In one embodiment, a magnet includes a three-dimensional structure with nanoscale features, where the three-dimensional structure has a near net shape corresponding to a predefined shape.

An L10-FeNi magnetic powder has an average particle size of 50 nm to 1 m, and an average value of sphericity P of 0.9 or more. The sphericity P is defined as P=Ls/Lr, where Lr is a perimeter of an L10-FeNi magnetic powder particle on an image of a microscope, and Ls is a perimeter of a perfect circle that has a same area as the L10-FeNi magnetic powder particle on the image for which Lr is calculated.

Example nanoparticles may include an iron-based core, and a shell. The shell may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example alloy compositions may include an iron-based grain, and a grain boundary. The grain boundary may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example techniques for forming iron-based core-shell nanoparticles may include depositing a shell on an iron-based core. The depositing may include immersing the iron-based core in a salt composition for a predetermined period of time. The depositing may include milling the iron-based core with a salt composition for a predetermined period of time. Example techniques for treating a composition comprising core-shell nanoparticles may include nitriding the composition.

The flaky magnetic metal particles of the embodiments include a plurality of flaky magnetic metal particles, each of the flaky magnetic metal particles including a first magnetic particle including a flat surface, at least one first element selected from the group consisting of Fe, Co and Ni, an average ratio between the maximum length and the minimum length in the flat surface being between 1 and 5 inclusive, an average thickness of the first magnetic particles being between 10 nm and 100 m inclusive, an average aspect ratio of the first magnetic particles being between 5 and 10000 inclusive; and a plurality of second magnetic particles disposed on the flat surface, an average number of the second magnetic particles being five or more, an average diameter of the second magnetic particles being between 10 nm and 1 m inclusive.

Example nanoparticles may include an iron-based core, and a shell. The shell may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example alloy compositions may include an iron-based grain, and a grain boundary. The grain boundary may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example techniques for forming iron-based core-shell nanoparticles may include depositing a shell on an iron-based core. The depositing may include immersing the iron-based core in a salt composition for a predetermined period of time. The depositing may include milling the iron-based core with a salt composition for a predetermined period of time. Example techniques for treating a composition comprising core-shell nanoparticles may include nitriding the composition.

To provide a rare earth magnet ensuring excellent magnetic anisotropy while reducing the amount of Nd, etc., and a manufacturing method thereof.

A rare earth magnet comprising a crystal grain having an overall composition of (R2.sub.(1-x)R1.sub.x).sub.yFe.sub.100-y-w-z-vCo.sub.wB.sub.zTM.sub.v (wherein R2 is at least one of Nd, Pr, Dy and Tb, R1 is an alloy of at least one or two or more of Ce, La, Gd, Y and Sc, TM is at least one of Ga, Al, Cu, Au, Ag, Zn, In and Mn, 0<x<1, y=12 to 20, z=5.6 to 6.5, w=0 to 8, and v=0 to 2), wherein the average grain size of the crystal grain is 1,000 nm or less, the crystal grain consists of a core and an outer shell, the core has a composition of R1 that is richer than R2, and the outer shell has a composition of R2 that is richer than R1.

A method of producing a phosphate-coated SmFeN-based anisotropic magnetic powder, the method including stirring a slurry containing a raw material SmFeN-based anisotropic magnetic powder, water, a phosphate source, and an aluminum source to obtain a SmFeN-based anisotropic magnetic powder having a surface coated with a phosphate.

A method for manufacturing a raw magnet includes manufacturing a first raw form from a first magnetic base material; manufacturing a second raw form from a second magnetic base material; applying an external magnetic field to at least one raw form selected from a group consisting of the first raw form and the second raw form during and/or after manufacturing of the raw form. Wherein a third raw form is manufactured from the first raw form and the second raw form by joining them together. A separating layer is provided between a first connection surface of the first raw form and a second connection surface of the second raw form. The third raw form is sintered.

To provide a rare earth magnet ensuring excellent magnetic anisotropy while reducing the amount of Nd, etc., and a manufacturing method thereof. A rare earth magnet comprising a crystal grain having an overall composition of (R2.sub.(1-x)R1.sub.x).sub.yFe.sub.100-y-w-z-vCo.sub.wB.sub.zTM.sub.v (wherein R2 is at least one of Nd, Pr, Dy and Tb, R1 is an alloy of at least one or two or more of Ce, La, Gd, Y and Sc, TM is at least one of Ga, Al, Cu, Au, Ag, Zn, In and Mn, 0<x<1, y=12 to 20, z=5.6 to 6.5, w=0 to 8, and v=0 to 2), wherein the average grain size of the crystal grain is 1,000 nm or less, the crystal grain consists of a core and an outer shell, the core has a composition of R1 that is richer than R2, and the outer shell has a composition of R2 that is richer than R1.

A permanent magnet includes R and T (R essentially includes Sm one or more of rare earth elements in addition to Sm, and T essentially includes Fe, or Fe and Co, one or more of transition metal elements in addition to Fe, or Fe and Co). A composition ratio of R in the permanent magnet is 20 at % or more and 40 at % or less. A remaining part is substantially only T, or only T and C. T amount is more than 1.5 times of R amount and less than 4.0 times of the R amount. Main phase grains included in the permanent magnet have an Nd5Fe17 type crystal structure. An average crystal grain size of the main phase grains of the permanent magnet is greater than 1 m. A number ratio of main phase grains having a crystal grain size of less than 0.4 m is less than 20%.