The present invention provides a monolithic integrated lattice mismatched crystal template and a preparation method thereof by using low-viscosity material, the preparation method for the crystal template includes: providing a first crystal layer with a first lattice constant; growing a buffer layer on the first crystal layer; below the melting point of the buffer layer, growing a second crystal layer and a template layer by sequentially performing the growth process of a second crystal layer and the growth process of a first template layer on the buffer layer, or growing a template layer by directly performing a first template layer growth process on the buffer layer; melting and converting the buffer layer to an amorphous state, performing a second template layer growth process on the template layer grown by the first template layer growth process at the growth temperature above the glass transition temperature of the buffer layer, sequentially growing a template layer until the lattice of the template layer is fully relaxed. Compared to the prior art, the invention has advantages of simple preparation, achieving in various lattice constant material combinations on one substrate and low dislocation density, high crystal quality.

A method of performing HVPE heteroepitaxy comprises exposing a substrate to a carrier gas, a first precursor gas, a Group II/III element, and ternary-forming gasses (V/VI group precursor), to form a heteroepitaxial growth of a binary, ternary, and/or quaternary compound on the substrate; wherein the carrier gas is H.sub.2, wherein the first precursor gas is HCl, the Group II/III element comprises at least one of Zn, Cd, Hg, Al, Ga, and In; and wherein the ternary-forming gasses comprise at least two or more of AsH.sub.3 (arsine), PH.sub.3 (phosphine), H.sub.2Se (hydrogen selenide), H.sub.2Te (hydrogen telluride), SbH.sub.3 (hydrogen antimonide, or antimony tri-hydride, or stibine), H.sub.2S (hydrogen sulfide), NH.sub.3 (ammonia), and HF (hydrogen fluoride); flowing the carrier gas over the Group II/III element; exposing the substrate to the ternary-forming gasses in a predetermined ratio of first ternary-forming gas to second ternary-forming gas (1tf:2tf ratio); and changing the 1tf:2tf ratio over time.

A semiconductor layered structure includes a substrate formed of a III-V compound semiconductor, a buffer layer disposed on and in contact with the substrate and formed of a III-V compound semiconductor, and a quantum well layer disposed on and in contact with the buffer layer and including a plurality of component layers formed of III-V compound semiconductors. The substrate has a diameter of 55 mm or more. At least one of the component layers is formed of a mixed crystal of three or more elements. When the compound semiconductor forming the substrate has a lattice constant d.sub.1, the compound semiconductor forming the buffer layer has a lattice constant d.sub.2, and the compound semiconductors forming the quantum well layer have an average lattice constant d.sub.3, (d.sub.2d.sub.1)/d.sub.1 is 310.sup.3 or more and 310.sup.3 or less, and (d.sub.3d.sub.1)/d.sub.1 is 310.sup.3 or more and 310.sup.3 or less.

Techniques are disclosed for using a high resistance layer between a III-V channel layer and a group IV substrate for semiconducting devices, such as metal-oxide-semiconductor (MOS) transistors. The high resistance layer can be used to minimize (or eliminate) current flow from source to drain that follows a path other than directly through the channel. In some cases, the high resistance layer may be a III-V wide bandgap layer. In some such cases, the wide bandgap layer may have a bandgap greater than 1.4 electron volts (eV), and may even have a bandgap greater than 2.0 eV. In other cases, the wide bandgap layer may be partially or completely converted to an insulator through oxidation or nitridation, for example. The resulting structures may be used with planar, finned, or nanowire/nanoribbon transistor architectures to help prevent substrate leakage problems.

A monolithic integrated semiconductor structure includes: A) an Si carrier layer, B) a layer having the composition B.sub.xAl.sub.yGa.sub.zN.sub.tP.sub.v, wherein x=0-0.1, y=0-1, z=0-1, t=0-0.1 and v=0.9-1, C) a relaxation layer having the composition B.sub.xAl.sub.yGa.sub.zIn.sub.uP.sub.vSb.sub.w, wherein x=0-0.1, y=0-1, z=0-1, u=0-1, v=0-1 and w=0-1, wherein w and/or u is on the side facing toward layer A) or B) smaller than, equal to, or bigger than on the side facing away from layer A) or B) and wherein v=1w and/or y=1uxz, and D) a group III/V, semiconductor material. The sum of the above stoichiometric indices for all group III elements and for all group V elements are each equal to one.

A photovoltaic device including a single junction solar cell provided by an absorption layer of a type IV semiconductor material having a first conductivity, and an emitter layer of a type III-V semiconductor material having a second conductivity, wherein the type III-V semiconductor material has a thickness that is no greater than 50 nm.

A photovoltaic device including a single junction solar cell provided by an absorption layer of a type IV semiconductor material having a first conductivity, and an emitter layer of a type III-V semiconductor material having a second conductivity, wherein the type III-V semiconductor material has a thickness that is no greater than 50 nm.

A first III-V material based buffer layer is deposited on a silicon substrate. A second III-V material based buffer layer is deposited onto the first III-V material based buffer layer. A III-V material based device channel layer is deposited on the second III-V material based buffer layer.

An epitaxial wafer of the present invention includes a substrate composed of a III-V compound semiconductor, a multiple quantum well structure composed of a III-V compound semiconductor and located on the substrate, and a top layer composed of a III-V compound semiconductor and located on the multiple quantum well structure. The substrate has a plane orientation of (100) and an off angle of 0.030 or more and +0.030 or less, and a surface of the top layer has a root-mean-square roughness of less than 10 nm.

A first III-V material based buffer layer is deposited on a silicon substrate. A second III-V material based buffer layer is deposited onto the first III-V material based buffer layer. A III-V material based device channel layer is deposited on the second III-V material based buffer layer.