, first and second connection paths connecting the coolant supply paths and the coolant discharge paths, first and second opening/closing valves in the connection paths, and a controller configured to, when there is a possibility of flooding, suspend power generation of the first fuel cell and control the adjusting device or the first cooling device such that a temperature of the coolant of the first fuel cell increases, and open the opening/closing valves.

A method of cleansing a redox flow battery system may include operating the redox flow battery system in a charge, discharge, or idle mode, and responsive to a redox flow battery capacity being less than a threshold battery capacity, mixing the positive electrolyte with the negative electrolyte. In this way, battery capacity degradation following cyclic charging and discharging of the redox flow battery system can be substantially reduced.

A method for preparation of electrolyte for a redox flow battery includes reducing chromium ore using a carbon source to convert the chromium ore to an iron/chromium alloy with carbon particles; dissolving the iron/chromium alloy with carbon particles in sulfuric acid to form a first solution; adding calcium chloride or barium chloride to the first solution to produce a second solution including FeCl.sub.3 and CrCl.sub.3; and adding an acid to the second solution to form the electrolyte. Other methods can be used for preparing an electrolyte from chromium waste material.

A redox flow battery system includes an anolyte; a catholyte; a first electrode structure including a base having a first surface and a second surface opposite the first surface, a first electrode disposed on the first surface, a second electrode disposed on the second surface, and conductive elements that extend through the base, wherein the base resists flow of anolyte and catholyte through the base and each of the conductive elements includes a first end portion exposed at the first surface and a second end portion exposed at the second surface, wherein the first electrode includes the first end portions of the conductive elements and the second electrode includes the second end portions of the conductive elements; a first half-cell in which the first electrode is in contact with the anolyte; and a second half-cell in which the second electrode is in contact with the catholyte.

A redox flow battery system includes an anolyte having chromium ions in solution, wherein at least a portion of the chromium ions form a chromium complex with at least one of the following: NH.sub.3, NH.sub.4.sup.+, CO(NH.sub.2).sub.2, SCN.sup.−, or CS(NH.sub.2).sub.2; a catholyte having iron ions in solution; a first half-cell including a first electrode in contact with the anolyte; a second half-cell including a second electrode in contact with the catholyte; and a first separator separating the first half-cell from the second half-cell.