A golf ball includes a core, a mid layer, and a cover. A ratio R1 calculated by mathematical formula (1): R1=(Df1−Df2)/(Df2−Df3) is not less than 5.00. A ratio R2 calculated by mathematical formula (2): R2=(T2*H2)/H3 is not less than 2.00. A ratio R3 calculated by mathematical formula (3): R3=D1/T3 is not less than 50. In mathematical formulas (1) to (3), Df1 represents an amount of compressive deformation of the core, Df2 represents an amount of compressive deformation of a sphere including the core and the mid layer, Df3 represents an amount of compressive deformation of the golf ball, T2 represents a thickness of the mid layer, H2 represents a hardness of the mid layer, H3 represents a hardness of the cover, D1 represents a diameter of the core, and T3 represents a thickness of the cover.

A golf ball includes a core, a mid layer, and a cover. A ratio R1 calculated by mathematical formula (1): R1=(Df1−Df2)/(Df2−Df3) is not less than 5.00. A ratio R2 calculated by mathematical formula (2): R2=(T2*H2)/H3 is not less than 2.00. A ratio R3 calculated by mathematical formula (3): R3=D1/T3 is less than 50. In mathematical formulas (1) to (3), Df1 represents an amount of compressive deformation of the core, Df2 represents an amount of compressive deformation of a sphere including the core and the mid layer, Df3 represents an amount of compressive deformation of the golf ball, T2 represents a thickness of the mid layer, H2 represents a hardness of the mid layer, H3 represents a hardness of the cover, D1 represents a diameter of the core, and T3 represents a thickness of the cover.

Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. Polyurethane primer coatings and polyurethane top-coatings are applied to the thermoplastic polyurethane cover. Different coating methods can be used. Isocyanate-rich and polyol-rich polyurethane coatings can be applied. In one embodiment, the golf ball can be treated with a multi-functional isocyanate prior to applying the coatings. The polyurethane cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. Heat is used to cure the coatings. The coating methods have many benefits and the finished balls have good physical properties.

Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. Polyurethane primer coatings and polyurethane top-coatings are applied to the thermoplastic polyurethane cover. Different coating methods can be used. Isocyanate-rich and polyol-rich polyurethane coatings can be applied. In one embodiment, the golf ball can be treated with a multi-functional isocyanate prior to applying the coatings. The polyurethane cover composition and surface coatings can further include catalysts, ultraviolet (UV)—light stabilizers, and other additives. Heat is used to cure the coatings. The coating methods have many benefits and the finished balls have good physical properties.

An object of the present disclosure is to provide a golf ball having excellent durability and flight distance and good shot feeling for an average golfer who hits a golf ball at a slow head speed. The present disclosure provides a golf ball comprising a spherical core and at least two cover layers covering the spherical core, wherein a difference between a core surface crosslinking density and a core center crosslinking density is more than 1.0×10.sup.2 mol/m.sup.3 and less than 9.0×10.sup.2 mol/m.sup.3, a hardness difference between a core surface hardness Cs (Shore C hardness) and a core center hardness Co (Shore C hardness) is 13.0 or more and 30.0 or less, a compression deformation amount of the core when applying a load from an initial load of 98 N to a final load of 1275 N to the core is 3.8 mm or more, and the at least two cover layers include a first cover layer and a second cover layer positioned closer to the spherical core than the first cover layer, an average hardness Dave=(Ti×Hi+To×Ho)/(Ti+To) of the first cover layer and the second cover layer is 55 or more, where To (mm) is a thickness of the first cover layer, Ho (Shore D) is a slab hardness of the first cover layer, Ti (mm) is a thickness of the second cover layer, and Hi (Shore D) is a slab hardness of the second cover layer.

A golf ball with improved durability is disclosed herein. The golf ball has a core comprising a polybutadiene material and methyl methacrylate, butadiene, styrene (MBS) with a weight percentage of MBS ranging from 0.5 to 5 weight percent of the core.

A golf ball with a core comprising polybutadiene and graphene is disclosed herein. The golf ball has a single core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an inner core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an outer core comprising polybutadiene and graphene.

A rubber composition for golf balls includes (A) a base rubber, (B) an acrylate ester or methacrylate ester containing an isocyanate group or a blocked isocyanate group, (C) diacrylic acid, dimethacrylic acid or a metal salt thereof, and (D) an organic peroxide. In a golf ball having a core formed of the rubber composition and a cover of one or more layers which encases the core, the rubber composition exhibits a spin rate-lowering effect on shots and can thus improve the flight performance of the ball.

A method for forming a golf ball core with a nanofiller masterbatch is disclosed herein. The method includes mixing the nanofiller masterbatch, a graphene masterbatch material with other materials to form a core mixture, wherein the masterbatch preferably comprises 1-80% by weight of nanofillers and 20-99% by weight of a carrier polymer.

A method for forming a golf ball core with a nanofiller masterbatch is disclosed herein. The method includes mixing the nanofiller masterbatch, a graphene masterbatch material with other materials to form a core mixture, wherein the masterbatch preferably comprises 1-80% by weight of nanofillers and 20-99% by weight of a carrier polymer.