A fuel cell control command device including: a catalyst potential calculation unit for calculating a catalyst potential of a cathode catalyst; a coating state calculation unit for calculating an oxide film formation amount of the catalyst; a command value candidate calculation unit for calculating a plurality of command value candidates including a combination of an estimated current, estimated total voltage, and a candidate control parameter, from which a power command value is obtained; a loss amount calculation unit for calculating an estimated loss for each combination; a provisional catalyst potential calculation unit for calculating an estimated catalyst potential for each combination; a deterioration amount calculation unit for calculating an estimated deterioration amount for each combination; and a command value calculation unit for selecting a combination having a minimum comprehensive index including the estimated loss and/or the estimated deterioration amount and outputting the selected combination as a command value.

In a case where each of the temperature, the impedance, and the output current of a fuel cell stack falls within a predetermined range, the output voltage of the fuel cell stack is measured, and the measured output voltage is compared with a reference value to thereby determine the degree of degradation of the fuel cell stack.

A fuel cell system includes: a reaction gas supply unit configured to supply a reaction gas to a fuel cell stack; a humidifier configured to transfer moisture from an off-gas discharged from the fuel cell stack to the reaction gas; and a controller configured to control the reaction gas supply unit so as to regulate a supply amount of the reaction gas, wherein the controller is configured to acquire a temperature of the humidifier and set the supply amount of the reaction gas based on a target power generation amount of the fuel cell stack, and in a case where the temperature of the humidifier is equal to or lower than a prescribed warm-up determination value, the controller executes warm-up control to increase the supply amount of the reaction gas as compared with a case where the temperature of the humidifier is higher than the warm-up determination value.

Disclosed are a method and apparatus for subzero start-up of a fuel cell. The method for the subzero start-up of the fuel cell includes: introducing a gas containing hydrogen having a mass percentage of 5% to 100% to a hydrogen electrode and an air electrode of the fuel cell (2) under a condition of minus 50° C. to 0° C.; applying a current or a voltage to the fuel cell (2), and utilizing ohmic heat generation, reaction heat, and concentration overpotential heat generation of the fuel cell (2) to raise the fuel cell (2) to a required temperature or to cause the fuel cell (2) to reach to a set time, so as to implement the subzero start-up of the fuel cell.

A fuel cell control method and system based on model prediction control are provided. The method includes: (1) obtaining data required for control; (2) determining whether the data required for control are received completely; (3) estimating an internal state of a fuel cell based on outlet pressure of an air compressor and a voltage of the fuel cell to obtain a state estimation result; (4) calculating a target outlet flow of the air compressor and a target current of the fuel cell with a model prediction control algorithm based on the state estimation result; (5) calculating a control voltage of the air compressor, and a target outlet flow of the air compressor; and (6) tracking power of the fuel cell based on the target current of the fuel cell, and controlling air supply of the fuel cell based on the control voltage of the air compressor.

Systems and methods for controlling fluid flow in a fuel cell circuit of a vehicle. A system may have a fuel cell stack configured to receive hydrogen gas. The system may have a current sensor configured to detect current flowing through the fuel cell stack. The system may have a plurality of actuators, which may include at least one injector, a pump, and a shut valve. The system may have an electronic control unit (ECU). The ECU may estimate pressures of the hydrogen gas and non-hydrogen gases in the circuit. The ECU may determine a current increase rate based on the detected current. The ECU may apply a compensatory hydrogen gas stoic to a base hydrogen gas stoic to meet a target hydrogen gas stoic by controlling one or more of the actuators based on the estimated pressures when the current increase rate is above a predetermined threshold value.

A fuel cell system includes a solid oxide fuel cell capable of generating power by receiving a supply of a reformed gas and an oxidant gas; an oxidant gas supply device that supplies the oxidant gas to the fuel cell; a reforming unit that supplies the reformed gas to the fuel cell; a fuel supply device that supplies a fuel which is a raw material for the reformed gas to the reforming unit; a combustion unit that combusts discharged gases of the fuel cell, wherein the reforming unit can reform the fuel into the reformed gas by exchanging heat with a combustion gas produced by the combustion unit; and a first control unit controls the fuel supply device to additionally supply the fuel to the fuel cell through the reforming unit in order to prevent the oxidant gas from flowing in from downstream of a fuel electrode of the fuel cell at the time of stopping the system. The fuel cell system further includes a second control unit that controls to supply the fuel to the reforming unit before the additional supply so that the temperature of the reformed gas flowing into the fuel cell does not exceed a predetermined temperature at the time of stopping the system.

Systems, methods, and devices of the various embodiments provide a hardware and software architecture enabling electrochemical impedance spectroscopy (“EIS”) to be performed on multiple electrochemical devices, such as fuel cells, at the same time without human interaction with the electrochemical devices and to use EIS to dynamically monitor the performance of a fuel cell system. Embodiment methods may include determining an impedance of a set of fuel cells using electrochemical impedance spectroscopy, determining an ohmic polarization of the set of fuel cells from the impedance, determining a concentration polarization of the set of fuel cells from the impedance, comparing the ohmic polarization of the set of fuel cells to a first threshold, comparing the concentration polarization of the set of fuel cells to a second threshold, and initiating a corrective action when the ohmic polarization is above the first threshold or when the concentration polarization is below the second threshold.

Methods are disclosed for detecting and lessening fuel starvation conditions in an operating fuel cell system. The fuel cell systems comprise a solid polymer electrolyte fuel cell with a regulating apparatus for regulating the pressure of fuel supplied to the anode inlet of the fuel cell, in which the outlet pressure from the regulating apparatus oscillates during operation. The methods involve monitoring an electrical output of the fuel cell during operation, determining the amplitude of oscillation in the electrical output, and then, if the determined amplitude of oscillation in the electrical output exceeds a predetermined amount thereby indicating a fuel starvation condition, taking a remedial action to lessen the fuel starvation condition.

A fuel cell system and method, the system including power generating fuel cells disposed in a stack, each power generating fuel cell including an anode, a cathode, and an electrolyte, a sensing fuel cell including an anode, a cathode, and an electrolyte, and a fuel processor configured to purify a fuel provided to the power generating fuel cells and the sensing fuel cell. The anode of the sensing fuel cell is thinner than the anodes of the power generating fuel cells.