The invention relates to golf balls having at least one layer formed from a highly-neutralized polymer material that has been crosslinked. In particular, the compositions of the invention include a highly-neutralized polymer, at least one crosslinking initiator, and at least one coagent. The invention also relates to methods of making the compositions and golf ball constructions that incorporate the compositions of the invention in at least a portion thereof.

A golf ball 2 includes a spherical core 4, an inner mid layer 6, an outer mid layer 8, a reinforcing layer 10, and a cover 12. When distances (%) from a central point of the core 4 to nine points and JIS-C hardnesses at the nine points, which nine points are obtained by dividing a region from the central point of the core 4 to a surface of the core 4 at intervals of 12.5% of a radius of the core 4, are plotted in a graph, R.sup.2 of a linear approximation curve obtained by a least-square method is equal to or greater than 0.95. Hm1 is greater than Hm2. Hc is less than Hm1. T2 is equal to or greater than 0.5 mm but equal to or less than 1.6 mm.

Golf ball multi-layered core sub-assemblies and the resulting golf balls are provided. The core structure includes a foam inner core (center); and intermediate and outer core layers. Foamed polyurethane is preferably used to make the inner core. The intermediate and outer core layers are preferably made from non-foamed thermoplastic compositions such as ethylene acid copolymer ionomer. In an alternative version, the intermediate core layer may be made of a thermoset rubber such as polybutadiene. The core layers have different hardness and specific gravity levels. The core structure and resulting ball have relatively good resiliency.

Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

A golf ball includes a core having an outer surface and a geometric center. The core is formed from a substantially homogenous rubber composition. An ionomeric inner cover layer is formed about the core and has a material hardness of about 60 Shore D or greater. The golf ball includes an outer cover layer formed from a polyurea or a polyurethane and having a material hardness of about 60 Shore D or less. The outer surface of the core has a trans content of about 12% or less and a hardness of about 71 to 88 Shore C. The geometric center of the core has a trans content of about 10% or less and a hardness of about 60 to 80 Shore C. The core has an outer surface hardness greater than a geometric center hardness by about 5 to 19 Shore C to define a positive hardness gradient.

A golf ball including a thermoplastic inner core layer that has a geometric center hardness greater than its surface hardness to define a negative hardness gradient. An outer core layer is disposed about the inner core and is formed from a thermoplastic material and has an inner surface hardness substantially less than its outer surface hardness to define a positive hardness gradient. An inner cover layer is disposed about the outer core layer and an outer cover layer is disposed about the inner cover layer.

A golf ball comprising a core and a cover layer, wherein at least one of the core or cover layer comprises a plasticized polyurethane composition comprising at least one polyurethane and at least one plasticizer.

An object of the present invention is to provide a golf ball traveling a great distance on driver shots and on iron shots. The present invention provides a golf ball comprising a spherical core including an inner layer and an outer layer, and a cover, wherein a difference (H.sub.X+1−H.sub.X−1) between a hardness (H.sub.X+1) at a point outwardly away in a radial direction from a boundary between the inner layer and the outer layer of the spherical core by 1 mm and a hardness (H.sub.X−1) at a point inwardly away in the radial direction from the boundary between the inner layer and the outer layer of the spherical core by 1 mm is 0 or more in Shore C hardness, a surface hardness (H.sub.X+Y) of the spherical core is more than 65 in Shore C hardness, an angle α of a hardness gradient of the inner layer is 0° or more, a difference (α−β) between the angle α and an angle β of a hardness gradient of the outer layer is 0° or more, a thickness of the cover is 3 mm or less, a difference (Hc−H.sub.x+y) between a hardness (Hc) of the cover and the surface hardness (H.sub.X+Y) of the spherical core is 2 or more in Shore C hardness, and the cover has a highest hardness among the constituent members of the golf ball.

A golf ball with a core comprising polybutadiene and graphene is disclosed herein. The golf ball has a single core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an inner core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an outer core comprising polybutadiene and graphene.

Multi-piece golf balls containing a dual-layered core and dual-layered cover are provided. The core structure includes a small, heavy inner core (center) having a relatively high specific gravity, and a surrounding outer core layer. The core layers may have different hardness gradients. The center of the core comprises a metal material such as copper, steel, brass, tungsten, titanium, aluminum, and combinations and alloys thereof preferably dispersed in a thermoplastic polymeric matrix. The outer core layer is preferably formed from a thermoset composition such as polybutadiene. The multi-layered cores and covers have selective specific gravity relationships between the different layers. This helps provide the ball with good flight distance and spin control. The resulting balls have good resiliency and other playing performance properties.