A golf ball with improved durability is disclosed herein. The golf ball has a core comprising a polybutadiene material and methyl methacrylate, butadiene, styrene (MBS) with a weight percentage of MBS ranging from 0.5 to 5 weight percent of the core.

Multi-layered golf balls having at least one layer made from silicone (polysiloxane) elastomers; silicone (polysiloxane) elastomer/polyurethane blends; polycarbonate-polysiloxane blends and copolymers; and polycarbonate-polysiloxane/polyurethane blends are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The polysiloxane compositions have good thermal stability and durability without sacrificing resiliency. The polysiloxane compositions also have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

An object of the present invention is to provide a cured product of a golf ball rubber composition capable of imparting excellent durability to a golf ball. The present invention provides a cured product of a golf ball rubber composition, wherein the golf ball rubber composition contains (a) a base rubber, (b) an ,-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, and (c) a crosslinking initiator, and wherein an effective crosslinking density DC (mmol/cm.sup.3) of the cured product of the golf ball rubber composition and a tensile elastic modulus TM (MPa) between 0.05% strain and 0.25% strain of the cured product of the golf ball rubber composition satisfy a relation of TM3.33In(DC)>(0.10).

A golf ball with a core comprising polybutadiene and graphene is disclosed herein. The golf ball has a single core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an inner core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an outer core comprising polybutadiene and graphene.

In a golf ball having a core of at least one layer and a cover of one or more layer encasing the core, at least one layer of the cover is formed of a resin composition that includes (I) a polyurethane or a polyurea and (II) an aromatic vinyl elastomer which together satisfy certain specific conditions. The golf ball has an excellent controllability on approach shots and is also able to maintain a good scuff resistance.

A golf ball having a cover with a plurality of dimples on the surface thereof is provided with a coat of mutually differing properties on dimple areas of the surface and on land areas between the dimples. The dimple areas are formed with a coat having a low coefficient of friction, do not affect the spin performance when the ball is struck and are not prone to staining. The land areas are formed with a coat having a high coefficient of friction, enabling a lower spin rate to be achieved and thus increasing the distance traveled by the ball, particularly when struck with a middle iron, and also help impart a high spin rate and a good controllability on approach shots.

A golf ball 2 includes a main body 4 and a paint layer 6 positioned outside the main body 4. The main body 4 includes a spherical core 8, a mid layer 10 positioned outside the core 8, and a cover 12 positioned outside the mid layer 10. An outer surface of the paint layer 6 forms a surface of the golf ball 2. A contact angle CAw with respect to water measured on the surface of the golf ball 2 is not less than 70 degrees. The paint layer 6 is preferably formed from a resin composition. A preferable resin composition includes a polyurethane as a base resin and includes a silicone compound and/or a fluorine compound. Another preferable resin composition includes a silicone compound and/or a fluorine compound as a base resin and includes no polyurethane.

An object of the present invention is to provide a golf ball having excellent shot feeling and resilience as well as improved durability and abrasion resistance. The present invention provides a golf ball comprising a spherical core and one or more cover layers disposed outside the spherical core, wherein at least one layer of the cover layers contains: (A) a base resin containing (a-1) an ionomer resin and having a material hardness of 58 or less in Shore D hardness; and (B) a polyrotaxane having a cyclodextrin with at least a part of hydroxyl groups thereof being modified with a caprolactone chain having a carboxyl group at a terminal of the caprolactone chain, a linear molecule piercing through a cyclic structure of the cyclodextrin, and blocking groups located at both terminals of the linear molecule to prevent disassociation of the cyclodextrin.

An object of the present invention is to provide a golf ball comprising a paint film having improved abrasion resistance without substantially lowering the spin performance. The present invention provides a golf ball comprising a golf ball body and a paint film formed on a surface of the golf ball body, wherein the paint film contains a resin fine particle in an amount of less than 10 parts by mass with respect to 100 parts by mass of a base resin thereof, the base resin of the paint film is a polyurethane, and the resin fine particle contains a polyrotaxane component having a cyclodextrin, a linear molecule penetrating the cyclic structure of the cyclodextrin in a skewering manner, and a blocking group located at both terminals of the linear molecule to prevent disassociation of the cyclodextrin, wherein at least a part of hydroxyl groups of the cyclodextrin is modified with a caprolactone chain via a OC.sub.3H.sub.6O group.

A golf ball includes a main body and a paint layer positioned outside the main body. The paint layer includes an inner layer and an outer layer positioned outside the inner layer. When an indentation depth (nm) is measured on a cross-section along a plane passing through a central point of the golf ball when a force of 30 mgf is applied to the cross-section in a direction perpendicular to the cross-section, an indentation depth Di on a cross-section of the inner layer is smaller than an indentation depth Do on a cross-section of the outer layer. A thickness To of the outer layer is larger than a thickness Ti of the inner layer.