The invention provides a golf ball that is a one-piece golf ball or a golf ball having a core and a cover of one layer or a plurality of layers, wherein the one-piece golf ball or core is formed of a material molded under heat from a rubber composition containing: (A) a base rubber, (B) an organic peroxide, (C) water, (D) a metal methacrylate and (E) zinc oxide. The content of component (D) per 100 parts by weight of component (A) is from 30 to 45 parts by weight. The molar ratio (C)/(D) between components (C) and (D) satisfies the formula
0.9<(C)/(D)<1.1. The core has an initial velocity V.sub.0 of at least 72.0 m/s and up to 75.0 m/s.

A golf ball includes a core having an outer surface, a geometric center, and a soft transition region adjacent to the outer surface. The soft transition region has a thickness of about 4 mm or less and includes about 2 to 10 percent of a trans-polybutadiene isomer. An outer cover layer has a hardness of about 50 Shore M or greater. The core outer surface hardness is greater than the hardness at the geometric center to define a positive hardness gradient of about 10 to 48 Shore C. The core has a secondary gradient quotient, GQ, of 1.5 to 7.25, GQ being defined by the equation: $\frac{G^{}+T}{10\mathrm{COR}}$
where G is the positive hardness gradient in Shore C, T is the percent trans-polybutadiene isomer at the core outer surface, and COR is the coefficient of restitution of the core measured at an incoming velocity of 125 ft/s.

Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a thermoplastic composition, preferably including: a) ethylene acid copolymer, b) plasticizer, and c) cation source. Preferably, a fatty acid ester such as ethyl oleate is used as the plasticizer. The outer core layer is preferably formed from a thermoset composition such as polybutadiene rubber. The core layers have different hardness levels. For example, the inner core can have a positive, zero, or negative hardness gradient. The core assembly preferably has a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency at given compressions.

In a multi-piece solid golf ball having a core, an envelope layer, an intermediate layer, and a cover with a plurality of dimples thereon, the core is a two-layer core consisting of an inner core layer and an outer core layer each formed primarily of a base rubber, the envelope layer, the intermediate layer and the cover layer are each composed of at least one layer and formed primarily of a synthetic resin material, and the initial velocities and surface hardnesses of the core, the envelope layer-encased sphere and the intermediate layer-encased sphere are designed within specific ranges. This golf ball satisfies at a very high level the flight and control performances expected for use by professional golfers and skilled amateurs, has the ability to move forward on a straight path particularly on full shots, and also has an excellent scuff resistance.

In a multi-piece solid golf ball having a core, an envelope layer, an intermediate layer, and a cover with a plurality of dimples formed thereon, the core is formed primarily of a base rubber, the envelope layer and the intermediate layer are formed primarily of synthetic resin materials, and the cover layer is formed primarily of a urethane material. The relationships between, respectively, the surface hardnesses of the envelope layer-encased sphere and the ball, the thicknesses of the intermediate layer and the cover layer, the deflections of the core and the ball, and the initial velocities of the core and various layer-encased spheres of the ball each satisfy specific conditions. This golf ball makes it possible for amateur golfers, while maintaining a good distance on shots with a driver (W#1), to obtain a good ball controllability on approach shots and moreover experience a soft feel at impact.

The invention provides a golf ball having a core and a cover of one layer or a plurality of layers, the core being formed of a material molded under heat from a rubber composition containing: (A) a base rubber, (B) an organic peroxide, and (C) water and/or a metal monocarboxylate. The core has a hardness profile which satisfies specific relationships between the JIS-C hardness at the core center (Cc), the JIS-C hardness at a position 10 mm from the core center (C10) and the JIS-C hardness at the core surface (Cs).

Golf ball comprising a positive hardness gradient core and an outer cover layer having a microhardness gradient and being formed from a thermoset polyurethane material throughout, and having: i) a treated region that is contacted with a thermoset polyurethane microhardness-increasing solution consisting of an isocyanate portion and at least one non-aqueous solvent; and ii) an untreated region that is not contacted with the thermoset polyurethane microhardness-increasing solution. The treated region comprises the isocyanate portion, whereas the untreated region does not comprise the isocyanate portion. Treated region has a microhardness M.sub.1 that is greater than microhardness M.sub.2 of untreated region to define the outer cover layer positive microhardness gradient M=M.sub.1M.sub.2. The treated region may have a depth Dtr that extends inward from the cover outer surface and in some embodiments is less than a thickness of the untreated region. Treated region may alternatively extend from the inner surface toward outer surface.

A multi-piece solid golf ball includes a core, an intermediate layer, and a cover, in which the core is formed of a rubber composition, the intermediate layer and the cover are formed of a single-layer resin composition, and a relationship among an initial velocity of the core, an initial velocity of an intermediate layer-encased sphere, and an initial velocity of a sphere (ball) obtained by encasing the intermediate layer-encased sphere with the cover satisfies (ball initial velocity)<(initial velocity of intermediate layer-encased sphere) and 0.60(initial velocity of intermediate layer-encased sphere)(core initial velocity)0.90 (m/s). When each sphere of the core and the ball is compressed under a specific load and deflections are denoted by C (mm) and B (mm), respectively, a value of CB is not more than 1.10 mm, and 0.024(intermediate layer thickness)/(ball diameter)0.034 is satisfied.

The invention provides a golf ball having a core and a cover of one layer or a plurality of layers, the core being formed of a material molded under heat from a rubber composition containing: (A) a base rubber, (B) an organic peroxide, and (C) water and/or a metal monocarboxylate. The core has a hardness profile which satisfies specific relationships between the JIS-C hardness at the core center (Cc), the JIS-C hardness at a position 10 mm from the core center (C10) and the JIS-C hardness at the core surface (Cs).

The invention provides a golf ball having a core and a cover of one layer or a plurality of layers, the core being formed of a material molded under heat from a rubber composition which includes (A) a base rubber, (B) an organic peroxide, and (C) water and/or a metal monocarboxylate. The product PE of the difference P (mol/m.sup.3) in crosslink density between the core surface and the core center, as measured based on a toluene swelling test, multiplied by the deflection E (mm) of the core when compressed under a final load of 1,275 N (130 kgf) from an initial load state of 98 N (10 kgf) is at least 2810.sup.2 mol/m.sup.3.Math.mm.