A fuel cell membrane electrode assembly is provided comprising a polymer electrolyte membrane comprising a first polymer electrolyte and at least one manganese compound; and one or more electrode layers comprising a catalyst and at least one cerium compound. The membrane electrode assembly demonstrates an unexpected combination of durability and performance.

This specification describes an ion exchange membrane and a method of making it. The membrane may be used, for example, in an electrodialysis module or electrochemical cell. The membrane comprises an ion exchange polymer and inorganic particles preferably linked to the ion exchange polymer. To make a membrane, inorganic particles are mixed into an ion exchange membrane pre-cursor. A polymerization initiator or catalyst is then added and the resulting mixture is placed in a form and cured. The inorganic particles may comprise, for example, an oxidized form of graphite such as graphite oxide. The ion exchange polymer may comprise an ionic monomer, containing a quaternary ammonium group for anion exchange or a sulfonate group for cation exchange, along with a crosslinking co-monomer containing polymerizable diacrylic functionalities. The membrane is self-supporting and can be made without a supporting fabric.

This specification describes an ion exchange membrane and a method of making it. The membrane may be used, for example, in an electrodialysis module or electrochemical cell. The membrane comprises an ion exchange polymer and inorganic particles preferably linked to the ion exchange polymer. To make a membrane, inorganic particles are mixed into an ion exchange membrane pre-cursor. A polymerization initiator or catalyst is then added and the resulting mixture is placed in a form and cured. The inorganic particles may comprise, for example, an oxidized form of graphite such as graphite oxide. The ion exchange polymer may comprise an ionic monomer, containing a quaternary ammonium group for anion exchange or a sulfonate group for cation exchange, along with a crosslinking co-monomer containing polymerizable diacrylic functionalities. The membrane is self-supporting and can be made without a supporting fabric.

The present invention relates to a graphene-based or other 2-D material membrane which allows the passage of protons and deuterons and to a method of facilitating proton or deuteron permeation through such a membrane. Monocrystalline membranes made from mono- and few-layers of graphene, hBN, molybdenum disulfide (MoS2), and tungsten disulfide (WS2) etc. are disclosed. In effect, the protons or deuterons are charge carriers that pass through the graphene or other 2-D material membrane. This process can be contrasted with the passage of gaseous hydrogen. Hydrogen is an uncharged gaseous species which is diatomic. In other words, the gas is in molecular form when considering the normal barrier properties whereas in the case of the present invention, the species which is being transported through the membrane is a charged ion comprising a single atom. Membranes of the invention find use in a number of applications such as fuel cells.

Disclosed are a polymer electrolyte membrane showing high ion conductivity even under the condition of low humidity and high temperature and a method for manufacturing the same. The polymer electrolyte membrane of the present invention comprises a porous substrate, a self proton conducting material dispersed in the porous substrate, and an ion conductor impregnated in the porous substrate. The self proton conducting material comprises an inorganic particle functionalized with an azole ring.

Disclosed are a polymer electrolyte membrane showing high ion conductivity even under the condition of low humidity and high temperature and a method for manufacturing the same. The polymer electrolyte membrane of the present invention comprises a porous substrate, a self proton conducting material dispersed in the porous substrate, and an ion conductor impregnated in the porous substrate. The self proton conducting material comprises an inorganic particle functionalized with an azole ring.

The present invention provides a proton exchange membrane comprising an ion-conducting layer which comprises an ion-conducting polymer and a supported recombination catalyst, wherein the recombination catalyst is supported on graphene.

A membrane electrode assembly for the fuel cell includes a solid polymer electrolyte membrane, an anode catalyst layer assembled to one surface of the solid polymer electrolyte membrane, and a cathode catalyst layer assembled to another surface of the solid polymer electrolyte membrane. The membrane electrode assembly contains cerium ions. The membrane electrode assembly includes a power-generation region and a non-power-generation region. The power-generation region includes the catalyst layers on both surfaces of the solid polymer electrolyte membrane in a center portion. The non-power-generation region is without the catalyst layer on at least one surface of the solid polymer electrolyte membrane in an outer periphery portion. A cerium ion content per area in the power-generation region is larger than a cerium ion content per area in the non-power-generation region.

Disclosed are a radical scavenger, a method for preparing same, and a membrane-electrode assembly containing same, wherein the radical scavenger can maintain the performance of a fuel cell for a long time and enhance the lifespan thereof since the elution of metal ions derived from radical scavenging particles during fuel cell operation can be continuously prevented for a long time. The radical scavenger of the present invention comprises: radical scavenging particles; and a porous protective film on the surface of the radical scavenging particles, wherein the porous protective film comprises at least one material of high oxidative stability selected from the group consisting of silica, carbon nitride, heteroatom-doped graphene, a porphyrin-based compound, a phenazine-based compound, and derivatives thereof.

Disclosed are a radical scavenger, a method for preparing same, and a membrane-electrode assembly containing same, wherein the radical scavenger can maintain the performance of a fuel cell for a long time and enhance the lifespan thereof since the elution of metal ions derived from radical scavenging particles during fuel cell operation can be continuously prevented for a long time. The radical scavenger of the present invention comprises: radical scavenging particles; and a porous protective film on the surface of the radical scavenging particles, wherein the porous protective film comprises at least one material of high oxidative stability selected from the group consisting of silica, carbon nitride, heteroatom-doped graphene, a porphyrin-based compound, a phenazine-based compound, and derivatives thereof.