Disclosed are an amorphous nanocrystalline soft magnetic material, a preparation method therefor and an application thereof, an amorphous ribbon material, an amorphous nanocrystalline ribbon material, and an amorphous nanocrystalline magnetic sheet. The soft magnetic material comprises an amorphous matrix phase, a nanocrystalline phase distributed in the amorphous matrix phase, and fine crystalline particles distributed in the amorphous matrix phase and the nanocrystalline phase. The amorphous matrix phase comprises Fe, Si, and B, the fine crystalline particles comprise metal carbides, and the soft magnetic material comprises Fe, Si, B, P, and Cu.

Provided is an amorphous alloy soft magnetic powder having a composition represented by the following formula: (Fe.sub.xCo.sub.(1−x)).sub.(100−(a+b))(Si.sub.yB.sub.(1−y)) .sub.aM.sub.b, [where M is at least one selected from the group consisting of C, S, P, Sn, Mo, Cu, and Nb, 0.73≤x≤0.85, 0.02 ≤y≤0.10, 13.0 ≤a≤19.0, and 0≤b≤2.0], in which a coercive force is 24 [A/m] or more (0.3 [Oe] or more) and 199 [A/m] or less (2.5 [Oe] or less), and a saturation magnetic flux density is 1.60 [T] or more and 2.20 [T] or less.

An amorphous metal ribbon includes a plurality of laser irradiation mark rows each including a plurality of laser irradiation marks arranged in a row, in which when a distance between the laser irradiation mark rows that are adjacent to each other is set as d1, a distance between the laser irradiation marks in the laser irradiation mark row is set as d2, a diameter of the laser irradiation mark is set as d3, and a number density D of the laser irradiation marks is set as (1/d1)×(1/d2), the number density D of the laser irradiation marks is 0.05 pieces/mm.sup.2 or more and 0.50 pieces/mm.sup.2 or less, and when an area occupancy rate A of the laser irradiation marks is set as D×(d3/2).sup.2×π×100, the area occupancy rate A of the laser irradiation marks is 0.0035% or more and 0.040% or less.

An amorphous metal ribbon includes a plurality of laser irradiation mark rows each including a plurality of laser irradiation marks arranged in a row, in which when a distance between the laser irradiation mark rows that are adjacent to each other is set as d1, a distance between the laser irradiation marks in the laser irradiation mark row is set as d2, a diameter of the laser irradiation mark is set as d3, a depth of the laser irradiation mark is set as d4, and a volume occupancy rate V of the laser irradiation marks is set as (1/d1×d3×d4)×(1/d2)×100, the volume occupancy rate V of the laser irradiation marks is 0.00057% or more and 0.010% or less.

A method for manufacturing a wound magnetic core of a nanocrystalline soft magnetic alloy ribbon, the method including: a first heat treatment step of subjecting a wound magnetic core, which is formed by winding an amorphous soft magnetic alloy ribbon capable of nanocrystallization, to a heat treatment at a temperature that is 300° C. or higher and below a crystallization start temperature, with a first inner shape correction jig for holding the wound magnetic core in a non-circular shape placed in an internal space of the wound magnetic core; and a second heat treatment step of subjecting the wound magnetic core to a heat treatment for nanocrystallization at a temperature equal to or higher than the crystallization start temperature, with the first inner shape correction jig removed and with at least one second inner shape correction jig placed in the internal space of the wound magnetic core, wherein: a cross section of the second inner shape correction jig perpendicular to a direction in which the second inner shape correction jig extends is smaller than a cross section of the first inner shape correction jig perpendicular to a direction in which the first inner shape correction jig extends; and a magnetic field is applied to the wound magnetic core over a partial period of the second heat treatment step.

The invention relates to the reduction of core losses in soft magnetic applications utilizing amorphous foil as the core material. Amorphous foil is known to have lower losses when compared to crystalline silicon steel laminations. It is found that a reduction of 10-40% of losses can be achieved over the current state of the art amorphous material by mechanical scribing of the surface of the soft magnetic laminations comprising the wound core in power conditioning devices such as a transformer. The scribing process introduces control of the magnetic domains causing ease of magnetic flux reversal

The present application provides an iron-based amorphous alloy powder, a preparation method therefor and an application thereof. The iron-based amorphous alloy powder comprises a Cu element, and the particle shape of the iron-based amorphous alloy powder is spherical. The preparation method comprises the following steps: (1) smelting a master alloy to obtain iron-based amorphous alloy molten iron, the master alloy comprising a Cu element; and (2) treating the iron-based amorphous alloy molten iron obtained in step (1) by means of water-gas combined atomization to obtain the iron-based amorphous alloy powder.

The method heats the metal foil made of amorphous soft magnetic material while bringing the metal foil into close contact with a placement surface of a metal base such that the metal foil conforms to the placement surface, to crystallize the amorphous soft magnetic material of the metal foil into nano-crystal soft magnetic material, in the crystallization, the metal foil is heated at a heating temperature to crystallize the amorphous soft magnetic material, the heating temperature being higher than or equal to a crystallization starting temperature at which the amorphous soft magnetic material crystallizes into nano-crystal soft magnetic material and allowing a temperature of the placement surface to be lower than a temperature of the metal foil having temperature rise due to heat generated by self-heating during crystallization, and the heat generated by self-heating of the metal foil during crystallization is absorbed by the base.

The object of the present invention is to provide an alloy ribbon capable of having excellent adhesiveness between the alloy ribbons when a plurality of the alloy ribbons is stacked; and also, to provide a magnetic core using the alloy ribbon. The present invention is an alloy ribbon comprising metals scattered on at least one surface of the alloy ribbon, in which diameters of the scattered metals are 1 μm or more, and the scattered metals include Cu.

The soft magnetic alloy of the present disclosure is represented by a composition formula of Fe.sub.aSi.sub.bB.sub.cCu.sub.dM.sub.e where M is at least one type of element selected from a group consisting of Nb, Mo, V, Zr, Hf, and W, and the formula satisfies 82.5≤a≤86, 0.3≤b≤3, 12.5≤c≤15.0, 0.05≤d≤0.9, and 0≤e<0.4 in at %. The soft magnetic alloy includes a structure that has a crystal grain with a grain diameter of 60 nm or less in an amorphous phase.