The laminate according to the invention is a multiple layer structure and contains predominantly urethane-based polymeric materials in the cap and base layers thereof, with no significant amount of PVC. As such, under combustion conditions, the laminate releases substantially no harmful halogen-based bases, such as HCl or other toxic gases, and exhibits toxicity and smoke generation parameters well below acceptable industry standards.

A compressible substrate coated at least in part with a waterborne coating composition comprising at least one base neutralized active hydrogen containing film-forming resin and a water dispersible carbodiimide crosslinker capable of reacting with the film-forming resin to form a crosslinked film is disclosed. An article of manufacture having at least two different flexible substrates coated at least in part with such a coating is also disclosed.

Proposed is a paint protection film with excellent self-healing ability, stain resistance, and weather resistance. When being applied to vehicles, damage to the painted surface, such as chipping, scratches, and the like occurring in the middle of driving, can be effectively prevented. In addition, even when exposed to the external environment for a long period of time, the transparency of the film can be maintained. Furthermore, discoloration or stains caused by contaminants can be prevented, thereby maintaining aesthetics.