A calcium-magnesium-alumino-silicate (CMAS)-reactive thermal barrier coating includes a ceramic coating and a CMAS-reactive overlay coating, wherein the CMAS-reactive overlay coating conforms to a surface of the ceramic coating and comprises a compound that forms a stable high melting point crystalline precipitate when reacted with molten CMAS at a rate that is competitive with CMAS infiltration kinetics into the thermal barrier coating. The ceramic coating phase is stable with the CMAS-reactive overlay coating.

A steel sheet for containers including a steel sheet, a Sn coated layer that is formed on at least one surface of the steel sheet, and a chemical treatment layer that is formed on the Sn coated layer. A variation amount in a yellowness index measured at one measurement point on the outermost surface of the chemical treatment layer is defined as YI, and represented by YI=YIYI.sub.0, wherein YI is the yellowness index measured after the steel sheet for containers is subjected to a retort treatment at a temperature of 130 C. for 5 hours, and YI.sub.0 is the yellowness index measured before the retort treatment. An average of absolute values of the YI obtained at a plurality of measurement points included in a unit area of the outermost surface is 5.0 or less.

A metal foil for electromagnetic shielding, comprising: a metal foil base having a thickness of exceeding 4 m, an alloy layer having an A element configured of Sn or In and a B element group selected from the group consisting of one or more of Ag, Ni, Fe and Co formed on one or both surfaces of the base, and an underlayer having the B element group formed between the alloy layer and the base, wherein an adhesion amount of the A element is 10 to 300 mol/dm.sup.2, and a total adhesion amount of the B element group is 40 to 900 mol/dm.sup.2.

A plated steel sheet for hot stamping including a base metal and a galvanized layer that is formed on a surface of the base metal, wherein the galvanized layer includes a galvannealed layer, a solidified zinc layer, and an oxide layer containing Al, in this order from the base metal, and a proportion of a content of Zn (g/m.sup.2) in the solidified zinc layer to a content of Zn (g/m.sup.2) in the galvanized layer is 10 to 95%.

An FeCoAl alloy magnetic thin film contains, in terms of atomic ratio, 20% to 30% Co and 1.5% to 2.5% Al. The FeCoAl alloy magnetic thin film has a crystallographic orientation such that the (100) plane is parallel to a substrate surface and the <100> direction is perpendicular to the substrate surface. The FeCoAl alloy magnetic thin film has good magnetic properties, that is, a magnetization of 1440 emu/cc or more, a coercive force of less than 100 Oe, a damping factor of less than 0.01, and an FMR linewidth H at 30 GHz of less than 70 Oe.

A thermal barrier coating includes a highly porous layer and a dense layer. The highly porous layer is formed on a heat-resistant base, is made of ceramic, has pores, has a layer thickness of equal to or larger than 0.3 mm and equal to or smaller than 1.0 mm, and has a pore ratio of equal to or higher than 1 vol % and equal to or lower than 30 vol %. The dense layer is formed on the highly porous layer, is made of ceramic, has a pore ratio of equal to or lower than 0.9 vol % that is equal to or lower than the pore ratio of the highly porous layer, and has a layer thickness of equal to or smaller than 0.05 mm.

A calcium-magnesium-alumino-silicate (CMAS)-reactive thermal barrier coating includes a ceramic coating and a CMAS-reactive overlay coating, wherein the CMAS-reactive overlay coating conforms to a surface of the ceramic coating and comprises a compound that forms a stable high melting point crystalline precipitate when reacted with molten CMAS at a rate that is competitive with CMAS infiltration kinetics into the thermal barrier coating. The ceramic coating phase is stable with the CMAS-reactive overlay coating.

In alternative embodiments, provided are products of manufacture such as medical or dental devices, e.g., bone implants, having zinc phosphate (ZnP) coatings prepared on zinc (Zn), magnesium (Mg), and iron (Fe) based biodegradable metals and other non-biodegradable substrates, e.g., stainless steel, titanium and its alloys, cobalt-chrome alloys, nickel titanium alloys, to improve surface biocompatibility and provide antibacterial properties, and to enhance vascularization, and methods of making and using them. In alternative embodiments, also provided are methods to form ZnP coatings, including ZnP coatings with a porous surface, on metal surfaces such as zinc surfaces, and Zn-, Mg-, and Fe-based biodegradable metals, and other non-biodegradable substrates.

To protect a superalloy substrate from oxidation and hot corrosion, disclosed herein is coating made by a process that deposits successive layers on the substrate, a first layer of aluminium and of at least one element capable of being alloyed with sulphur, and a second layer of a material that isolates the at least one element capable of being alloyed with sulphur.

A flat steel product for hot forming may be produced from a steel substrate that includes a steel comprising 0.1-3% by weight Mn and up to 0.01% by weight B, along with a protective coating that is applied to the steel substrate. The protective coating may be based on Al and may contain up to 20% by weight of other alloy elements. Also disclosed are methods for producing such flat steel products, steel components, and methods for producing steel components. Absorption of hydrogen is minimized during heating necessary for hot forming. This is achieved at least in part through an alloy constituent of 0.1-0.5% by weight of at least one alkaline earth or transition metal in the protective coating, wherein an oxide of the alkaline earth or transition metal is formed on an outer surface of the protective coating during hot forming of the flat steel product.