A method for etching silicon at cryogenic temperatures is provided. The method includes forming an inert layer from condensation of a noble gas at cryogenic temperatures on exposed surfaces such as the sidewalls of a feature to passivate the sidewalls prior to the etching process. The method further includes flowing a fluorine-containing precursor gas into the chamber to form a fluorine-containing layer on the inert layer. The method further includes exposing the fluorine-containing layer and the inert layer to an energy source to form a passivation layer on the exposed portions of the substrate and exposing the substrate to ions to etch the substrate.

Processing methods disclosed herein comprise forming a nucleation layer and a flowable chemical vapor deposition (FCVD) film on a substrate surface by exposing the substrate surface to a silicon-containing precursor and a reactant. By controlling at least one of a precursor/reactant pressure ratio, a precursor/reactant flow ratio and substrate temperature formation of miniature defects is minimized. Controlling at least one of the process parameters may reduce the number of miniature defects. The FCVD film can be cured by any suitable curing process to form a smooth FCVD film.

A nitrogen plasma treatment is used on an adhesion layer of a contact plug. As a result of the nitrogen plasma treatment, nitrogen is incorporated into the adhesion layer. When a contact plug is deposited in the opening, an interlayer of a metal nitride is formed between the contact plug and the adhesion layer. A nitrogen plasma treatment is used on an opening in an insulating layer. As a result of the nitrogen plasma treatment, nitrogen is incorporated into the insulating layer at the opening. When a contact plug is deposited in the opening, an interlayer of a metal nitride is formed between the contact plug and the insulating layer.

Films are modified to include deuterium in an inductive high density plasma chamber. Chamber hardware designs enable tunability of the deuterium concentration uniformity in the film across a substrate. Manufacturing of solid state electronic devices include integrated process flows to modify a film that is substantially free of hydrogen and deuterium to include deuterium.

In a variety of processes for forming electronic devices that use spin-on dielectric materials, properties of the spin-on dielectric materials can be enhanced by curing these materials using plasma doping. For example, hardness and Young's modulus can be increased for the cured material. Other properties may be enhanced. The plasma doping to cure the spin-on dielectric materials uses a mechanism that is a combination of plasma ion implant and high energy radiation associated with the species ionized. In addition, physical properties of the spin-on dielectric materials can be modified along a length of the spin-on dielectric materials by selection of an implant energy and dopant dose for the particular dopant used, corresponding to a selection variation with respect to length.

The present disclosure provides a semiconductor device and a method of manufacturing a semiconductor device. The method of manufacturing a semiconductor device includes: providing a substrate that includes an array region and an edge region; forming a composite layer on the substrate, where the composite layer includes an amorphous silicon layer and a silicon dioxide layer, and the silicon dioxide layer is located on a surface of the amorphous silicon layer away from the substrate; dry etching the silicon dioxide layer in the array region by using first plasma, to expose a part of the surface of the amorphous silicon layer in the array region; performing, by using second plasma, a plasma surface treatment on an exposed part of the surface of the amorphous silicon layer; cleaning an amorphous silicon layer on which the plasma surface treatment has been performed and a dry etched silicon dioxide layer; and coating a first photoresist layer on the composite layer in the edge region and the array region of the substrate, and performing exposing and developing.

The present disclosure provides a processing method for semiconductor surface defects and a preparation method for semiconductor devices. The processing method for semiconductor surface defects includes: placing a semiconductor device in a plasma processing device, the semiconductor device comprising a semiconductor substrate and deposition layers formed on the surface of the semiconductor substrate, bubbles being formed in the deposition layers; and plasma bombarding the surface of the deposition layer to break the bubbles, so that the surface of the deposition layer is flat.

Structures and methods of forming semiconductor devices are presented in which a void-free core-shell hard mask is formed over a gate electrode. The void-free core-shell hard mask may be formed in some embodiments by forming a first liner layer over the gate electrode, forming a void-free material over the first liner layer, recessing the void-free material, and forming a second liner over the recessed void-free material.

Methods and apparatus for forming a barrier layer are provided herein. In some embodiments, a method of forming a barrier layer on a substrate includes treating an exposed layer deposited on a substrate and within a feature of the substrate by pulsing a bias power applied to a substrate support supporting the substrate while exposing the layer to a plasma. The exposed layer can be deposited by an atomic layer deposition process, and can be, for example, a tantalum nitride layer. The bias power can be up to 500 watts of RF power at a pulse frequency of about 1 Hz to about 10 kHz. The bias power can be pulsed uniformly or at multiple different levels.

A method may include providing a substrate having, on a first surface of the substrate, a low dielectric constant layer characterized by a layer thickness. The method may include heating the substrate to a substrate temperature in a range of 200° C. to 550° C.; and directing an ion implant treatment to the low dielectric constant layer, while the substrate temperature is in the range of 200° C. to 550° C. As such, the ion implant treatment may include implanting a low weight ion species, at an ion energy generating an implant depth equal to 40% to 175% of the layer thickness.