A golf ball with a cover layer composed of a blend of non- or partially neutralized copolymeric or terpolymeric ionomer(s), hydroxyl-functionalized styrenic block copolymer and silane coupling agent (SCA). The amount of SCA is preferably between 0.01 and 2.0 weight percent based on the total weight of the polymer composition. The cover layer preferably has a Shore A hardness less than 90.

Golf balls having a single or dual-layered solid core are provided. In one embodiment, the golf ball has dimensions and properties that do not conform to the rules of the United States Golf Association (USGA). For example, the ball weight; ball size; ball spherical symmetry; ball initial velocity; and/or ball overall distance may fall outside of the USGA standards. The dual-layered core can have an inner core comprising a thermoplastic composition and surrounding outer core comprising a thermoset composition. In another embodiment, the dual-layered core has an inner core comprising a thermoplastic composition and outer core comprising a thermoset composition. The thermoplastic composition preferably comprises an ethylene acid copolymer ionomer and plasticizer. The thermoset composition preferably comprises polybutadiene rubber. The ball further includes a cover of at least one layer.

A golf ball can include a core, a mid layer, and a cover. The golf ball can satisfy the following mathematical formulas (1), (2), and (3):
C1≤(124.8−Hs)/11.5  (1)
C2−C1≥(−1/6*C1+(68−H2)/20+(5−Hd)/100)*T2   (2)
10≤H2*T2−H3*T3  (3), where C1 is an amount of compressive deformation (mm) of the core, C2 is an amount of compressive deformation (mm) of a sphere including the core and the mid layer, Hd is Hs−Ho, Ho is a hardness (Shore C) of a center the core, Hs is a hardness (Shore C) of a surface of the core, H2 is a hardness (Shore D) of the mid layer, H3 is a hardness (Shore D) of the cover, T2 is a thickness (mm) of the mid layer, and T3 is a thickness (mm) of the cover.

A golf ball with a core comprising polybutadiene and graphene is disclosed herein. The golf ball has a single core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an inner core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an outer core comprising polybutadiene and graphene.

A golf ball 2 includes a core 4 and a cover 6 positioned outside the core 4. The cover 6 is formed in a mold having support pins by injection molding. A ratio (V/S) of a volume V (mm.sup.3) of the cover 6 to an amount of compressive deformation S (mm) of the core 4 is not less than 1000 and not greater than 1900. The cover 6 has a shore D hardness of not greater than 62. The golf ball 2 has a plurality of dimples 8 on a surface thereof. A total volume W of these dimples is not less than 490 mm.sup.3 and not greater than 620 mm.sup.3. A ratio (α/P) of a latitude α (degree) of each support pin to a total cross-sectional area P (mm.sup.2) of the support pins is not less than 0.35 and not greater than 0.60.

An object of the present invention is to provide a golf ball traveling a great flight distance and having a good shot feeling on long iron shots. The present invention provides a golf ball comprising a core, at least one intermediate layer covering the core and a cover covering the intermediate layer, wherein the core is formed from a core rubber composition containing (a) a base rubber containing a polybutadiene, (b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator, and (d) a terpene-based resin, and a material hardness (Hm) of the intermediate layer is higher than a material hardness (Hc) of the cover, and the material hardness (Hc) of the cover is 50 or more in Shore D hardness.

In a golf ball having a core, an intermediate layer and a cover, the core is formed primarily of a base rubber and has a diameter set in a specific range, and the intermediate layer and cover are each formed of resin materials. The core has an internal hardness such that, regarding the hardness at the core center, the hardnesses at positions located at 2 mm intervals from the core center outward up to 16 mm and the core surface hardness, the hardness differences therebetween are set within a specific range. The ball surface hardness is set so as to be higher than the surface hardness of the intermediate layer-encased sphere. This ball achieves a satisfactory distance on full shots not only with a driver, but also with a long iron or a middle iron, in addition to which it has an excellent durability to repeated impact.

In a multi-piece solid golf ball having a core, an envelope layer, an intermediate layer and a cover, the envelope layer is formed into two layers—an inner envelope layer and an outer envelope layer. The inner envelope layer-encased sphere, outer envelope layer-encased sphere, intermediate layer-encased sphere and ball have respective surface hardness that satisfy a specific relationship. The inner envelope layer or outer envelope layer is formed primarily of one or more elastomer, and further the core has a particular hardness profile. This ball has an excellent flight when struck by golfers whose head speeds are not that fast and has a good, soft feel at impact, thus making it highly suitable for amateur golfers.

In a golf ball having a core, envelope layer, intermediate layer and cover, the (core diameter)/(ball diameter) value falls within a particular range, the core has a specific hardness profile, and the Shore C hardness relationships among the core center and surface hardnesses and the surface hardnesses of the envelope layer-encased sphere, intermediate layer-encased sphere and ball satisfy the following conditions:
core surface hardness<surface hardness of envelope layer-encased sphere<surface hardness of intermediate layer-encased sphere>ball surface hardness,  (1)
(surface hardness of envelope layer-encased sphere)−(core center hardness)≥28.  (2) Also, the envelope layer, intermediate layer and cover have respective thicknesses which satisfy the condition:
cover thickness<intermediate layer thickness envelope layer thickness.  (3) This ball enables mid-level and skilled amateur golfers to achieve superior distances on driver shots and on iron shots, and moreover has a soft yet good feel at impact.

In a golf ball having a core of at least one layer and a cover of one or more layer encasing the core, at least one layer of the cover is formed of a resin composition that includes (I) a polyurethane or a polyurea and (II) an aromatic vinyl elastomer which together satisfy certain specific conditions. The golf ball has an excellent controllability on approach shots and is also able to maintain a good scuff resistance.