A process for the production of sponge iron and a system for the production of sponge iron. The process includes the steps of: producing electrolytic hydrogen and oxygen by electrolysis of water; producing methanol by reacting the electrolytic hydrogen with carbon dioxide; storing the methanol; reforming the methanol using water and/or oxygen to provide carbon dioxide and released hydrogen; providing the released hydrogen as a component portion of a reducing gas to a direct reduction shaft; and reducing iron ore in the direct reduction shaft using the reducing gas to produce the sponge iron.

The present invention relates to a method and apparatus for producing reduced iron from ironmaking dust which contains iron oxide which is generated at an ironmaking plant, takes note of the rotary kiln reduction method which does not require pretreatment of the dust, and has as its problem the pursuit of facilities which achieve further improvement of heat efficiency and stable operation.

To solve this problem, the present invention is characterized by heating and reducing carbon-containing shaped materials in a single closed space in which an internal heat type rotary kiln and an external heat type rotary kiln are arranged in series and including at least the insides of the two rotary kilns during which making the reduced exhaust gas which is generated at the external heat type rotary kiln burn inside of the internal heat type rotary kiln.

A method for producing reduced iron that produces reduced iron by reducing iron oxide charged in a shaft furnace, in which a gas mixture which contains a reducing gas and a nitrogen gas, and has a predetermined temperature, is blown into the shaft furnace. The reducing gas contains 90 volume% or more of a hydrogen gas.

A method for producing reduced iron that produces reduced iron by reducing iron oxide charged in a shaft furnace, in which a heated gas mixture which contains a reducing gas and a nitrogen gas, the reducing gas containing 90 volume % or more of a hydrogen gas, is blown into the shaft furnace from a tuyere equipped at a lower portion of a reduction zone of the shaft furnace, at least part of the reducing gas is blown into a cooling zone of the reduced iron provided at a lower portion of the shaft furnace at normal temperature, and the reducing gas that has flowed up in the cooling zone is used for reduction of the iron oxide.

In a process and apparatus for the reduction of metal oxides to form metalized material by contact with hot reducing gas, which is produced at least partially by catalytic reformation of a mixture of—a gas containing carbon dioxide (CO.sub.2) and/or steam (H.sub.2O) with—gaseous hydrocarbons, the fuel gas for burners which provide the heat for the endothermal reformation processes which take place during the reformation is obtained at least partially from a partial quantity of the top gas produced during the reduction of metal oxides to form metalized material, wherein this partial quantity of the top gas, before it is used as a component of the fuel gas, is firstly subjected to dedusting and then to a CO conversion reaction, and the conversion gas obtained during the CO conversion reaction is subjected to CO.sub.2 removal after cooling.

A method for producing steel in which iron ore is reduced with hydrogen and the resulting intermediate product of reduced iron ore is subjected to further metallurgical processing; the hydrogen is produced through electrolysis of water; the electrical energy required for the electrolysis is regenerative energy from hydroelectric, wind, and/or photovoltaic sources and the hydrogen and/or the intermediate product is produced regardless of demand, whenever enough regeneratively produced electrical energy is available; and unneeded intermediate product is stored until there is demand or it is used so that the regenerative energy that is stored therein is also stored; and using a calculation model to calculate a required discharge rate in a reduction shaft to achieve a desired metallization grade of the steel by tracing batches of the iron ore in the reduction shaft, and using the calculation model to calculate the amount of carbon-containing gas or hydrogen-containing gas to add to the hydrogen for the reduction.

A method for mitigating the buildup of direct reduced iron (DRI) clusters on the walls of a direct reduction (DR) furnace, comprising: injecting one or more of lime, dolomite, and another anti-sticking agent into a charge disposed within a reduction zone of the DR furnace, wherein the one or more of lime, dolomite, and another anti-sticking agent is injected into the charge by one or more of: (1) injecting the one or more of lime, dolomite, and another anti-sticking agent into a bustle gas stream upstream of a bustle of the DR furnace; (2) injecting the one or more of lime, dolomite, and another anti-sticking agent into the bustle gas stream in the bustle of the DR furnace; (3) injecting the one or more of lime, dolomite, and another anti-sticking agent into the bustle gas stream through a pipe collocated with a bustle gas port through which the bustle gas stream is introduced into the DR furnace; and (4) injecting the one or more of lime, dolomite, and another anti-sticking agent directly into the reduction zone of the DR furnace separate from the bustle gas stream.

Direct reduction process and plant for producing DRI comprising a reduction reactor and at least one reducing gas heater typically comprising a convective heating section and a radiant heating section for raising the reducing gas temperature to a level adequate for iron oxides reduction to metallic iron, typically above 850° C., wherein the reducing gas fed to the reduction reactor comprises a stream of reducing gas recycled from the reduction reactor and a make-up stream of coke oven gas containing carbon compounds which may form carbon deposits in the heating path of said heater, namely BTX and other complex carbon compounds. The heater is provided with means for feeding oxidizing agents, for example steam, steam and air and/or oxygen at predetermined heating tubes successively for eliminating the carbon deposits which may form inside the heating tubes of said heater without interrupting the operation of the plant. The make-up stream of cold COG can be combined with the recycled gas at a point in the gas heating path of the heater where the tubes have a skin wall temperature of at least 700° C., or when the mixture of recycled gas and COG is at a temperature above 700° C. for minimizing clogging or fouling of heating equipment.

A method and a device for reducing iron-oxide-containing feedstocks, in which a reducing gas is fed to a reducing unit (1) containing the iron-oxide-containing feedstocks. The reducing gas is generated by introducing a process gas having reduction potential into a heating appliance (3) for heating the process gas, which is withdrawn as reducing gas therefrom. In the heating appliance (3), heat energy is transferred to the process gas. The heat energy is formed by combustion of a fuel gas containing organic substances, including coke oven gas with addition of technically pure oxygen. The flames of the combustion have an adiabatic flame temperature of above 1000° C., wherein, in the combustion of the fuel gas, at least some of the organic substances present in the fuel gas are cracked.

A method of starting a molten bath-based process for smelting a metalliferous material is disclosed. The method includes using the heat flux of water-cooled elements in lower parts of a smelting vessel to provide an indication of molten bath temperature during at least an early part of the start-up method and adjusting injection rates of oxygen-containing gas and/or carbonaceous material into the smelting vessel to control the molten bath temperature during start-up without exceeding critical heat flux levels and tripping the start-up method.