Golf ball comprising a core having a hardness gradient and an outer cover layer having a microhardness gradient and being formed from a thermoset polyurethane material throughout, and having: i) a treated region that is contacted with a thermoset polyurethane microhardness-increasing solution consisting of an isocyanate portion and at least one non-aqueous solvent; and ii) an untreated region that is not contacted with the thermoset polyurethane microhardness-increasing solution. The treated region comprises the isocyanate portion, whereas the untreated region does not comprise the isocyanate portion. Treated region has a microhardness M.sub.1 that is greater than microhardness M.sub.2 of untreated region to define the outer cover layer positive microhardness gradient M=M.sub.1M.sub.2. The treated region may have a depth Dtr that extends inward from the cover outer surface and in some embodiments is less than a thickness of the untreated region. Treated region may alternatively extend from the inner surface toward outer surface.

In a multi-piece solid golf ball having a core, a cover and an intermediate layer therebetween, the core, an intermediate layer-encased sphere and the ball have surface hardnesses which satisfy a specific relationship, and the intermediate layer and the cover have thicknesses which satisfy a specific relationship. Also, the core has a hardness profile in which the hardnesses at the core surface, core center, a position 5 mm from the core center, and a position midway between the surface and center of the core satisfy specific relationships. This golf ball, when used by mid- and high-level amateurs, enables the golfer to maintain an adequate distance on shots with a driver and achieve a good distance on iron shots, has a good spin performance on approach shots and has a good feel on impact. In addition, the ball has an excellent scuff resistance when struck with a grooved wedge.

Golf ball comprising a positive hardness gradient core and an outer cover layer having a microhardness gradient and being formed from a thermoset polyurethane material throughout, and having: i) a treated region that is contacted with a thermoset polyurethane microhardness-increasing solution consisting of an isocyanate portion and at least one non-aqueous solvent; and ii) an untreated region that is not contacted with the thermoset polyurethane microhardness-increasing solution. The treated region comprises the isocyanate portion, whereas the untreated region does not comprise the isocyanate portion. Treated region has a microhardness M.sub.1 that is greater than microhardness M.sub.2 of untreated region to define the outer cover layer positive microhardness gradient M=M.sub.1M.sub.2. The treated region may have a depth Dtr that extends inward from the cover outer surface and in some embodiments is less than a thickness of the untreated region. Treated region may alternatively extend from the inner surface toward outer surface.

In a multi-piece solid golf ball made up of, successively, a core, an intermediate layer and a cover having numerous dimples on the surface thereof, the intermediate layer is formed of a resin material and the cover is formed of a urethane resin material, each having a specific respective Shore D hardness. The ball has a specific (intermediate layer thickness)/(core diameter) value and a specific (cover thickness)/(core diameter) value, and the core has a specific deflection. The sphere consisting of the core encased by the intermediate layer has an initial velocity A and the core has an initial velocity B which together satisfy the condition AB0 m/s. This golf ball provides an increased distance and has both a soft feel when played and a high durability to repeated impact.

A golf ball comprising at least one layer comprised of a neutralized acid polymer composition consisting of a mixture of: (a) at least one low molecular weight acid-containing wax; (b) at least one non-acid-polymer; and (c) at least one organic acid or salt thereof. Each low molecular weight acid-containing wax may have a molecular weight of from about 500 to about 7000, and in some embodiments, the molecular weight may be considered low up to 30,000. Interactions between components (a), (b) and (c) as disclosed herein advantageously produce a layer of ionomeric material having desirable physical properties, such as heat stability, and processability (excellent melt flow) without the need for blending high and low molecular weight acid-containing polymer(s).

Provided is a golf ball including a core, an intermediate layer, and a cover. A relationship between surface hardnesses of an intermediate layer-encased sphere and the ball satisfies a predetermined relational expression. With a ball initial velocity and a deflection under a predetermined load applied to the ball optimized, and letting a value of (initial velocity of core?weight of core) be Ciw, a value of [(initial velocity of intermediate layer-encased sphere-initial velocity of core)?(weight of intermediate layer-encased sphere-weight of core)] be Miw, and a value of [(initial velocity of ball-initial velocity of intermediate layer-encased sphere)?(weight of ball-weight of intermediate layer-encased sphere)] be CViw, the following condition is satisfied:

[00001]$2500?\mathrm{Ciw}+\mathrm{Miw}+\mathrm{CViw}?2650.$

Lift coefficients and drag coefficients at predetermined Reynolds numbers and spin rates are set to predetermined ranges.

Golf balls having a single or dual-layered solid core are provided. In one embodiment, the golf ball has dimensions and properties that do not conform to the rules of the United States Golf Association (USGA). For example, the ball weight; ball size; ball spherical symmetry; ball initial velocity; and/or ball overall distance may fall outside of the USGA standards. The dual-layered core can have an inner core comprising a thermoplastic composition and surrounding outer core comprising a thermoset composition. In another embodiment, the dual-layered core has an inner core comprising a thermoplastic composition and outer core comprising a thermoset composition. The thermoplastic composition preferably comprises an ethylene acid copolymer ionomer and plasticizer. The thermoset composition preferably comprises polybutadiene rubber. The ball further includes a cover of at least one layer.

Golf ball having a core and a cover of one or more layers, the core being formed of a material molded under heat from a rubber composition including a base rubber, an organic peroxide, and water and/or a metal monocarboxylate. Defining the tan slope as (tan .sub.10tan .sub.1)/(10%1%), where tan .sub.1 and tan .sub.10 are the loss tangents at dynamic strains of, respectively, 1% and 10% when the loss tangents of the core center and the core surface are measured at 12 C. and 15 Hz, the difference between the tan slopes at the core surface and the core center is larger than 0.002. Because a core material which undergoes little decrease in resilience over time and experiences little energy loss can be obtained, the golf ball maintains a good rebound, has a reduced spin rate and thus is able to achieve an increased distance.

In a multi-piece solid golf ball having a core, an envelope layer encasing the core, an intermediate layer encasing the envelope layer, and an outermost layer encasing the intermediate layer, the envelope layer-encased sphere, the intermediate layer-encased sphere and the ball have surface hardnesses which satisfy a specific relationship, the intermediate layer and the cover have thicknesses which satisfy a specific relationship, and the core has a hardness profile in which the hardnesses at the core surface, core center, a position 5 mm from the core center, and a position midway between the core surface and center satisfy specific relationships. This golf ball satisfies at a high level the flight and control performances desired for use by professional golfers and skilled amateurs. In particular, it holds down the spin rate on full shots and follows a straight trajectory, thus having a superior flight performance, and moreover is endowed with an excellent scuff resistance.

In a multi-piece solid golf ball having a core, a cover and an intermediate layer therebetween, the core, an intermediate layer-encased sphere and the ball have surface hardnesses which satisfy a specific relationship, and the intermediate layer and the cover have thicknesses which satisfy a specific relationship. Also, the core has a hardness profile in which the hardnesses at the core surface, core center, a position 5 mm from the core center, and a position midway between the surface and center of the core satisfy specific relationships. This golf ball, when used by mid- and high-level amateurs, enables the golfer to maintain an adequate distance on shots with a driver and achieve a good distance on iron shots, has a good spin performance on approach shots and has a good feel on impact. In addition, the ball has an excellent scuff resistance when struck with a grooved wedge.