A method for forming a golf ball core with a nanofiller masterbatch is disclosed herein. The method includes mixing the nanofiller masterbatch, a graphene masterbatch material with other materials to form a core mixture, wherein the masterbatch preferably comprises 1-80% by weight of nanofillers and 20-99% by weight of a carrier polymer.

A golf ball can include a core, a mid layer, and a cover. The golf ball can satisfy the following mathematical formulas (1) and (2),

(Fa/Fan)≤0.90  (1),

(Fa/Fan).sup.2/(Fp/Fpn)≤0.90  (2),

wherein Fa represents a maximum vertical force of the golf ball measured under a first condition. Fan represents a maximum vertical force of a standard ball measured under the first condition, Fp represents a maximum vertical force of the golf ball measured under a second condition, and Fpn represents a maximum vertical force of the standard ball measured under the second condition.

A method for forming a golf ball core with a nanofiller masterbatch is disclosed herein. The method includes mixing the nanofiller masterbatch, a graphene masterbatch material with other materials to form a core mixture, wherein the masterbatch preferably comprises 1-80% by weight of nanofillers and 20-99% by weight of a carrier polymer.

In a golf ball having a core, envelope layer, intermediate layer and cover, the (core diameter)/(ball diameter) value falls within a particular range, the core has a specific hardness profile, and the Shore C hardness relationships among the core center and surface hardnesses and the surface hardnesses of the envelope layer-encased sphere, intermediate layer-encased sphere and ball satisfy the following conditions:
core surface hardness<surface hardness of envelope layer-encased sphere<surface hardness of intermediate layer-encased sphere>ball surface hardness,  (1)
(surface hardness of envelope layer-encased sphere)−(core center hardness)≥28.  (2)
Also, the envelope layer, intermediate layer and cover have respective thicknesses which satisfy the condition:
cover thickness<intermediate layer thickness  (3)
cover thickness<envelope layer thickness  (4)
envelope layer thickness≥0.8 mm.  (5)
This ball enables mid-level and skilled amateur golfers to achieve superior distances on driver shots and on iron shots, and moreover has a soft yet good feel at impact.

Multi-layered golf balls having at least one layer made of a foamed silicone composition are provided. Multi-layered golf balls having at least one layer made of non-foamed silicone elastomer composition also are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The foamed silicones have good thermal stability and durability without sacrificing resiliency. The non-foamed silicone elastomers have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

A golf ball 2 includes a core 4, a mid layer 6, a cover 8, and dimples 10. A difference DH in hardness between a surface and a central point of the core 4, a thickness Tm and a hardness Hm of the mid layer 6, a thickness Tc and a hardness Hc of the cover 8, and an amount of compressive deformation Sb meet the following mathematical formulas.

(DH*Hm)/(Hc*Tc)>80

((Sb*Tc)/(Hc* Hm*Tm))*1000>0.75

An area ratio So of dimples 10 and a ratio Rs of a number of the dimples 10 each having a diameter of equal to or greater than 9.60% but equal to or less than 10.37% of a diameter of the golf ball 2 meet the following mathematical formula (3).

Rs≧−2.5*So+273   (3)

Provided is a golf ball is excellent in flight distance performance, approach performance, and feel at impact. A ball 2 includes a core 4, a mid layer 6, and a cover 8. The core 4 includes an inner core 10 and an outer core 12. The cover 8 includes an inner layer cover 10 and an outer layer cover 12. An inner core volume Vc, a mid layer volume Vm, a mid layer hardness Hm, an inner layer cover volume Vinc, an inner layer cover hardness Hinc, an outer layer cover volume Vouc, an outer layer cover hardness Houc, and a ball volume V meet the following relational expressions (a) to (g): (a) Vc/V<0.07, (b) Hm>Hinc>Houc, (c) Hm−Houc>25, (d) Vm>Vinc>Vouc, (e) (Vm+Vinc+Vouc)/V<0.30, (f) Vm/Vouc>1.50, and (g) (Vm*Hm)/(Vouc*Houc)>3.0.

An object of the present invention is to provide a golf ball traveling a great distance on driver shots. The present invention provides a golf ball comprising a spherical core including an inner layer and an outer layer, wherein a difference (H.sub.X+1−H.sub.X−1) between a hardness (H.sub.X+1) at a point outwardly away in a radial direction from a boundary between the inner layer and the outer layer of the spherical core by 1 mm and a hardness (H.sub.X−1) at a point inwardly away in the radial direction from the boundary between the inner layer and the outer layer of the spherical core by 1 mm is 0 or more in Shore C hardness, a surface hardness (H.sub.X+Y) of the spherical core is more than 70 in Shore C hardness, an angle α of a hardness gradient of the inner layer is 0° or more, a difference (α−β) between the angle α and an angle β of a hardness gradient of the outer layer is 0° or more, and the intermediate layer has a highest hardness among the constituent members of the golf ball.

A golf ball 2 includes a spherical core 4, an inner mid layer 6 positioned outside the core 4, an outer mid layer 8 positioned outside the inner mid layer 6, a reinforcing layer 10 positioned outside the outer mid layer 8, and a cover 12 positioned outside the reinforcing layer 10. When distances (%) from a central point of the core 4 to nine points and JIS-C hardnesses at the nine points, which nine points are obtained by dividing a region from the central point of the core 4 to a surface of the core 4 at intervals of 12.5% of a radius of the core 4, are plotted in a graph, R.sup.2 of a linear approximation curve obtained by a least-square method is equal to or greater than 0.95.