In alternative embodiments, provided are products of manufacture such as medical or dental devices, e.g., bone implants, having zinc phosphate (ZnP) coatings prepared on zinc (Zn), magnesium (Mg), and iron (Fe) based biodegradable metals and other non-biodegradable substrates, e.g., stainless steel, titanium and its alloys, cobalt-chrome alloys, nickel titanium alloys, to improve surface biocompatibility and provide antibacterial properties, and to enhance vascularization, and methods of making and using them. In alternative embodiments, also provided are methods to form ZnP coatings, including ZnP coatings with a porous surface, on metal surfaces such as zinc surfaces, and Zn-, Mg-, and Fe-based biodegradable metals, and other non-biodegradable substrates.

A steel part includes a steel sheet substrate and a coating on at least one surface of the steel sheet substrate. The coating includes between 0.2 and 0.7% by weight of Al, with a remainder of the metal coating being Zn and inevitable impurities. The steel sheet substrate and the coating have at least one deformation. An outer surface of the coating has a waviness Wa.sub.0.8 of less than or equal to 0.43 m.

A peening method which can sufficiently improve fatigue properties of a lap fillet welded joint having a thin steel sheet as a base sheet, in which a knocking pin having a predetermined shape is continuously knocked as a series of knocking toward a direction inclined relative to the welding direction, the series of knocking is repeatedly performed in the welding direction, at that time, a knocking mark group made of a plurality of knocking marks formed by the series of knocking is superimposed on at least a part of an adjacent knocking mark group while an end part in the direction orthogonal to the welding direction of the knocking mark group is separated from an end part in the direction orthogonal to the welding direction of the adjacent knocking mark group.

A steel sheet for cans has, on the surface thereof, in order from the steel sheet side, a chromium metal layer and a hydrous chromium oxide layer. The chromium metal layer is deposited in an amount of 65-200 mg/m.sup.2, and the hydrous chromium oxide layer is deposited in an amount of 3-15 mg/m.sup.2 in terms of chromium. The chromium metal layer includes: a flat chromium metal layer that has a thickness of at least 7 nm; and a granular chromium metal layer that includes granular protrusions that are formed on the surface of the flat chromium metal layer. The maximum grain size of the granular protrusions is 100 nm or smaller. The number density of the granular protrusions per unit area is 10/m.sup.2 or higher.

The present invention provides a method for manufacturing a metal sheet. In this method, at least one of the following equations is satisfied: $\begin{array}{cc}\frac{Z}{d}+18\ln \left(\frac{Z}{d}\right)<8\ln \left(\frac{P}{V}\right)-27.52& \left(A\right)\\ f{O}_2<\frac{2.304.Math.{10}^{-3}}{{(27.52+\frac{Z}{d}+8\ln (}^{}}\end{array}$

A surface-treated steel sheet for fuel tanks, including a ZnNi alloy plating layer on one surface or both surfaces of a steel sheet; and a trivalent chromate covering layer or a chromate-free covering layer on the ZnNi alloy plating layer, wherein, in a surface outermost layer of the trivalent chromate covering layer or the chromate-free covering layer, concavities, of which a depth from an arithmetic average height of a cross-sectional curve of the surface outermost layer is more than or equal to 0.1 m, exist in a proportion of 50 to 1000 concavities/mm2 and at an area ratio of 20 to 80% to a surface area of the steel sheet.

A metallic material that includes a base material; and a surface layer formed on a surface of the base material and exposed on an outermost surface, wherein the surface layer contains Ag, and In less than the Ag in atomic ratio, and a connection terminal being made of the metallic material, wherein the surface layer is formed on a surface of the base material, at least in a contact portion electrically contacting an opposite electrically conductive member.

Provided is a steel sheet for a hot press formed member having excellent coating adhesion, and a method for manufacturing the same. A steel sheet for hot press forming is an aluminum alloy plated steel sheet, wherein an average Fe content in a plating layer may be 40 wt % or more, and a concentration gradient of a section having a Fe content of 45 wt % to 80 wt % in the plating layer may 7 wt %/m or less of a concentration gradient at a section having an Fe content of 45% to 80% in the plating layer in a thickness direction from a surface of the plating layer according to a result of GDS analysis.

A method of manufacturing a hot dip coated steel strip, wherein coating takes place by leading the strip through a bath of molten metal including Al, the remainder of the metal being Zn, inevitable impurities and optionally a maximum of 0.3% of one or more additional elements, wherein the composition of the bath is controlled so as to have an aluminium content of more than 0.50%.

A grain-oriented electrical steel sheet comprising a steel sheet having a surface on which grooves, in which an extending direction crosses a rolling direction and a depth direction is parallel to a sheet thickness direction, are formed, and wherein a molten solidified substance ranging in parallel to the groove exists on both sides of the groove on the surface of the steel sheet, and a height becoming a maximum frequency in a height distribution of height data in which the surface of the steel sheet in a specific area including the groove is measured at regular intervals is set as a virtual plane, and a value of V2/V1 is more than 0.10 and less than 0.80, wherein V1 is a space volume of recess parts recessed from the virtual plane and V2 is a volume of projection parts projected from the virtual plane.