In a golf ball having a core, an envelope layer, an intermediate layer and a cover, the difference between the center hardness and the surface hardness of the core is set in a specific range, the intermediate layer is formed of a resin material that includes a high-acid ionomer, the Shore C hardness relationships among the core center and the surfaces of the envelope-encased layer and the intermediate layer-encased sphere satisfy specific conditions; and the ball has a deflection when compressed under a given load which is at least 2.7 mm. This ball achieves a good distance on shots with a driver, utility club or iron, is receptive to spin in the short game, and has a soft feel at impact on all shots, making it useful to amateur golfers.

A golf ball 2 includes a core 4, an inner cover 6 positioned outside the core 4, and an outer cover 8 positioned outside the inner cover 6. The core 4 has a capsule 14, a plurality of separators 16, an electronic unit 18, and a plurality of fillings 20. The capsule 14 has a melting point of not lower than 100° C. A ratio P1 of a volume Vr of the capsule 14 to a volume Vc of the core 4 is not less than 25% and not greater than 75%. The electronic unit 18 is housed in the capsule 14. The electronic unit 18 detects behavior of the golf ball 2.

A golf ball includes a core and a cover positioned outside the core. An n-layer (n is a natural number) partial mid layer is provided between the core and the cover. An area of the core in a region where the cover is laminated thereon is not less than 5.0% and not greater than 95.0% of a surface area of a phantom sphere having a radius equal to an average value of a distance from a central point of the core to a surface of the core. In an outer surface of the golf ball, a color difference ΔE1 based on a CIELAB color system between a region C where the cover is directly laminated on the core and a region M where the cover is laminated on the partial mid layer is not less than 20.0.

In a golf ball having a core, a cover and at least one intermediate layer therebetween, the cover is formed of a rubber composition which includes a diene rubber, methacrylic acid, a metal oxide and an organic peroxide. The cover has a specific Poisson's ratio, Shore D hardness and thickness. At least one intermediate layer has a specific Shore D hardness and thickness. This golf ball, even with the use of a rubber cover, compares favorably with balls having conventional resin covers, both in that it can achieve a lower spin rate on shots with a driver (W #1) and thus has an excellent flight performance and also in that it can improve controllability in the short game.

A golf ball comprising layers that have from 0.05% to 70% by weight of a radio-opaque filler, and wherein the concentration of the radio-opaque filler is measurably different in each layer is disclosed herein. The radio-opaque filler is preferably a compound based on barium, bismuth, tungsten, iodine, or reduced iron.

A method for forming a golf ball with a graphene core disclosed herein. The method includes mixing a graphene masterbatch material with a polybutadiene material to form a core mixture, wherein the graphene masterbatch material comprises graphene in an amount from 0.1 to 80.0 weight percent of the graphene masterbatch material mixed with a carrier polymer in an amount from 99.9 to 20 weight percent of the graphene masterbatch material.

An object of the present invention is to provide a golf ball traveling a great flight distance and having a good shot feeling and durability on driver shots. The present invention provides a golf ball comprising a core, at least one intermediate layer covering the core and a cover covering the intermediate layer, wherein the core is formed from a core rubber composition containing (a) a base rubber containing a polybutadiene, (b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator, and (d) a terpene-based resin, and a material hardness (Hm) of the intermediate layer and a material hardness (Hc) of the cover satisfy an equation of Hm≤Hc.

A golf ball comprising layers that have from 0.05% to 70% by weight of a radio-opaque filler, and wherein the concentration of the radio-opaque filler is measurably different in each layer is disclosed herein. The radio-opaque filler is preferably a compound based on barium, bismuth, tungsten, iodine, or reduced iron.

A method for forming a golf ball core with a nanofiller masterbatch is disclosed herein. The method includes mixing the nanofiller masterbatch, a graphene masterbatch material with other materials to form a core mixture, wherein the masterbatch preferably comprises 1-80% by weight of nanofillers and 20-99% by weight of a carrier polymer.

A golf ball with improved durability is disclosed herein. The golf ball has a mantle layer comprising a blend of ionomers and methyl methacrylate, butadiene, styrene (MBS) with a weight percentage of MBS ranging from 5 to 15 weight percent of the mantle layer.