The present invention is directed to multi-layer golf balls including a layer formed from a relatively soft or low modulus HNP composition and a layer formed from a relatively hard or high modulus HNP composition. Optionally, the soft (or low modulus) HNP composition and/or the hard (or high modulus) HNP composition is plasticized or is replaced with a different plasticized acid copolymer composition.

Multi-piece golf balls having a solid core of at least one layer and cover of at least one layer are provided. Thermoplastic ethylene acid copolymer ionomer compositions are used to form the core layers. Preferably, the ball contains a dual-core having an inner core and surrounding outer core layer. Low modulus and high modulus ionomer compositions may be used in the core structure. In one embodiment, a first ionomer composition is used to form the inner core and a second ionomer composition is used to form the outer core, and the flex modulus of the first composition is greater than the flex modulus of the second composition. The ionomer compositions have varying levels of hardness. The resulting ball has high resiliency and rebounding properties.

A golf ball includes an inner core layer formed from a thermoset rubber composition. The inner core layer has a first outer surface Shore D hardness and an outer diameter of about 0.8 to 1.40 inches. A thermoplastic outer core layer is formed around the inner core layer, has a second outer surface Shore D hardness, and is formed from a copolymer of ethylene and an ,-unsaturated carboxylic acid, a magnesium salt of oleic acid, and sufficient cation source to fully-neutralize the acid groups of the copolymer. The golf ball includes an inner cover layer and an outer cover layer. The first outer surface Shore D hardness is greater than the second outer surface Shore D hardness and the outer core layer has a thickness of about 0.01 inches to 0.05 inches.

Multi-layer golf balls comprising a center, intermediate layer, and cover are disclosed. The center is formed from a highly-neutralized acid copolymer composition.

Multi-layered golf balls having a dual-layered core and cover of at least one layer are provided. The dual-core construction includes a non-foamed inner core (center) made of a thermoplastic or thermoset composition such as polybutadiene rubber. An outer core layer comprising a foamed composition, such as polyurethane foam, is disposed about the inner core. In one version, the foamed outer core layer is made of a relatively soft foam composition having low flex modulus and density. The foamed outer core layer may specific gravity gradient within the layer, wherein the outer surface specific gravity is greater than the midpoint specific gravity. A cover may be disposed about the core structure. For example, an inner cover made of ethylene acid copolymer ionomer and outer cover made of polyurethane may be used.

The present invention is directed to multi-layer golf balls including a layer formed from a composition comprising a relatively soft or low modulus HNP, a layer formed from a composition comprising a relatively hard or high modulus HNP, an inner cover layer formed from a thermoplastic composition, and an outer cover layer.

Golf balls having multi-layered covers are provided. Preferably, the ball includes an inner cover layer made of an aromatic polyurethane composition; and an outer cover layer made of an aliphatic polyurethane composition. At least one of the cover layers is formed by casting an aromatic or aliphatic thermoplastic polyurethane composition. Ethylene acid copolymer ionomers can be used to make a second inner cover layer. The cover layers are disposed about a single or multi-layered core. The invention also includes casting methods for making such multi-layered covers. The resulting ball has good light-stability, cut/shear-resistance, and impact durability.

An object of the present invention is to provide a golf ball traveling a great flight distance. The present invention provides a golf ball comprising a spherical core and a cover covering the spherical core, wherein the golf ball has a ratio (t2/t1) of a time (t2) to a time (t1) of 1.05 or more in a hitting test using a driver (at a head speed of 40 m/sec), wherein the time (t1) is a time taken from a moment that the driver begins to contact with the golf ball to a moment that the golf ball reaches a maximum deformation amount, and the time (t2) is a time taken from the moment that the golf ball reaches the maximum deformation amount to a moment that the golf ball leaves the driver.

Multi-piece golf balls having at least one layer made from a polyamide non-ionomeric composition are provided. The polyamide composition consists essentially of about 40 to about 99% by weight polyamide; about 1 to about 60% by weight of an acid anhydride-modified polyolefin; and about 1 to about 60% of a fatty acid additive selected from the group consisting of fatty acid salts, fatty acid amides, and mixtures thereof. The ball includes a core, preferably a dual core construction; and a cover of at least one layer. In another preferred construction, a multi-layered core containing an inner, intermediate, and outer core layer is made. For example, the intermediate core layer may be made of a rubber composition; and each of the inner core and outer core layers may be made of the polyamide composition. The resulting ball has high resiliency along with a soft feel.

A golf ball includes an intermediate layer, a cover, and a paint film, wherein a base resin of the paint film is a polyurethane obtained by a reaction between a polyisocyanate composition and a polyol composition containing a urethane polyol including a polyether diol with a number average molecular weight ranging from 800 to 3000 as a constituent component, and the golf ball satisfies the following requirements;
Mp200X75
Mp100
MmMc>100
Tm>Tc>Tp
(TmMm)/(TcMc)>7.5
(TcMc)/(TpMp)>2.4.
[Mp, Mm and Mc represent 10% modulus (kgf/cm.sup.2) of the paint film, intermediate layer and cover, respectively; Tp, Tm and Tc represent thicknesses (mm) of the paint film, intermediate layer and cover, respectively; and X represents a molar ratio (NCO/OH).]