Provided are a method of producing a titanium-containing rare earth-iron-nitrogen anisotropic magnetic powder having good magnetic properties, and secondary particles for a titanium-containing anisotropic magnetic powder. The method includes: obtaining a first precipitate containing R, iron, and titanium by mixing a first precipitating agent with a solution containing R, iron, and titanium, wherein R is at least one selected from Sc, Y, Pr, Nd, Pm, Sm, Gd, Tb, Dy, Ho, Er, Tm, and Lu; obtaining a second precipitate containing R and iron by mixing, in the presence of the first precipitate, a second precipitating agent with a solution containing R and iron; obtaining an oxide containing R, iron, and titanium by calcining the second precipitate; obtaining a partial oxide by heat treating the oxide in a reducing gas atmosphere; obtaining alloy particles by reducing the partial oxide; and obtaining an anisotropic magnetic powder by nitriding the alloy particles.

A method for producing a permanent or soft magnet including the following steps: a) providing: a solution containing a solvent in which are dispersed a set of objects which possess a permanent magnetic moment; a substrate on which are fixed to the surface or within a cavity that it may have, a 1st pad and a 2nd pad, said 1st pad includes a face facing and parallel to a face that the 2nd pad includes; b) the solution is deposited on the surface of the substrate or, as the case may be, within its cavity; c) the substrate is placed in a magnetic field so that the set of objects are grouped together between the face of the 1st pad and the face of the 2nd pad so as to form a permanent magnet.

A two-step diffusion method for preparing high-performance dual-main-phase sintered mischmetal-iron-boron magnet belongs to the preparing technical field of rare earth permanent magnet materials. The compositions of the two main phase alloys are RE-Fe—B (RE is Nd or Pr) and (Nd, MM)-Fe—B (MM is mischmetal), respectively. First, PrHoFe strip-casting alloy is used as a diffusion source. Next, a PrHo-rich layer is uniformly coated on the surface of (Nd, MM)-Fe—B hydrogen decrepitation powders. The higher anisotropic fields of Pr.sub.2Fe.sub.14B and Ho.sub.2Fe.sub.14B are used to improve the coercivity. Then, the ZrCu strip-casting alloy is used as a diffusion source. A Zr-rich layer is uniformly coated on the surface of the powders after the first-step diffusion, which prevents the growth of the MM-rich main phase grains during the sintering process and the inter-diffusion between the two main phases, thus obtains high coercivity.

Compositions including hard magnetic photoresists, soft photoresists, hard magnetic elastomers and soft magnetic elastomers are provided.

An L10-FeNi magnetic powder has an average particle size of 50 nm to 1 μm, and an average value of sphericity P of 0.9 or more. The sphericity P is defined as P=Ls/Lr, where Lr is a perimeter of an L10-FeNi magnetic powder particle on an image of a microscope, and Ls is a perimeter of a perfect circle that has a same area as the L10-FeNi magnetic powder particle on the image for which Lr is calculated.

A magnetic composite includes a polymeric substrate and a magnetic material including a Z-type phase and represented by the following Chemical Formula:

Ba.sub.1.5-xSr.sub.1.5-xCa.sub.2xM.sub.2Fe.sub.24O.sub.41  Chemical Formula

wherein, in the Chemical Formula, M is at least one selected from Co, Ni, Cu, Mg, Mn, Ti, Al, Zn, and Zr, and 0≦x<0.3.

In one embodiment, a permanent magnet has a composition expressed by a composition formula: RN.sub.x(Cr.sub.pSi.sub.qM.sub.1-p-q).sub.z (R is at least one element selected from Y and rare-earth elements, M is at least one element selected from Fe and Co, and x, p, q, and z are atomic ratios satisfying 0.5≦x≦2.0, 0.005≦p≦0.2, 0.005≦q≦0.2, and 4≦z≦13, respectively). The permanent magnet has a density of 6.5 g/cm.sup.3 or more and satisfies the relationship of I(110)/{I(110)+I(303)}≦0.05, in which I(303) represents a diffraction peak intensity from a (303) plane of a Th.sub.2Zn.sub.17 phase obtained through powder X-ray diffraction of the permanent magnet, and I(110) represents a diffraction peak intensity from a (110) plane of an α-Fe phase obtained through the powder X-ray diffraction.

A method for producing a sintered R-T-B based magnet of this disclosure includes the steps of preparing a plurality of sintered R-T-B based magnet bodies (R is at least one of rare earth elements and necessarily contains Nd and/or Pr; and T is at least one of transition metals and necessarily contains Fe); preparing a plurality of alloy powder particles having a size of 90 μm or less and containing a heavy rare earth element RH (the heavy rare earth RH is Tb and/or Dy) at a content of 20 mass % or greater and 80 mass % or less; loading the plurality of sintered R-T-B based magnet bodies and the plurality of alloy powder particles of a ratio of 2% by weight or greater and 15% by weight or less with respect to the plurality of sintered R-T-B based magnet bodies into a process chamber; and heating, while rotating and/or swinging, the process chamber to move the sintered R-T-B based magnet bodies and the alloy powder particles continuously or intermittently to perform an RH supply and diffusion process.

Provided are a method of producing a titanium-containing rare earth-iron-nitrogen anisotropic magnetic powder having good magnetic properties, and secondary particles for a titanium-containing anisotropic magnetic powder. The method includes: obtaining a first precipitate containing R, iron, and titanium by mixing a first precipitating agent with a solution containing R, iron, and titanium, wherein R is at least one selected from Sc, Y, Pr, Nd, Pm, Sm, Gd, Tb, Dy, Ho, Er, Tm, and Lu; obtaining a second precipitate containing R and iron by mixing, in the presence of the first precipitate, a second precipitating agent with a solution containing R and iron; obtaining an oxide containing R, iron, and titanium by calcining the second precipitate; obtaining a partial oxide by heat treating the oxide in a reducing gas atmosphere; obtaining alloy particles by reducing the partial oxide; and obtaining an anisotropic magnetic powder by nitriding the alloy particles.

A permanent magnet includes R and T (R essentially includes Sm one or more of rare earth elements in addition to Sm, and T essentially includes Fe, or Fe and Co, one or more of transition metal elements in addition to Fe, or Fe and Co). A composition ratio of R in the permanent magnet is 20 at % or more and 40 at % or less. A remaining part is substantially only T, or only T and C. T amount is more than 1.5 times of R amount and less than 4.0 times of the R amount. Main phase grains included in the permanent magnet have an Nd5Fe17 type crystal structure. An average crystal grain size of the main phase grains of the permanent magnet is greater than 1 μm. A number ratio of main phase grains having a crystal grain size of less than 0.4 μm is less than 20%.