Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided. In one version, a six-piece ball having a three-layered core and three-layered cover is formed. Preferably, the inner core is made of a thermoset rubber composition, the intermediate core layer is made of a thermoplastic composition, and the outer core layer is made of a highly neutralized polymer (HNP) composition. The cover includes inner, intermediate, and outer cover layers, wherein the outer cover is made of a composition comprising a polyurethane, polyurea, or copolymer or blend thereof. In a second version, a five-piece ball having a two-layered core and three-layered cover is produced. The finished balls have high resiliency and rebounding properties.

Multi-layered golf balls having at least one layer made from silicone (polysiloxane) elastomers; silicone (polysiloxane) elastomer/polyurethane blends; polycarbonate-polysiloxane blends and copolymers; and polycarbonate-polysiloxane/polyurethane blends are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The polysiloxane compositions have good thermal stability and durability without sacrificing resiliency. The polysiloxane compositions also have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

Multi-layered golf ball core sub-assemblies and the resulting golf balls are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The intermediate and outer core layers are preferably formed from foamed and non-foamed thermoset compositions. For example, the intermediate core can be formed from a thermoset rubber so there are adjoining foam core layers (inner and intermediate) and the outer core layer can be formed from a non-foamed thermoset rubber. The core layers have different hardness and specific gravity levels. The core assembly preferably has a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency.

Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

Golf ball comprising a positive hardness gradient core and an outer cover layer having a microhardness gradient and being formed from a thermoset polyurethane material throughout, and having: i) a treated region that is contacted with a thermoset polyurethane microhardness-increasing solution consisting of an isocyanate portion and at least one non-aqueous solvent; and ii) an untreated region that is not contacted with the thermoset polyurethane microhardness-increasing solution. The treated region comprises the isocyanate portion, whereas the untreated region does not comprise the isocyanate portion. Treated region has a microhardness M.sub.1 that is greater than microhardness M.sub.2 of untreated region to define the outer cover layer positive microhardness gradient M=M.sub.1M.sub.2. The treated region may have a depth Dtr that extends inward from the cover outer surface and in some embodiments is less than a thickness of the untreated region. Treated region may alternatively extend from the inner surface toward outer surface.

A golf ball includes an inner core layer having a first surface hardness and a geometric center hardness. The center hardness is less than the first surface hardness to define a first positive hardness gradient of about 1 to 12 Shore C. An outer core layer has a second surface hardness. A cover layer is formed over the outer core layer. The second outer surface hardness is greater than the geometric center hardness to define a second positive hardness gradient of about 12 to 22 Shore C.

In a golf ball having a rubber core of at least one layer and a cover of at least one layer encasing the core, at least one layer of the cover is formed of a resin composition that includes (I) a polyurethane or a polyurea and (II) a (meth)acrylic block copolymer, and the CS1 value calculated by formula (1) below

[00001]$\begin{array}{cc}{\mathrm{CS}}_1=\left({\mathrm{CV}}_{50}-{\mathrm{CV}}_{12}\right)/38& \left(1\right)\end{array}$

(wherein CV.sub.50 is the coefficient of restitution at an incident velocity of 50.0 m/s and CV.sub.12 is the coefficient of restitution at an incident velocity of 12.0 m/s) is larger than ?4.08?10.sup.?3. The golf ball has an excellent controllability on approach shots and is able to maintain a good scuff resistance and moldability.

Thermoplastic and thermoset compositions including hydroxyurethane linkages, golf ball components formed using such thermoplastic or thermoset compositions, and golf balls including such golf components.

In a golf ball for professional golfers and skilled amateurs which has a single-layer core, a cover and at least one intermediate layer therebetween, the core is molded from a rubber composition that includes a base rubber, an unsaturated carboxylic acid and/or metal salt thereof, an organic peroxide and, in a specific weight ratio, water and sulfur, and has a hardness profile which satisfies certain specific conditions. The ball achieves an excellent distance on full shots with a driver (W #1) and a middle iron, and is designed for high controllability in the short game.

Disclosed herein are polyurethane/urea golf ball compositions. The compositions comprise the reaction product of a polyisocyanate prepolymer, a reactive ultraviolet light absorber, and a chain extender. Suitable reactive ultraviolet light absorbers contain at least one reactive functional end group.