The present invention provides a photocurable resin composition that has good fabricability, and that exhibits superior flexibility, fracture resistance, and water resistance in the form of a cured product. The present invention relates to a photocurable resin composition comprising: a urethanized (meth)acrylic compound (A); a mono(meth)acrylic acid ester compound (B) containing no urethane bond; and a photopolymerization initiator (C), the urethanized (meth)acrylic compound (A) being a (meth)acrylate comprising, per molecule, at least one kind of structure selected from the group consisting of a polyester, a polycarbonate, a polyurethane, a polyether, a poly-conjugated diene, and a hydrogenated poly-conjugated diene; and a urethane bond, the mono(meth)acrylic acid ester compound (B) containing no urethane bond comprising at least one selected from the group consisting of a mono(meth)acrylic acid ester compound (b-I) represented by general formula (I), and a mono(meth)acrylic acid ester compound (b-II) represented by general formula (II).

The present invention provides a photocurable resin composition that has good fabricability, and that exhibits superior flexibility, fracture resistance, and water resistance in the form of a cured product. The present invention relates to a photocurable resin composition comprising: a urethanized (meth)acrylic compound (A); a mono(meth)acrylic acid ester compound (B) containing no urethane bond; and a photopolymerization initiator (C), the urethanized (meth)acrylic compound (A) being a (meth)acrylate comprising, per molecule, at least one kind of structure selected from the group consisting of a polyester, a polycarbonate, a polyurethane, a polyether, a poly-conjugated diene, and a hydrogenated poly-conjugated diene; and a urethane bond, the mono(meth)acrylic acid ester compound (B) containing no urethane bond comprising at least one selected from the group consisting of a mono(meth)acrylic acid ester compound (b-I) represented by general formula (I), and a mono(meth)acrylic acid ester compound (b-II) represented by general formula (II).

A polymerisable radiation-curable composition comprising:

(i) monomers, comprising at least (a) a first monomer having a TG (glass-transition point) of the homopolymer of said first monomer ≥120° C. and at least (b) a second monomer having a TG (glass-transition point) of the homopolymer of the second monomer ≤100° C., wherein at least one of the at least one first monomer or of the at least one second monomer has an alicyclic group, and
comprising (ii) at least one further component, comprising at least one photo-initiator for the UV and/or Vis spectral region or a photo-initiator system for the UV and/or Vis spectral region. Also disclosed is a blank in the form of a three-dimensional moulded body of a polymerised composition, in particular a radiation-cured composition, for producing 3D moulded bodies, dental prosthetic parts, orthopaedic appliances or dental pre-forms in a rapid prototyping, rapid manufacturing, or rapid tooling method.

A polymerisable radiation-curable composition comprising:

(i) monomers, comprising at least (a) a first monomer having a TG (glass-transition point) of the homopolymer of said first monomer ≥120° C. and at least (b) a second monomer having a TG (glass-transition point) of the homopolymer of the second monomer ≤100° C., wherein at least one of the at least one first monomer or of the at least one second monomer has an alicyclic group, and
comprising (ii) at least one further component, comprising at least one photo-initiator for the UV and/or Vis spectral region or a photo-initiator system for the UV and/or Vis spectral region. Also disclosed is a blank in the form of a three-dimensional moulded body of a polymerised composition, in particular a radiation-cured composition, for producing 3D moulded bodies, dental prosthetic parts, orthopaedic appliances or dental pre-forms in a rapid prototyping, rapid manufacturing, or rapid tooling method.

A polymerisable radiation-curable, in particular UV-Vis-, UV- or Vis-curable, composition comprising: (i) monomers, wherein the monomers comprise: (a.1) at least one triacrylate derived from 1,3,5-tris(ω-hydroxyalkyl) isocyanurate, wherein the hydroxyalkyl residue comprises 1 to 8 C-atoms and may be linear, branched and/or cyclic, and (a.2) at least one di-functional monomer, not being a urethane (meth)acrylate, and (ii) at least one further component, comprising: at least one photo-initiator for the UV and/or Vis spectral region or a photo-initiator system for the UV and/or Vis spectral region. Also disclosed is a blank in the form of a three-dimensional moulded body of a polymerised composition, in particular of a radiation-cured composition for producing dental prosthetic parts, orthopaedic appliances or dental pre-forms, and also to the use of the composition for producing dental prosthetic parts, orthopaedic appliances or dental pre-forms in a rapid prototyping or in a rapid manufacturing or rapid tooling method.

A polymerisable radiation-curable, in particular UV-Vis-, UV- or Vis-curable, composition comprising: (i) monomers, wherein the monomers comprise: (a.1) at least one triacrylate derived from 1,3,5-tris(ω-hydroxyalkyl) isocyanurate, wherein the hydroxyalkyl residue comprises 1 to 8 C-atoms and may be linear, branched and/or cyclic, and (a.2) at least one di-functional monomer, not being a urethane (meth)acrylate, and (ii) at least one further component, comprising: at least one photo-initiator for the UV and/or Vis spectral region or a photo-initiator system for the UV and/or Vis spectral region. Also disclosed is a blank in the form of a three-dimensional moulded body of a polymerised composition, in particular of a radiation-cured composition for producing dental prosthetic parts, orthopaedic appliances or dental pre-forms, and also to the use of the composition for producing dental prosthetic parts, orthopaedic appliances or dental pre-forms in a rapid prototyping or in a rapid manufacturing or rapid tooling method.

The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes at least one urethane component, at least one monofunctional reactive diluent, an initiator, and optionally an inhibitor. The present disclosure also provides an article including the reaction product of the photopolymerizable composition. Further, the present disclosure provides a method of making an article. The method includes (i) providing a photopolymerizable composition and (ii) selectively curing the photopolymerizable composition to form an article. The method optionally also includes (iii) curing unpolymerized urethane component and/or reactive diluent remaining after step (ii). Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes at least one urethane component, at least one monofunctional reactive diluent, an initiator, and optionally an inhibitor. The present disclosure also provides an article including the reaction product of the photopolymerizable composition. Further, the present disclosure provides a method of making an article. The method includes (i) providing a photopolymerizable composition and (ii) selectively curing the photopolymerizable composition to form an article. The method optionally also includes (iii) curing unpolymerized urethane component and/or reactive diluent remaining after step (ii). Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes at least one urethane component, at least one monofunctional reactive diluent, an initiator, and optionally an inhibitor. The present disclosure also provides an article including the reaction product of the photopolymerizable composition. Further, the present disclosure provides a method of making an article. The method includes (i) providing a photopolymerizable composition and (ii) selectively curing the photopolymerizable composition to form an article. The method optionally also includes (iii) curing unpolymerized urethane component and/or reactive diluent remaining after step (ii). Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer. Often, the polycarbonate diol has a number average molecular weight of greater than 1,000 grams per mole (g/mol) or a weighted average of all polycarbonate diols present in the components has a Mn of greater than 1,000 g/mol; alternatively, the polyurethane methacrylate polymer has a weight average molecular weight of 8,000 g/mol or greater. An article is also provided including the photopolymerizable composition reaction product. Further, the present disclosure provides articles and methods of making articles. Methods are additionally provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.