The present invention provides a heat shrinkable multilayer film which has excellent adhesiveness between front and back layers and an interlayer not only at normal temperature but also at low temperature to effectively prevent delamination and is less likely to have residual white streaks along creases. The present invention also provides a heat shrinkable label including the heat shrinkable multilayer film. The present invention relates to a heat shrinkable multilayer film including: front and back layers each containing a polyester resin; an interlayer containing a polystyrene resin; and adhesive layers, the front and back layers and the interlayer being stacked with the adhesive layers interposed therebetween, the adhesive layers each containing 20 to 65% by weight of a polystyrene resin and 35 to 80% by weight of a polyester elastomer.

An automotive assembly line tool system and method utilizing a heat-shrinkable bumper disposed around a portion of an assembly line tool for absorbing kinetic energy between the portion of the tool and a work-piece on an assembly line. The bumper may be a chemically cross-linked polyolefin heat-shrinkable material having a shore D hardness of 42 or less after being heat-shrunk. The bumper may be a tubular bumper that has a continuous outer surface around its circumference and a heavy wall that is highly split-resistant. The bumper may have a life term of at least one year in an automotive assembly line environment. By protecting the tools and equipment, chips and scratches on a work-piece on the assembly line may be reduced.

A heat shrink tubing, which can be readily peeled in the longitudinal direction after use (e.g., to remove the heat shrink tubing from an underlying material) is provided herein. The heat shrink tubing can be of various compositions, and generally is produced from at least one fluorinated, copolymeric resin. The tubing can exhibit desirable physical properties such as good optical clarity (e.g., translucency or transparency) and/or peelability, exhibiting one or more of complete, straight, and even peeling along a given length of tubing.

The present subject matter provides an adhesive article having a release agent or liner that is free of silicon-containing and fluorine-containing material, and related methods of adhering a backing material of the adhesive article to a substrate. The adhesive article utilizes an amorphous polyvinyl alcohol layer that facilitates removal of an optional release liner from an adhesive layer. Upon removal of the release liner, the amorphous polyvinyl alcohol layer remains disposed on the adhesive layer. A method of adhering the backing material to a substrate includes dissolving the amorphous polyvinyl alcohol layer and disposing the backing material to a substrate. During dissolution of the amorphous polyvinyl alcohol layer, a weak, temporary bond is formed between the substrate and the backing material. When the amorphous polyvinyl alcohol layer substantially dissolves and dries, the adhesive layer is exposed and forms a permanent bond with the substrate.

The invention provides a polyester sealant film having at least one of a heat sealing layer and a heat resistant layer, wherein each layer consists of a polyester component containing ethylene terephthalate. The polyester sealant film has (1) a heat sealing strength of the heat sealing layers of 8-20 N/15 mm; (2) a difference in reversible heat capacity (Cp) for the heat sealing layer of 0.5-1.1 J/g/K; (3) a Cp for the heat resistant layer of 0.1 to less than 0.6 J/g/K; (4) a fold holding angle of 20-60 degrees; (5) a smaller curvature radius of 50-300 mm in a longitudinal or widthwise direction; and (6) a heat shrinkage ratio of 5% to 5% in both longitudinal and widthwise directions. The invention also provides a laminate comprising at least one layer of the polyester sealant and a packaging bag comprising the laminate.

The present subject matter provides a shrink film free of silicon-containing material, fluorine-containing material, and solvent-formed seams. The shrink film utilizes a water soluble layer covering an adhesive layer. The water soluble layer is in dry form and non-tacky, allowing processing of the shrink film subsequent to adhesive application to the shrink film. When the water soluble layer is dissolved, the adhesive layer is exposed and is capable of forming a permanent bond. The adhesive can be used to form a seam in the film and/or can be used to form a bond between the film and a substrate. The water soluble layer facilitates removal of an optional release liner from the adhesive. A substrate with the shrink film attached thereto and a related method of attaching a heat shrinkable film to a substrate are also disclosed.

The present subject matter provides a shrink film free of silicon-containing material, fluorine-containing material, and solvent-formed seams. The shrink film utilizes a water soluble layer covering an adhesive layer. The water soluble layer is in dry form and non-tacky, allowing processing of the shrink film subsequent to adhesive application to the shrink film. When the water soluble layer is dissolved, the adhesive layer is exposed and is capable of forming a permanent bond. The adhesive can be used to form a seam in the film and/or can be used to form a bond between the film and a substrate. The water soluble layer facilitates removal of an optional release liner from the adhesive. A substrate with the shrink film attached thereto and a related method of attaching a heat shrinkable film to a substrate are also disclosed.

Disclosed is a heat-shrinkable polyester film having a heat shrinkage initiation temperature of 60 C. or lower, a glass transition temperature (Tg) of 77 C. or lower and a heat shrinkage rate of 2% or more at 60 C. which has relatively low glass transition temperature and heat shrinkage initiation temperature, and thus can be useful as a label for a high-density polyethylene (HDPE) container and the like.

The invention has for its object to provide a heat-shrinkable laminated film for deep drawing, which has an increased carbon dioxide transmission rate (CO.sub.2TR) and an enhanced ratio (CO.sub.2TR/O.sub.2TR) of carbon dioxide transmission rate-to-oxygen transmission rate (O.sub.2TR), and is less susceptible to pinholes. In the inventive heat-shrinkable laminated film for deep drawing, a polyamide resin composition layer (a) containing a polyamide resin mixture comprising 60 to 95% by mass of an aliphatic polyamide resin (A) and 5 to 40% by mass of a polyamide base resin (B) having a heat of crystalline fusion of 5 to 40 J/g is laminated onto a heat-sealing resin layer (a) containing a polyolefin resin via an adhesive resin layer (b).

A packaging article has tear initiators for initiating a manual tear that can be propagated to open a package and allow a product to be readily removed therefrom, without the use of a knife or scissors or any other implement. The packaging article is made from a heat-shrinkable multilayer film having at least one layer containing an incompatible polymer blend, and/or a layer containing an inorganic filler, and/or a layer having a high Young's modulus. The film also has a Peak Load Impact Strength of at least 50 Newtons per mil, The tear initiators can be used to generate a manual machine direction tears to open the package, with the manual machine direction tear being capable of propagating in the machine direction to the opposite edge of the packaging article. A process for making a package and manually opening the package is also disclosed.