An object of the present invention is to provide a golf ball having a decreased spin rate on driver shots. The present invention provides a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) a base rubber, (b) a compound represented by the formula (1) as a co-crosslinking agent, and (c) a crosslinking initiator,

(R.sup.1COO)M(OCOR.sup.2)m(1) in the formula (1), M represents a metal atom, m represents 1 or 2, R.sup.1 and R.sup.2 are different from each other, represent an alkenyl group having 2 to 30 carbon atoms or an alkynyl group having 2 to 30 carbon atoms and have a carbon-carbon double bond or a carbon-carbon triple bond at an -position carbon atom bonding to the carbonyl group, and when m is 2, two of R.sup.2 may be identical to or different from each other.

In a multi-piece solid golf ball having a core, an envelope layer, an intermediate layer and a cover, the core is formed primarily of a base rubber and has a diameter set in a specific range, the envelope layer, intermediate layer and cover are each formed of resin materials, and the envelope layer is formed into two layersan inner layer and an outer layer. The center and surface hardnesses of the core, the surface hardness of the inner envelope layer-encased sphere, the surface hardness of the outer envelope layer-encased sphere, the surface hardness of the intermediate layer-encased sphere and the surface hardness of the ball together satisfy a specific relationship. This ball achieves a satisfactory distance on full shots both with a driver and with irons, in addition to which it is superior in the short game and has a good feel at impact and an excellent scuff resistance.

Multi-layered golf balls having at least one layer made from silicone (polysiloxane) elastomers; silicone (polysiloxane) elastomer/polyurethane blends; polycarbonate-polysiloxane blends and copolymers; and polycarbonate-polysiloxane/polyurethane blends are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The polysiloxane compositions have good thermal stability and durability without sacrificing resiliency. The polysiloxane compositions also have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

An object of the present invention is to provide a golf ball having excellent shot feeling and resilience as well as improved durability and abrasion resistance. The present invention provides a golf ball comprising a spherical core and one or more cover layers disposed outside the spherical core, wherein at least one layer of the cover layers contains: (A) a base resin containing (a-1) an ionomer resin and having a material hardness of 58 or less in Shore D hardness; and (B) a polyrotaxane having a cyclodextrin with at least a part of hydroxyl groups thereof being modified with a caprolactone chain having a carboxyl group at a terminal of the caprolactone chain, a linear molecule piercing through a cyclic structure of the cyclodextrin, and blocking groups located at both terminals of the linear molecule to prevent disassociation of the cyclodextrin.

In a golf ball having a core of one or more layer and a cover of one or more layer encasing the core, the core has a deflection when compressed under a specific load of at least 3.8 mm; at least an innermost portion of the core has a specific difference between maximum and minimum values in cross-sectional hardnesses (JIS-C) from a center to a surface thereof; and the center core is formed of a rubber composition that includes (a) a base rubber, (b) an ,-unsaturated carboxylic acid and/or metal salt thereof, (c) a diacyl peroxide and/or a peroxyester, and (d) a dialkyl peroxide and/or a peroxyketal. The golf ball has a low spin rate on driver shots by low head speed golfers, and thus achieves an improved distance, while minimizing any decrease in durability.

A golf ball according to the present invention includes: a module including an electronic circuit and its power source; a protective layer that surrounds an outer periphery of the module and is formed from a material having a Shore D hardness of at least 60; a core that surrounds an outer periphery of the protective layer; and a cover that surrounds an outer periphery of the core. A weight may be arranged on a surface of the protective layer. A difference between a value MOImax of the moment of inertia in a direction in which the moment of inertia of the golf ball is maximum and a value MOImin of the moment of inertia in a direction in which the moment of inertia of the golf ball is minimum is at most 1.0 g.Math.cm.sup.2.

An object of the present invention is to provide a golf ball having excellent durability. The present invention provides a golf ball comprising a core and at least one cover layer covering the core, wherein the core is formed from a core rubber composition containing (a) a base rubber, (b) an ,-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator, and (d) a hindered phenol compound, and (b) the co-crosslinking agent and (d) the hindered phenol compound are blended in the core rubber composition such that the following expression (1) is satisfied:

0.04HF/B0.35(1) in the formula (1), HF=a number of OH functional group in one molecule of (d) the hindered phenol compoundan amount of (d) the hindered phenol compound (mole) with respect to 100 parts by mass of (a) the base rubber, and B=an amount of (b) the co-crosslinking agent (mole) with respect to 100 parts by mass of (a) the base rubber.

A method for forming a golf ball with a graphene core disclosed herein. The method includes mixing a graphene masterbatch material with a polybutadiene material to form a core mixture, wherein the graphene masterbatch material comprises graphene in an amount from 0.1 to 80.0 weight percent of the graphene masterbatch material mixed with a carrier polymer in an amount from 99.9 to 20 weight percent of the graphene masterbatch material.

Multi-layered golf balls having at least one layer made from silicone (polysiloxane) elastomers; silicone (polysiloxane) elastomer/polyurethane blends; polycarbonate-polysiloxane blends and copolymers; and polycarbonate-polysiloxane/polyurethane blends are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The polysiloxane compositions have good thermal stability and durability without sacrificing resiliency. The polysiloxane compositions also have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

In a golf ball having a two-layer core consisting of an inner core layer and an outer core layer and a cover of one or more layer, the inner core layer and outer core layer are each formed of a rubber composition made up primarily of a base rubber, the inner core layer has a diameter of not more than 30 mm; and the core has specific hardness ratios (JIS-C hardness/Shore D hardness) at specific points on the cross-section thereof. This golf ball has a reduced spin rate on full shots with a driver and middle irons, thus imparting to an excellent flight performance, and moreover has a good controllability in the short game on approach shots, making it ideal as a golf ball for professional golfers and mid- and high-level amateur golfers.