A substrate in which a high-dielectric-constant gate insulator is formed on a silicon substrate with an interface layer film sandwiched in between is housed in a chamber. A mixed gas of ammonia and nitrogen gas is supplied to the chamber to form an ammonia atmosphere, and flash light is applied in the ammonia atmosphere from flash lamps to the surface of the substrate for an emission time of 0.2 milliseconds to one second. This allows the high-dielectric-constant gate insulator to be heated in the ammonia atmosphere and accelerates nitriding of the high-dielectric-constant gate insulator. Since the time for which flash light is applied is an extremely short time, nitrogen will not reach and nitride the interface layer film, which is formed as a base of the high-dielectric-constant gate insulator.

A method for forming a semiconductor structure is provided. The method includes providing a substrate having a first region and a second region; and forming at least one first trench in the first region of the substrate, and at least one second trench in second region of the substrate. The method also includes forming a first liner layer on side and bottom surfaces of the first trench, and the side and bottom surfaces of the second trench; and performing a rapid thermal oxy-nitridation process on the first liner layer to release a tensile stress between the first liner layer and the substrate. Further, the method includes removing a portion of the first liner layer in the first region to expose the first trench; and forming a second liner layer on the side and bottom surface of the first trench.

A spin torque oscillator (STO) device includes a main pole, a trailing shield, an STO stack disposed between the main pole and the trailing shield, a passivation layer disposed on a sidewall of the STO stack, and a dielectric layer disposed on the passivation layer. The passivation layer is non-magnetic and includes one or more layers that is selected from the group consisting of a B-containing layer, a C-containing layer, and a Ge-containing layer.

Methods and apparatuses for depositing superconformal dielectric material using thermal chemical vapor deposition-enhanced atomic layer deposition are provided. Methods and apparatuses for depositing material using modified atomic layer deposition integrating pyrolyzing a deposition precursor such as an aminosilane during dose to form a pyrolyzed layer, optional inert gas plasma for densification, and an oxygen-containing or nitrogen-containing plasma to convert the pyrolyzed layer into an oxygen-containing or nitrogen-containing material.

In an embodiment, a device includes: a gate structure over a substrate; a gate spacer adjacent the gate structure; a source/drain region adjacent the gate spacer; a first inter-layer dielectric (ILD) on the source/drain region, the first ILD having a first concentration of an impurity; and a second ILD on the first ILD, the second ILD having a second concentration of the impurity, the second concentration being less than the first concentration, top surfaces of the second ILD, the gate spacer, and the gate structure being coplanar; and a source/drain contact extending through the second ILD and the first ILD, the source/drain contact coupled to the source/drain region.

A semiconductor device structure is provided. The semiconductor device structure includes a plurality of nanowire structures over a fin structure, and a gate stack wrapping around the plurality of nanowire structures. The gate stack includes a first portion above the plurality of nanowire structures and second portions between the nanowire structures. The semiconductor device structure further includes a gate spacer layer along a sidewall of the first portion of the gate stack, and a plurality of inner spacer layers along sidewalls of the second portions of the gate stack. The gate spacer layer has a first carbon concentration, the inner spacer layers have a second carbon concentration, and the second carbon concentration is lower than the first carbon concentration.

In an embodiment, a device includes: a gate structure over a substrate; a gate spacer adjacent the gate structure; a source/drain region adjacent the gate spacer; a first inter-layer dielectric (ILD) on the source/drain region, the first ILD having a first concentration of an impurity; and a second ILD on the first ILD, the second ILD having a second concentration of the impurity, the second concentration being less than the first concentration, top surfaces of the second ILD, the gate spacer, and the gate structure being coplanar; and a source/drain contact extending through the second ILD and the first ILD, the source/drain contact coupled to the source/drain region.

Methods and apparatus for forming an integrated circuit structure, comprising: delivering a process gas to a process volume of a process chamber; applying low frequency RF power to an electrode formed from a high secondary electron emission coefficient material disposed in the process volume; generating a plasma comprising ions in the process volume; bombarding the electrode with the ions to cause the electrode to emit electrons and form an electron beam; and contacting a dielectric material with the electron beam to cure the dielectric material, wherein the dielectric material is a flowable chemical vapor deposition product. In embodiments, the curing stabilizes the dielectric material by reducing the oxygen content and increasing the nitrogen content of the dielectric material.

In an embodiment, in the method for processing a workpiece including an etching target layer containing silicon oxide, a mask provided on the etching target layer, and an opening provided in the mask and exposing the etching target layer, according to the embodiment, the etching target layer is etched by removing the etching target layer for each atomic layer through repetitive execution of a sequence of generating plasma of a first processing gas containing nitrogen, forming a mixed layer containing ions included in the plasma on an atomic layer on an exposed surface of the etching target layer, generating plasma of a second processing gas containing fluorine, and removing the mixed layer by radicals included in the plasma. The plasma of the second processing gas contains the radicals that remove the mixed layer containing silicon nitride.

Embodiments described herein generally relate to methods of forming hardmask and bottom dielectric isolation layers in vertical trench structures. A method of forming a gate-all-around field-effect transistor includes depositing a conformal oxide layer on a channel surface and a bottom surface of vertical structures of a substrate, the vertical structures including an NMOS portion having NMOS vertical structures defining NMOS contact trenches and a PMOS portion having PMOS structures defining PMOS contact trenches having a PMOS source/drain layer deposited therein. The method further includes selectively etching the conformal oxide layer at the bottom surface of the vertical structures, inhibiting the conformal oxide layer, selectively depositing a nitride layer at the bottom surface of the vertical structures, etching the conformal oxide layer to expose the channel surface of the vertical structures, and depositing an NMOS source/drain layer on the bottom surface of the NMOS contact trenches.