Patent classifications
H01M2300/0077
Fuel cell
The fuel cell of the present disclosure includes: a fuel single cell comprising a fuel electrode, an air electrode, and an electrolyte disposed between the electrodes; a separator for separating a fuel gas flowing through the fuel electrode and air flowing through the air electrode; and a sealing portion for hermetically bonding between the separator and the electrolyte, wherein the sealing portion is constituted of a glass composition containing at least two of metallic or metalloid elements contained in the electrolyte and at least two of metallic or metalloid elements contained in the separator; the electrolyte includes a proton conductor; and the proton conductor is represented by a compositional formula: BaZr.sub.1-xM.sub.xO.sub.3, where 0.05≤x≤0.5; and M is at least one selected from the group consisting of Sc, In, Lu, Yb, Tm, Er, Y, Ho, Dy, and/or Gd.
Solid electrolyte and all-solid battery
A solid electrolyte having a garnet type crystal structure. The garnet type crystal structure contains Li, La, Zr, O and Ga and at least one element selected from Al, Mg, Zn and Sc.
Electrolyte, battery, electronic apparatus, and methods for producing electrolyte and battery
An electrolyte according to the present disclosure contains a lithium composite metal oxide represented by the following compositional formula.
Li.sub.7-xLa.sub.3(Zr.sub.2-xA.sub.x)O.sub.12-yF.sub.y
In the formula, 0.1≤x≤1.0, 0.0<y≤1.0, and A represents two or more types of Ta, Nb, and Sb.
ELECTRODE FOR POWER STORAGE DEVICE, AND POWER STORAGE DEVICE
To enhance lithium ion conductivity in an electrode for a power storage device, and at the interface between the electrode and another member. The power storage device electrode includes an oxide-based lithium ion conductive solid electrolyte, an active material, and an ionic liquid.
Composition for use as an electrolyte in a protonic ceramic fuel cell and a fuel cell thereof
The present invention relates to a solid oxide fuel cell especially protonic ceramic fuel cell which can operate at intermediate temperature and fuel cell thereof. The composition comprising a formula BaCe.sub.0.7Zr.sub.0.25-xY.sub.xZn.sub.0.05O.sub.3-δ or BaCe.sub.0.7Zr.sub.0.1Y.sub.0.2-xPr.sub.xO.sub.3-δ, wherein x=0.05, 0.1, 0.15, 0.2 or 0.25 to vary Zr and Y percentage at the B-site, and Ba=100%, Ce=70%; and Zn=5%.
Composition for forming lithium reduction resistant layer, method for forming lithium reduction resistant layer, and lithium secondary battery
A composition for forming a lithium reduction resistant layer includes a solvent, and a lithium compound, a lanthanum compound, a zirconium compound, and a compound containing a metal M, each of which shows solubility in the solvent, and in which with respect to the stoichiometric composition of a compound represented by the general formula (I), the lithium compound is contained in an amount 1.05 times or more and 2.50 times or less, the lanthanum compound and the zirconium compound are contained in an amount 0.70 times or more and 1.00 times or less, and the compound containing a metal M is contained in an equal amount.
Li.sub.7-xLa.sub.3(Zr.sub.2-x,M.sub.x)O.sub.12 (I)
Composite polymer electrolyte (CPE) membranes for secondary solid state li-metal cells and process for the production thereof
The present invention relates to a curable composition for preparing a composite polymer electrode, the curable composition containing: A) a Li-ion conducting solid electrolyte whose general composition has the formula:
Li.sub.7+x−yM.sup.II.sub.xM.sup.III.sub.3−xM.sup.IV.sub.2−yO.sub.12 wherein
M.sup.II, M.sup.III, M.sup.IV, M.sup.V are species of valence II to V; where 0≤x<3, preferably 0≤x≤2; and 0≤y<2 preferably 0≤y≤1; (B) a polymer; (C) a lithium salt; (D) an active plasticizer; and (E) a photoinitiator. The invention also relates to a process of preparing the curable composition, cured compositions and films derived from the curable composition, and solid-state lithium batteries whose solid electrolyte layer contains a cured composition or a cured film according to the invention.
METHOD FOR FORMING A LI-ION BATTERY CELL
A Li-ion battery cell includes cathode and anode materials, a separator, and an electrolyte including a mixture of a polyethylene oxide and an oxide of formula LivLasZnOn. A method of forming the cell includes the following successive cycling steps: (a) at least two successive charge and discharge cycles of the cell at a first cycling rate C/x, the charge/discharge steps being limited in time to x/2; (b) at least two successive charge and discharge cycles of the cell at a second charging rate C/y, different from the first cycling rate, where y is lower than x, the charge/discharge steps being limited in time to y/2; and (c) at least two successive charge and discharge cycles of the cell at a third cycling rate C/z different from the first and second charging rates, where z is lower than x and y, the charge/discharge steps being limited in time to z/2.
Electrolyte for a solid-state battery
Electrolyte for a solid-state battery includes a body having grains of inorganic material sintered to one another, where the grains include lithium. The body is thin, has little porosity by volume, and has high ionic conductivity.
Non-aqueous electrolyte secondary battery
Provided is a non-aqueous electrolyte secondary battery capable of reliably operating an electricity shut-off mechanism at overcharging without deteriorating battery performance. The non-aqueous electrolyte secondary battery (1) includes, in a container (2): a positive electrode (41); in-container positive electrode terminals (21) and (23); a negative electrode (42); in-container negative electrode terminals (22) and (24); a non-aqueous electrolyte solution; and an electricity shut-off mechanism (68b) capable of shutting off energization with the outside of the container when the internal pressure of the container rises. A solid electrolyte layer that produces gas allowing the electricity shut-off mechanism (68b) to be operated is included in at least one member of a positive electrode mixture layer unformed portion (41b), a negative electrode mixture layer unformed portion (42b), the in-container positive electrode terminals (21) and (23), and the in-container negative electrode terminals (22) and (24).