A method of making a metallic alloy, more particularly, a high-entropy alloy with a composite structure that exhibits high strength and good ductility, and is used as a component material in electromagnetic, chemical, shipbuilding, machinery, and other applications, and in extreme environments, and the like.

A coated metallic substrate is provided, including, at least; one layer of oxides, such layer being directly topped by an intermediate coating layer comprising Fe, Ni, Cr and Ti wherein the amount of Ti is above or equal to 5 wt. % and wherein the following equation is satisfied: 8 wt. %<Cr+Ti<40 wt. %, the balance being Fe and Ni, such intermediate coating layer being directly topped by a coating layer being an anticorrosion metallic coating.

The Cu core ball contains a Cu ball and one or more metal layer for covering a surface of the Cu ball, each layer including one or more element selected from Ni, Co, Fe and Pd. The Cu ball contains at least one element selected from Fe, Ag, and Ni in a total amount of 5.0 or more to 50.0 ppm by mass or lower, S in an amount of 0 ppm by mass or more to 1.0 ppm by mass or lower, P in an amount of 0 ppm by mass or more to less than 3.0 ppm by mass, and remainder of Cu and inevitable impurities. The Cu ball contains purity which is 99.995% by mass or higher and 99.9995% or lower, sphericity which is 0.95 or higher and a diameter of 1 m or more to 1000 m or lower.

Provided is a ZnNi electroplated steel sheet having excellent corrosion resistance and formability and a manufacturing method therefor. The steel sheet includes: abase steel sheet; and a ZnNi plated layer formed on the base steel sheet, wherein a Ni alloying degree within the ZnNi plated layer is 7.5-14%, and the Ni amount is 40-50 atom % in a region within 1 pm toward the ZnNi plated layer from an interface of the base steel sheet and the ZnNi plated layer. Provided is a ZnNi electroplated steel sheet, which has superior corrosion resistance and formability despite having a relatively low nickel alloying degree, has excellent price competitiveness compared with that of a conventional ZnNi plated steel sheet and two-layer plated steel sheet, and can ensure high productivity.

A method of applying a protective coating to an article comprises the steps of a) depositing aluminum in a surface region of an article, and b) depositing chromium is the surface region of the article subsequent to step a), whereby at least a portion of the chromium replaces at least a portion of the aluminum. Another method and an article are also disclosed.

A steel sheet for a container includes: a steel sheet; a coated layer containing Ni provided as an upper layer of the steel sheet; and a chemical treatment layer as an upper layer of the coated layer, and containing a Zr compound in an amount of 3.0 to 30.0 mg/m.sup.2 in terms of Zr metal, and a Mg compound in an amount of 0.50 to 5.00 mg/m.sup.2 in terms of Mg metal, in which the coated layer is one of: a Ni coated layer which contains Ni in amount of 10 to 1000 mg/m.sup.2 in terms of Ni metal, and a composite coated layer which contains Ni in an amount of 5 to 150 mg/m.sup.2 in terms of Ni metal and Sn in an amount of 300 to 3000 mg/m.sup.2 in terms of Sn metal, and has an island-shaped Sn coated layer formed on an FeNiSn alloy layer.

A metallic alloy, more particularly, a high-entropy alloy with a composite structure exhibits high strength and good ductility, and is used as a component material in electromagnetic, chemical, shipbuilding, machinery, and other applications, and in extreme environments, and the like.

A wire material for a canted coil spring includes a core wire composed of a steel having a pearlite structure, a copper plating layer covering the outer peripheral surface of the core wire, the copper plating layer being composed of copper or a copper alloy, and a hard layer disposed adjacent to the outer periphery of the copper plating layer, the hard layer having a higher hardness than the copper plating layer. The steel constituting the core wire contains 0.5% or more by mass and 1.0% or less by mass carbon, 0.1% or more by mass and 2.5% or less by mass silicon, and 0.3% or more by mass and 0.9% or less by mass manganese, the balance being iron and unavoidable impurities.

A steel sheet for a container includes a steel sheet, a Sn coated layer which is provided as an upper layer of the steel sheet and contains Sn in an amount of 560 to 5600 mg/m.sup.2 in terms of Sn metal, and a chemical treatment layer which is provided as an upper layer of the Sn coated layer and contains a Zr compound in an amount of 3.0 to 30.0 mg/m.sup.2 in terms of Zr metal and a Mg compound in an amount of 0.50 to 5.00 mg/m.sup.2 in terms of Mg metal.

A coating system for a surface of a superalloy component is provided. The coating system includes a MCrAlY coating on the surface of the superalloy component, where M is Ni, Fe, Co, or a combination thereof. The MCrAlY coating generally has a higher chromium content than the superalloy component. The MCrAlY coating also includes a platinum-group metal aluminide diffusion layer. The MCrAlY coating includes Re, Ta, or a mixture thereof. Methods are also provided for forming a coating system on a surface of a superalloy component.