Provided are methods, devices and systems that utilize free-surface fluidics and SERS for analyte detection with high sensitivity and specificity. The molecules can be airborne agents, including but not limited to explosives, narcotics, hazardous chemicals, or other chemical species. The free-surface fluidic architecture is created using an open microchannel, and exhibits a large surface to volume ratio. The free-surface fluidic interface can filter interferent molecules, while concentrating airborne analyte molecules. The microchannel flow enables controlled aggregation of SERS-active probe particles in the flow, thereby enhancing the detector's sensitivity.

Disclosed herein are devices and methods to provide a holographic optical element (HOE) having a modified shape and a structural attribute. At least one wavefront may be used to cause a first structure change in a material, used for the HOE, in a first shape. The material used for the HOE may be changed from the first shape to the modified shape to cause a second structure change in the material. The structural attribute in the material may be provided from a combination of the first structure change and the second structure change.

An apparatus is described that selectively absorbs electromagnetic radiation. The apparatus includes a conducting surface, a dielectric layer formed on the conducting surface, and a plurality of conducting particles distributed on the dielectric layer. The dielectric layer can be formed from a material and a thickness selected to yield a specific absorption spectrum. Alternatively, the thickness or dielectric value of the material can change in response to an external stimulus, thereby changing the absorption spectrum.

Monodisperse carboxylate functionalized gold nanoparticles comprising a capping agent layer of pamoic acid and colloidal suspensions thereof are disclosed. These gold nanoparticles have an average particle size of greater than 15 nm or less than 8 nm and demonstrate significant fluorescent properties. In addition, a method for the size controlled preparation of these monodisperse carboxylate functionalized gold nanoparticles wherein pamoic acid acts as both a reducing and capping agent and wherein the size of the particles can be controlled by the pH of the process is disclosed. In addition, a method for the size controlled preparation of these monodisperse carboxylate functionalized gold nanoparticles utilizing seed mediated growth is disclosed.

A tool system is provided for resisting abrasive wear of a ground-engaging tool of an agricultural implement during a crop production procedure. The tool system may include a tool for engaging an agricultural field while performing crop production procedure and that defines a main segment and a cutting segment having a working edge covered by a nanostructure coating. The cutting segment may include multiple wear zones with multiple working edges, respectively, covered by nanostructure coatings which may have different thicknesses.

In some embodiments, the present invention provides amphiphilic nanosheets that comprise lamellar crystals with at least two regions: a first hydrophilic region and a second hydrophobic region. In some embodiments, the amphiphilic nanosheets of the present invention also comprise a plurality of functional groups that are appended to the lamellar crystals. In some embodiments the functional groups are hydrophobic functional groups that are appended to the second region of the lamellar crystals. In some embodiments, the lamellar crystals comprise -zirconium phosphates. Additional embodiments of the present invention pertain to methods of making the aforementioned amphiphilic nanosheets. Such methods generally comprise appending one or more functional groups to a stack of lamellar crystals; and exfoliating the stack of lamellar crystals for form the amphiphilic nanosheets.

An insulation structure for an appliance includes a cabinet having an outer wrapper and an inner liner, with an insulating cavity defined therebetween. Insulating powder material is disposed substantially throughout the insulating cavity. An insulating gas is disposed within the insulating cavity, wherein the insulating powder material is combined with the insulating gas and cooperatively defines a suspended state and a precipitated state. The suspended state is defined by the insulating gas in motion and the insulating powder being in an aeolian suspension within the insulating gas while in motion. The precipitated state is defined by the insulating gas being in a deposition state and the insulating powder being precipitated from the insulating gas and deposited within the insulating cavity.

An insulation structure for an appliance includes a cabinet having an outer wrapper and an inner liner, with an insulating cavity defined therebetween. A plurality of hollow insulating organic/inorganic spheres is disposed within the insulating cavity, wherein a secondary insulating volume is defined between the plurality of hollow insulating organic/inorganic spheres and an interior surface of the cabinet. The interior surface of the cabinet defines the insulating cavity. An insulating fill material is disposed within the secondary insulating volume, wherein the insulating fill material and the plurality of hollow insulating organic/inorganic spheres define a substantially uniform insulating material.

An object is to form a hole having a desired size accurately and uniformly in a carbon nanomaterial used for a filter or the like, such as a graphene, a carbon nanotube, or a carbon nanohorn.

Provided is a method for perforating a carbon nanomaterial for forming a hole having a desired size in a carbon nanomaterial, characterized in that the carbon nanomaterial is heated and held at a low temperature in the air containing oxygen of 160 to 250 C. for a predetermined time and that a hole having a desired size is thereby formed uniformly in the carbon nanomaterial by controlling a length of heating time.

Size-controlled ultra-small iron-based metal oxide nanoparticles, nanocolloids comprising the nanoparticles, and methods of making the nanoparticles. The method for making the iron-based nanoparticles include sequential mixing of an iron(III) salt, a metal (II) salt, a carboxylic acid, an amine, and an inorganic base in water at temperatures ranging from 25-80 C. Nanoparticles in the size ranging from 2 nm to 10 nm with a narrow size distribution are obtained with the method. The nanoparticles have an iron-based core surrounded by molecules such as a panel of different carboxylates, polycarboxylates, and amines. Depending on the hydrophilicity of the carboxylates used, the functional nanoparticulate colloid can be dispersed in either organic or aqueous solvents. The nanocolloids comprise the nanoparticles in a concentration ranging from 1-10 mg/ml, and are stable for at least several months.