The present invention provides a dental adhesive material kit that exhibits high adhesive property to tooth structure and dental prosthesis through photopolymerization while maintaining good ease of handling with the paste properties that undergo little change during long storage. The present invention relates to a dental adhesive material kit comprising:

an aqueous adhesive dental composition (X) comprising a radical polymerizable monomer (a) containing an acidic group, a polymerization accelerator (b), water (c), and a radical polymerizable monomer (d) containing no acidic group; and

a curable dental composition (Y) comprising a hydrophilic radical polymerizable monomer (d-1) containing no acidic group, a hydrophobic radical polymerizable monomer (d-2) containing no acidic group, a chemical polymerization initiator (e), a photopolymerization initiator (f), and a filler (g),

the filler (g) being a filler treated with a surface treatment agent, and having an average particle diameter of 0.01 to 50.0 m,

the surface treatment agent comprising a silane coupling agent (A) represented by general formula [1], and an organosilazane (B) represented by general formula [2].

The present invention provides a dental adhesive material kit that exhibits high adhesive property to tooth structure and dental prosthesis through photopolymerization while maintaining good ease of handling with the paste properties that undergo little change during long storage. The present invention relates to a dental adhesive material kit comprising:

an aqueous adhesive dental composition (X) comprising a radical polymerizable monomer (a) containing an acidic group, a polymerization accelerator (b), water (c), and a radical polymerizable monomer (d) containing no acidic group; and

a curable dental composition (Y) comprising a hydrophilic radical polymerizable monomer (d-1) containing no acidic group, a hydrophobic radical polymerizable monomer (d-2) containing no acidic group, a chemical polymerization initiator (e), a photopolymerization initiator (f), and a filler (g),

the filler (g) being a filler treated with a surface treatment agent, and having an average particle diameter of 0.01 to 50.0 m,

the surface treatment agent comprising a silane coupling agent (A) represented by general formula [1], and an organosilazane (B) represented by general formula [2].

A composition comprising microcapsules functionalized with polymerizable functional groups on the surface of said microcapsules wherein the functional groups form covalent bonds with monomers in the continuous phase to enhance the mechanical properties of the composition.

A composition comprising microcapsules functionalized with polymerizable functional groups on the surface of said microcapsules wherein the functional groups form covalent bonds with monomers in the continuous phase to enhance the mechanical properties of the composition.

A dental resin composite comprising a thermally cured composition of polymeric resin monomers and inorganic fillers that comprise at least 80 wt % total filler loading is provided. Mill blocks made from the dental resin composite and produced via free radical polymerization under high-temperature (approximately 160 C. to 220 C.) and high-pressure process (approximately 300 MPa to 560 MPa) exhibited enhanced mechanical strength and good esthetics suitable for use in CAD/CAM indirect restorations such as, inlays, onlays, crowns and bridges.

A dental resin composite comprising a thermally cured composition of polymeric resin monomers and inorganic fillers that comprise at least 80 wt % total filler loading is provided. Mill blocks made from the dental resin composite and produced via free radical polymerization under high-temperature (approximately 160 C. to 220 C.) and high-pressure process (approximately 300 MPa to 560 MPa) exhibited enhanced mechanical strength and good esthetics suitable for use in CAD/CAM indirect restorations such as, inlays, onlays, crowns and bridges.

A polymerizable monomer, a filler (A), and a filler (B) are contained, the filler (A) includes an inorganic particle and a compound covering the inorganic particle, the filler (B) includes another inorganic particle and another compound covering the other inorganic particle, and the average particle size of the filler (B) is 20% to 550% of the average particle size of the filler (A).

A polymerizable monomer, a filler (A), and a filler (B) are contained, the filler (A) includes an inorganic particle and a compound covering the inorganic particle, the filler (B) includes another inorganic particle and another compound covering the other inorganic particle, and the average particle size of the filler (B) is 20% to 550% of the average particle size of the filler (A).

The present disclosure provides an inorganic dental filler including a surface treated with at least one silane. Exemplary silanes described in the present disclosure for the surface treatment of the inorganic filler include silanes of Formula I and/or Formula II: (R.sup.Si)(CR.sup.1R.sup.2).sub.n(NHC(O)OCH.sub.2CH.sub.2).sub.qN(R.sup.5)C(O)NH(CH.sub.2CH.sub.2O).sub.tCR.sup.3R.sup.4CH.sub.2-(A) Formula I (R.sup.Si)(CR.sup.1R.sup.2).sub.nNHC(O)OCR.sup.3R.sup.4-(L).sub.q-CH.sub.2-(A) Formula II, wherein: R.sup.Si is a silane-containing group of the formula Si(Y.sub.p)(R.sup.6).sub.3-p, wherein Y is a hydrolysable group, R.sup.6 is a monovalent alkyl or aryl group, and p is 1, 2, or 3. Methods of making and using the surface treated inorganic dental fillers are also disclosed.

A composition comprising microcapsules functionalized with polymerizable functional groups on the surface of said microcapsules wherein the functional groups form covalent bonds with monomers in the continuous phase to enhance the mechanical properties of the composition.