An apparatus is provided that receives waste and generates electrical power or thermal energy with minimal NOx emissions. A gasifier is provided that receives the waste and air to produce fuel gas for delivery to a fluidly coupled reformer. The reformer receives the fuel gas, recycled flue gas, and air to auto-thermally produce a reformed fuel gas and destroy fuel gas pollutants at a first temperature without a catalyst. A burner is fluidly coupled to the reformer and receives recycled flue gas and air to oxidize the reformed fuel gas at a second temperature that prevents nitrogen oxide formation, the second temperature being lower than the first temperature. A quench chamber is fluidly coupled to the burner and receives flue gas from the burner for quenching with recycled flue gas. A heat recovery system is fluidly coupled to the reformer, burner, and quench chamber to extract usable energy.

Systems and methods axe disclosed herein that generally involve a double pinch criterion for optimization of regenerative Rankine cycles. In some embodiments, operating variables such as bleed extraction pressure and bleed flow rate are selected such that a double pinch is obtained in a feedwater heater, thereby improving the efficiency of the Rankine cycle. In particular, a first pinch point is obtained at the onset of condensation of the bleed and a second pinch point is obtained at the exit of the bleed from the feedwater heater. The minimal approach temperature at the first pinch point can be approximately equal to the minimal approach temperature at the second pinch point. Systems that employ regenerative Rankine cycles, methods of operating such systems, and methods of optimizing the operation of such systems are disclosed herein in connection with the double pinch criterion.

A gasifier start-up method for a gasifier capable of preventing or inhibiting a temporary occurrence of black smoke when a gasifier is started-up. A gasifier start-up method for a gasifier, in which a gasifying agent and a solid carbonaceous fuel are supplied and gasified, includes a start-up burner igniting step of supplying a start-up fuel and oxygen-containing gas to a start-up burner and igniting the start-up fuel and oxygen-containing gas, under an inert atmosphere in which an inside of the gasifier around the start-up burner is filled with inert gas; and an oxygen-containing-gas supply adjusting step of adjusting the supply of the oxygen-containing gas such that combustion gas obtained after the combustion reaction of the start-up fuel and the oxygen-containing gas becomes the inert gas, which contains little oxygen.

A system and method for the simultaneous sequestration of CO2, production of hydrogen, and production of electricity at any iron and steel industries is described. In one illustrative example, the raw materials particularly used in a blast furnace can also be used for locking CO2 gas in the form of siderite. Siderite, thus formed, can be decomposed to generate pure CO2 gas. Eventually, the generated pure CO2 gas can be sequestered underground, sold or used for oil gas recovery or for other applications.

The present invention demonstrates a solid fuel grade gasification-combustion dual bed poly-generation system, comprising a combustion system, a gasification system, a synthesized gas cooling and purifying system and a synthesized gas methanization system. The combustion system is connected with the gasification system through a circulating material return system. The gasification system mainly adapts the circulating fluidized-bed combustion mode. The gasification system adapts the fluidized-bed incomplete gasification method and the generated semi-coke is returned to the combustion system for re-utilization. The synthesized gas purifying and cooling unit adapts water cycling and combustible recycling. The by-products, CO.sub.2 and steam, in the methanization unit can be recovered, so the maximum utilization rate of energy in this system is realized.

A CO shift catalyst according to the present invention reforms carbon monoxide (CO) in gas. The CO shift catalyst has one of molybdenum (Mo) or iron (Fe) as a main component and has an active ingredient having one of nickel (Ni) or ruthenium (Ru) as an accessory component and one or two or more kinds of oxides from among titanium (Ti), zirconium (Zr), and cerium (Ce) for supporting the active ingredient as a support. The temperature at the time of manufacturing and firing the catalyst is equal to or higher than 550° C.

The present disclosure provides a method for preparing hydrogen-rich gas by solid organics. For example, solid organic raw materials are heated in a pyrolysis reaction device to perform pyrolysis reaction, and gaseous product generated from the pyrolysis reaction performs gasification with steam in a moving bed gasification reaction device to generate hydrogen-rich product. The present disclosure also provides a system for preparing hydrogen-rich gas by solid organics, and the system may include a solid heat carrier grading-dedusting device; a pyrolysis reaction device; a moving bed gasification reaction device; and a riser and combustion reactor. The present disclosure may operate at atmospheric pressure, and the technology is simple and suitable for the gasification and co-gasification of various high-volatile solid organics, such as raw materials containing a relatively large amount of moisture, mineral substance, and sulfur content.

The present invention provides integrated bunker storage systems for waste streams based on the composition and characteristics of waste stream. In particular, the present invention provides a process for generating individual waste streams based on a set of material characteristics. According to the system and method of the present invention, individual waste streams from wastes stored in bunkers are mixed in a given feed ratio to generate a food stock that will produce a desired output from a chemical conversion process, e.g., gasification. Optionally, composition data regarding the fed stock can be certified to a third party.

A temperature measurement system for a gasifier may employ a first stage gasifier with a refractory wall that defines a first stage gasifier volume. A protruding refractory brick may protrude from the first stage refractory wall and into a gaseous flow path of the first stage gasifier volume. The temperature sensor may reside completely through the refractory wall, which may be a plurality of brick layers, except for a tip end of a temperature sensor that may reside in a blind or non-through hole within the protruding refractory brick. The protruding refractory brick protrudes beyond a normal wall surface of the plurality of brick layers that defines the first stage gasifier volume. The protruding refractory brick may have a face that forms an angle that is not 90 degrees, such as 45 degrees, relative to the gaseous flow path of the fluid stream through the first stage gasifier volume.

This powder transport device comprises: transport pipe (11) that can transport powder by way of gravity by having a prescribed angle of inclination; a porous plate (12) that is disposed along the transport pipe (11) so as to divide a line cross section into a top section and bottom section and form a powder line (11d) in the top section; an inert gas supply line for fluidization (13) that is provided under the porous plate (12) and supplies an assist gas (g) to the powder line (11d) through the porous plate (12); and a deposit status monitoring device (20) that constantly monitors the state of the powder deposited on the top face side of the porous plate (12) in the powder line (11d).