Multi-layered golf balls having at least one layer made of a foamed silicone composition are provided. Multi-layered golf balls having at least one layer made of non-foamed silicone elastomer composition also are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The foamed silicones have good thermal stability and durability without sacrificing resiliency. The non-foamed silicone elastomers have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

A golf ball includes a core, a mid layer, and a cover. A ratio R1 calculated by mathematical formula (1): R1=(Df1−Df2)/(Df2−Df3) is not less than 5.00. A ratio R2 calculated by mathematical formula (2): R2=(T2*H2)/H3 is not less than 2.00. A ratio R3 calculated by mathematical formula (3): R3=D1/T3 is not less than 50. In mathematical formulas (1) to (3), Df1 represents an amount of compressive deformation of the core, Df2 represents an amount of compressive deformation of a sphere including the core and the mid layer, Df3 represents an amount of compressive deformation of the golf ball, T2 represents a thickness of the mid layer, H2 represents a hardness of the mid layer, H3 represents a hardness of the cover, D1 represents a diameter of the core, and T3 represents a thickness of the cover.

A golf ball includes a core, a mid layer, and a cover. A ratio R1 calculated by mathematical formula (1): R1=(Df1−Df2)/(Df2−Df3) is not less than 5.00. A ratio R2 calculated by mathematical formula (2): R2=(T2*H2)/H3 is not less than 2.00. A ratio R3 calculated by mathematical formula (3): R3=D1/T3 is less than 50. In mathematical formulas (1) to (3), Df1 represents an amount of compressive deformation of the core, Df2 represents an amount of compressive deformation of a sphere including the core and the mid layer, Df3 represents an amount of compressive deformation of the golf ball, T2 represents a thickness of the mid layer, H2 represents a hardness of the mid layer, H3 represents a hardness of the cover, D1 represents a diameter of the core, and T3 represents a thickness of the cover.

In an aspect, a sports ball includes a core including a negative Poisson's ratio (NPR) foam material, in which the core has a Poisson's ratio of between 0 and −1, and in which the NPR foam material includes an NPR polymer foam; and a cover layer surrounding the core. In an aspect, a golf club includes an elongated shaft; a grip disposed at a first end of the elongated shaft; and a head connected to a second end of the elongated shaft, the head having a flat face configured for contact with a golf ball, in which the flat face is formed of a negative Poisson's ratio (NPR) foam material, in which the head has a Poisson's ratio of between 0 and −1, and in which the NPR foam material includes an NPR metal foam, an NPR ceramic foam, or an NPR-PPR composite foam.

Dual core golf ball constructions achieving consistent and repeatable concentricity by incorporating/using an assembly of dual core components comprising a solid spherical inner core component and three outer core components that are collectively compression molded about the solid spherical inner core component to create an outer core layer thereabout. The three outer core components include a first half-shell, a second half-shell; and a ring-shaped securing plate such that the solid spherical inner core component is immovably centered within the outer core layer. Each of the first half-shell, the ring-shaped securing plate, and the second half-shell is comprised of the same rubber composition(s) and possess strong cohesive and adhesive bonds at parting lines between the three molded assembly parts and collectively create an outer core layer having one or more uniform property profile, such as a hardness gradient throughout, without interruption at parting lines between the three outer core components.

Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. Polyurethane primer coatings and polyurethane top-coatings are applied to the thermoplastic polyurethane cover. Different coating methods can be used. Isocyanate-rich and polyol-rich polyurethane coatings can be applied. In one embodiment, the golf ball can be treated with a multi-functional isocyanate prior to applying the coatings. The polyurethane cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. Heat is used to cure the coatings. The coating methods have many benefits and the finished balls have good physical properties.

A formulation for making at least one element of a golf ball, wherein the formulation includes: (i) from 50 weight percent to 95 weight percent of a thermoplastic composition comprising: (1) at least one ethylene acid copolymer consisting essentially of copolymerized comonomers of: (A) ethylene, and (B) from 5 weight percent to 25 weight percent of at least one α,β-ethylenically unsaturated carboxylic acid having from 3 carbon atoms to 8 carbon atoms, based on the total weight of monomers present in the ethylene acid copolymer; wherein the acid moieties of component (1) are neutralized to a level of from 25 percent to 220 percent; and (ii) from 5 weight percent to 50 weight percent of a crosslinked material having a gel content of at least 80 weight percent, wherein the crosslinked material is a crosslinked elastomer, a crosslinked rubber, or a blend of a crosslinked elastomer and a crosslinked rubber; a process for making the above formulation; at least one element of a multilayer golf ball and a process for making the at least one element of a multilayer golf ball using the above formulation; a multilayer golf ball including (a) at least one core, and (b) a cover; wherein the at least one core is made from the above formulation; and a process of manufacturing the above multilayer golf ball.

Golf balls including a plurality of radar detectable marks disposed on any single layer or among two or more layers thereof are provided. When all of the radar detectable marks present on any layer of the ball are radially projected onto the outer surface of the ball, the resulting overall pattern of projected radar detectable marks includes a series of three or marks located on a 1.5 mm wide great circle band on the outer surface of the ball.

In a golf ball having a core and a cover, the cover is formed primarily of polyurethane, dimples formed on the cover have a volume occupancy ratio VR of from 0.80 to 0.92%, the ball has a weight of not more than 45.0 g and, in an impact test carried out by hitting the ball with a driver at a head speed of 40 m/s, the sum t1+t2 of the time t1 required from initial contact by the driver with the ball for deformation of the ball to reach a maximum and the time t2 required from the state of maximum ball deformation for the ball and driver to separate is not more than 660 μsec. This golf ball makes it possible for golfers who have a high head speed and ordinary golfers who do not to compete without relying excessively on superiority in terms of distance.

Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. Polyurethane primer coatings and polyurethane top-coatings are applied to the thermoplastic polyurethane cover. Different coating methods can be used. Isocyanate-rich and polyol-rich polyurethane coatings can be applied. In one embodiment, the golf ball can be treated with a multi-functional isocyanate prior to applying the coatings. The polyurethane cover composition and surface coatings can further include catalysts, ultraviolet (UV)—light stabilizers, and other additives. Heat is used to cure the coatings. The coating methods have many benefits and the finished balls have good physical properties.