Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) made from a foam or metal-containing composition, or it has a hollow shell construction, and the outer core layer is made of a thermoplastic composition. Preferably, the thermoplastic composition comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. The core assembly preferably has a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency at given compressions.

In a multi-piece solid golf ball having a core, a cover and an intermediate layer therebetween, the core, an intermediate layer-encased sphere and the ball have surface hardnesses which satisfy a specific relationship, and the intermediate layer and the cover have thicknesses which satisfy a specific relationship. Also, the core has a hardness profile in which the hardnesses at the core surface, core center, a position 5 mm from the core center, and a position midway between the surface and center of the core satisfy specific relationships. This golf ball, when used by mid- and high-level amateurs, enables the golfer to maintain an adequate distance on shots with a driver and achieve a good distance on iron shots, has a good spin performance on approach shots and has a good feel on impact. In addition, the ball has an excellent scuff resistance when struck with a grooved wedge.

In a multi-piece solid golf ball having a core, an intermediate layer encasing the core and a cover which encases the intermediate layer and has numerous dimples on an outside surface thereof, the intermediate layer is formed of a resin material, the cover is formed of a urethane resin material, the core has a diameter of at least 38.0 mm, the sphere obtained by encasing the core with the intermediate layer has a surface hardness on the Shore D hardness scale of at least 69, the cover has a material hardness on the Shore D hardness scale of 55 or less, the (intermediate layer thickness)/(core diameter) value is from 0.025 to 0.043, the (cover thickness)/(core diameter) value is from 0.014 to 0.027, and the sphere obtained by encasing the core with the intermediate layer has an initial velocity A and the core has an initial velocity B which together satisfy the condition AB0 m/s.

In a golf ball having a two-layer core consisting of an inner core layer and an outer core layer, one or more intermediate layer, and a cover serving as an outermost layer, the inner core layer and outer core layer are each formed primarily of a base rubber, the inner core layer has a diameter of at least 21 mm, the intermediate layer and the cover are each formed primarily of a resin material, and the overall core has a specific hardness profile. The golf ball has a high initial velocity while holding down the spin rate on full shots with a driver or long iron, thus enabling a good distance to be achieved. The ball also has a high controllability in the short game.

The invention provides a golf ball having a core and a cover of one layer or a plurality of layers, the core being formed of a material molded under heat from a rubber composition containing: (A) a base rubber, (B) an organic peroxide, and (C) water and/or a metal monocarboxylate. The core has a hardness profile which satisfies specific relationships between the JIS-C hardness at the core center (Cc), the JIS-C hardness at a position 10 mm from the core center (C10) and the JIS-C hardness at the core surface (Cs).

Golf ball comprising a core having a hardness gradient and an outer cover layer having a microhardness gradient and being formed from a thermoset polyurethane material throughout, and having: i) a treated region that is contacted with a thermoset polyurethane microhardness-increasing solution consisting of an isocyanate portion and at least one non-aqueous solvent; and ii) an untreated region that is not contacted with the thermoset polyurethane microhardness-increasing solution. The treated region comprises the isocyanate portion, whereas the untreated region does not comprise the isocyanate portion. Treated region has a microhardness M.sub.1 that is greater than microhardness M.sub.2 of untreated region to define the outer cover layer positive microhardness gradient M=M.sub.1M.sub.2. The treated region may have a depth Dtr that extends inward from the cover outer surface and in some embodiments is less than a thickness of the untreated region. Treated region may alternatively extend from the inner surface toward outer surface.

A golf ball includes a core, an intermediate layer, and a cover, in which an initial velocity is not more than 76.0 m/s, a deflection when the ball is compressed under a specific load is at least 2.8 mm, and letting a value of (initial velocity of core?weight of core) be Ciw, a value of [(initial velocity of intermediate layer-encased sphere?initial velocity of core)?(weight of intermediate layer-encased sphere?weight of core)] be Miw, and a value of [(initial velocity of ball?initial velocity of intermediate layer-encased sphere)?(weight of ball?weight of intermediate layer-encased sphere)] be CViw, the condition is of Ciw+Miw+CViw?2,550 is satisfied, thereby to be capable of making a distance for reducing a distance on shots with a driver and an iron by average hitters smaller.

A multi-piece solid golf ball includes a core, an intermediate layer, and a cover, in which the core is formed of a rubber composition, the intermediate layer and the cover are formed of a resin composition, and a specific gravity of the intermediate layer is set to at least 1.05, or a relationship among a core surface hardness, a surface hardness of an intermediate layer-encased sphere, and a ball surface hardness satisfies the following condition:

ball surface hardness<surface hardness of intermediate layer-encased sphere>core surface hardness and the core has a specific cross-sectional hardness profile, thereby to have a superior distance on full shots with clubs from a driver to an iron, good durability on repeated impact, and good controllability in the short game when used by amateur users who are advanced players.

Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises a layer formed from a highly neutralized polymer composition and a layer formed from a thermoset rubber.

The invention provides a golf ball having a core and a cover of one layer or a plurality of layers, the core being formed of a material molded under heat from a rubber composition which includes (A) a base rubber, (B) an organic peroxide, and (C) water and/or a metal monocarboxylate. The product PE of the difference P (mol/m.sup.3) in crosslink density between the core surface and the core center, as measured based on a toluene swelling test, multiplied by the deflection E (mm) of the core when compressed under a final load of 1,275 N (130 kgf) from an initial load state of 98 N (10 kgf) is at least 2810.sup.2 mol/m.sup.3.Math.mm.