A continuous automated process and production line for preparing an acid doped polybenzimidazole, PBI, polymer membrane film for use in a fuel cell, the process having a washing stage, a drying procedure, and a doping stage.

A new polyelectrolyte multilayer coated proton-exchange membrane for electrolysis and fuel cell applications has been developed for electrolysis and fuel cell applications. The polyelectrolyte multilayer coated proton-exchange membrane comprises: a cation exchange membrane, and a polyelectrolyte multilayer coating on one or both surfaces of the cation exchange membrane. The polyelectrolyte multilayer coating comprises alternating layers of a polycation polymer and a polyanion polymer. The polycation polymer layer is deposited on and is in contact with the cation exchange membrane. The top layer of the polyelectrolyte multilayer coating can be either a polycation polymer layer or a polyanion polymer layer.

A continuous automated process and production line for preparing an acid doped polybenzimidazole, PBI, polymer membrane film for use in a fuel cell, the process having a washing stage, a drying procedure, and a doping stage.

A continuous automated process and production line for preparing an acid doped polybenzimidazole, PBI, polymer membrane film for use in a fuel cell, the process having a washing stage, a drying procedure, and a doping stage.

This invention relates to an an-ion exchange membrane and method for making said membrane. The membrane being intended for use in electrolysers or other AEM electrochemical devices. The membrane comprises: a thermoplastic elastomer (TPE) comprising styrene, said TPE being a polymeric backbone, wherein: the styrene content of the thermoplastic elastomer is between 30 wt % and 70 wt %, and crosslinking of a first polymeric backbone to one or more other polymeric backbones, and one or more cationic groups, and the functionalisation degree is between 1% and 50%.

The present disclosure relates to a composition that includes a first layer that includes a polymer having a repeat unit with a structure that includes

##STR00001##

where m is between 2 and 100, inclusively, the repeat unit is protonated at at least one of position A) and/or B) and/or sulfonated at at least one of rings 1) and/or 2), R.sub.1 includes at least one of a lone pair of electrons, a covalent bond, hydrogen, and/or a hydrocarbon functional group, R.sub.2 includes at least one of a lone pair of electrons, a covalent bond, hydrogen, and/or a hydrocarbon functional group, and is a covalent bond.

The present disclosure relates to a composition that includes a first layer that includes a polymer having a repeat unit with a structure that includes

##STR00001##

where m is between 2 and 100, inclusively, the repeat unit is protonated at at least one of position A) and/or B) and/or sulfonated at at least one of rings 1) and/or 2), R.sub.1 includes at least one of a lone pair of electrons, a covalent bond, hydrogen, and/or a hydrocarbon functional group, R.sub.2 includes at least one of a lone pair of electrons, a covalent bond, hydrogen, and/or a hydrocarbon functional group, and is a covalent bond.

A proton exchange solid support includes a porous polymer network including a polymer. The polymer includes a tetravalent boron-based acid group in a side chain of the polymer, and the tetravalent boron-based acid group includes a boron atom having a negative formal charge. A cation is ionically linked to the boron atom.

An ion exchange membrane (52) for a fuel cell comprises a polymer having an acid functional group normally including protons, and having alkali metal ions partially ion-exchanged with the protons of the acid functional group of the membrane. The partial ion exchange of alkali metal ions into the membrane relates either to patterning of the exchanged ion make-up of the membrane, with some being ion exchanged and some not, or to the extent or concentration of the ion exchange in any particular location, or to both.

An ion exchange membrane (52) for a fuel cell comprises a polymer having an acid functional group normally including protons, and having alkali metal ions partially ion-exchanged with the protons of the acid functional group of the membrane. The partial ion exchange of alkali metal ions into the membrane relates either to patterning of the exchanged ion make-up of the membrane, with some being ion exchanged and some not, or to the extent or concentration of the ion exchange in any particular location, or to both.