In at least one embodiment, a single sintered magnet is provided having a concentration profile of heavy rare-earth (HRE) elements within a continuously sintered rare-earth (RE) magnet bulk. The concentration profile may include at least one local maximum of HRE element concentration within the bulk such that a coercivity profile of the magnet has at least one local maximum within the bulk. The magnet may be formed by introducing alternating layers of an HRE containing material and a magnetic powder into a mold, pressing the layers into a green compact, and sintering the green compact to form a single, unitary magnet.

A rare earth permanent magnet includes a main phase composed of a main phase particle and a grain boundary present among a plurality of the main phase particles. The grain boundary includes a region whose electric resistance is higher than that of the main phase.

A sintered annular magnet with a radial orientation of a remanent magnetic field, including: a principal annular part made from a ferromagnetic material, that has a first degree of magnetic anisotropy in the radial direction; and an annular reinforcing part fixed to the principal part of the magnet, the reinforcing part being made from same ferromagnetic material as the ferromagnetic material forming the principal part, and that has a second degree of magnetic anisotropy in the radial direction, the first degree being higher than the second degree.

The present invention discloses a short process preparation technology of sintered NdFeB magnets from the NdFeB sludge, which relates to a field of recycle technology of NdFeB sludge. The present invention comprises the following steps: water bath distillation of organics in sludge, ultrasonic cleaning, calcium reduction and diffusion, ultrasonic rinsing in a magnetic field and drying, powders mixing and sintering. NdFeB sludge as raw materials was directly prepared from recycled sintered magnets with high magnetic properties. Most of the organics in the sludge could be removed by a vacuum distillation process with stepwise heating. The ultrasonic rinsing process in a magnetic field could effectively remove the remaining organics. The recycled sintered magnets exhibited good maximum energy product [(BH).sub.max] of 35.26 MGOe. The present invention has important features, such as the short processing time, efficient environmental protection, high recycling rate and effective utilization rate of rare earth metals.

Disclosed herein is a method for manufacturing an R-T-B permanent magnet and the magnet made with the method. The method may include preparation of strip pieces by melting and casting, preparing coarse powder by hydrogen decrepitation of the strip pieces; milling the powder into fine powder; pressing the fine powder is pressed to form a compact, pre-sintering the compact in vacuum or inert gas, machining the pre-sintered block to a desired shape; and dispersing the heavy rare earth compound powder into an organic solvent to prepare a slurry and a second sintering step.

A sintered R.sub.2M.sub.17 magnet is provided that comprises at least 70 Vol % of a Sm.sub.2M.sub.17 phase, wherein R is at least one of the group consisting of Ce, La, Nd, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yt, Lu and Y, and M comprises Co, Fe, Cu and Zr. In an area of the R.sub.2M.sub.17 sintered magnet of 200 by 200 μm viewed in a Kerr micrograph, an areal proportion of demagnetised regions after application of an internal opposing field of 1200 kA/m is less than 5% or less than 2%.

A permanent magnet of an embodiment includes a sintered compact, the sintered compact including: a composition expressed by R.sub.pFe.sub.qM.sub.rCu.sub.sCo.sub.100-p-q-r-s, (R is at least one element selected from rare earth elements, M is at least one element selected from Zr, Ti, and Hf, 10.5≦p≦12.5 atomic %, 24≦q≦40 atomic %, 0.88≦r≦4.5 atomic %, and 3.5≦s≦10.7 atomic %); and a structure having crystal grains each composed of a main phase including a Th.sub.2Zn.sub.17 crystal phase, and a crystal grain boundary of the crystal grains. An average crystal grain diameter of the crystal grains is 50 μm or more and 100 μm or less, and a ratio of the crystal grains having a crystal grain diameter of 50 μm or more is 75% or more.

The present invention relates to a Ce-containing sintered rare earth permanent magnet with high toughness and high coercivity and a method of preparing the magnet, belonging to the technical field of rare earth permanent magnetic materials. The magnet is prepared by steps of raw material batching, strip casting, hydrogen decrepitation and jet milling, powder orientating and forming, sintering and heat treatment. The materials of the permanent magnet comprise the main phase alloy powders and the Ce added phase alloy powders, wherein the Ce added phase alloy is a magnetic phase or a non-magnetic liquid-phase alloy; and the Ce added phase alloy accounts for 5% to 30% of the total weight of the permanent magnet, and the remainder is the main phase alloy. During the jet milling stage, a certain concentration of oxygen is added into the inert gas, so that the final magnet has an oxygen content of 1500 to 2500 ppm. The Ce-containing dual-alloy magnet prepared in accordance with the present invention has high coercivity, and the intrinsic coercivity (H.sub.cj) is up to 17 to 28.73 kOe. The magnet of the present invention has good fracture toughness which is increased by 10% to 30% as compared with the conventional Nd—Fe—B sintered magnet. The magnet of the present invention can meet needs of high-end applications such as wind power generation, new energy vehicles, and the like, and greatly expands the application fields of Ce-containing magnets.

A method for producing a powdered starting material, which is provided for production of rare earth magnets, including the following steps: pulverizing an alloy, including at least one rare earth metal, wherein a powdered intermediate product is formed from the alloy including at least one rare earth metal, and carrying out at least one classification aimed at particle size and/or density for the powdered intermediate product, wherein a fraction of the powdered intermediate product, which is formed by means of the at least one classification, for fabrication of rare earth magnets. Furthermore, at least one dynamic classifier is provided, implementing at least one classification directed at particle size and/or density for the powdered intermediate product and thereby separates the fraction from the powdered intermediate product, which forms the starting material provided for manufacturing rare earth magnets.

A two-step diffusion method for preparing high-performance dual-main-phase sintered mischmetal-iron-boron magnet belongs to the preparing technical field of rare earth permanent magnet materials. The compositions of the two main phase alloys are RE-Fe—B (RE is Nd or Pr) and (Nd, MM)-Fe—B (MM is mischmetal), respectively. First, PrHoFe strip-casting alloy is used as a diffusion source. Next, a PrHo-rich layer is uniformly coated on the surface of (Nd, MM)-Fe—B hydrogen decrepitation powders. The higher anisotropic fields of Pr.sub.2Fe.sub.14B and Ho.sub.2Fe.sub.14B are used to improve the coercivity. Then, the ZrCu strip-casting alloy is used as a diffusion source. A Zr-rich layer is uniformly coated on the surface of the powders after the first-step diffusion, which prevents the growth of the MM-rich main phase grains during the sintering process and the inter-diffusion between the two main phases, thus obtaining high coercivity.