Disclosed herein is a ceramic particle comprising a core substrate chosen from yttria-stabilized zirconia, partially stabilized zirconia, zirconium oxide, aluminum nitride, silicon nitride, silicon carbide, and cerium oxide, and a conformal coating of a sintering aid film having a thickness of less than three nanometers and covering the core substrate, and methods for producing the ceramic particle.

A metal-supported anode for a solid oxide fuel cell is provided that includes a metal substrate having at least one hole formed therein, and an anode material formed on a first surface of the metal substrate. The anode material is also formed within each of the at least one hole. The at least one hole extends from the first surface of the metal substrate to a second surface of the metal substrate opposite the first surface, and the at least one hole has a different size at the first surface of the metal substrate than at the second surface of the metal substrate.

A solid electrolyte including: a lithium ion inorganic conductive layer; and an amorphous phase on a surface of the lithium ion inorganic conductive layer, wherein the amorphous phase is an irradiation product of the lithium ion inorganic conductive layer. Also, the method of preparing the same, and a lithium battery including the solid electrolyte.

A cerium-zirconium oxide-based ionic conductor (CZOIC) material including zirconium oxide in an amount ranging from 5 wt. % up to 95 wt. %, cerium oxide in an amount ranging from 95 wt. % to 5 wt. %, and at least one oxide or a rare earth metal in an amount ranging from 30 wt. % or less, based on the overall mass of the CZOIC material. The CZOIC material exhibits a structure comprising one or more expanded unit cells and a plurality of crystallites having ordered nano-domains. The structure of the CZOIC material exhibits a crystal lattice defined by a d-value measured at multiple (hkl) locations using a SAED technique that exhibit distortions, such that the d-values for the same (hkl) location varies from about 2% to about 5% from the d-value measured for a reference cerium-zirconium material at the same (hkl) location.

A solid electrolyte ceramic material that includes sintered solid electrolyte particles containing, at least, lithium (Li), lanthanum (La), bismuth (Bi), and oxygen (O), wherein the Bi is at a higher concentration in a vicinity of a grain boundary of the sintered solid electrolyte particles than in a grain interior of the sintered solid electrolyte particles.

A positive electrode active material that is used in a high-temperature operation type lithium ion solid secondary battery, wherein the positive electrode active material is made of oxide particles, which contains a first transition element and does not include an alkali metal.

A method of forming an interlayer of a solid oxide cell unit on the surface of a substrate may include: providing a base interlayer solution comprising a solution of a soluble salt precursor of a metal oxide (crystalline) ceramic and crystalline nanoparticles, depositing the base interlayer solution onto the surface of the substrate, drying the base interlayer solution to define a nanocomposite sub-layer of the soluble salt precursor and nanoparticles, heating the sub-layer to decompose it and form a film of metal oxide comprising nanoparticles on the surface, and firing the substrate with the film on the metal surface, to form a nanocomposite crystalline layer.

A powder with particulates of a lithium ion-conducting material has a conductivity of at least 10.sup.−5 S/cm. The powder has an inorganic carbon content (Total Inorganic Carbon Content (TIC)) of less than 0.4 wt % and/or an organic carbon content (Total Organic Carbon Content (TOC)) of less than 0.1 wt %. The particulates have a d50 particle size in a range from 0.05 μm to 10 μm. The particulates have a particle size distribution log (d90/d10) of less than 4.

A battery of the present disclosure includes a positive electrode, a negative electrode, and an electrolyte layer provided between the positive electrode and the negative electrode. The positive electrode contains a positive electrode active material and a first solid electrolyte. The electrolyte layer contains a second solid electrolyte. The first solid electrolyte contains lithium and two or more types of anions. The second solid electrolyte contains lithium and two or more types of anions. The molar ratio of Br to the two or more types of anions contained in the first solid electrolyte is smaller than the molar ratio of Br to the two or more types of anions contained in the second solid electrolyte.

Integrated devices comprising integrated circuits and energy storage devices are described. Disclosed energy storage devices correspond to an all-solid-state construction, and do not include any gels, liquids, or other materials that are incompatible with microfabrication techniques. Disclosed energy storage device comprises energy storage cells with electrodes comprising metal-containing compositions, like metal oxides, metal nitrides, or metal hydrides, and a solid state electrolyte.