Methods for making multi-piece golf balls having an outer cover, intermediate, or other layer comprising a heterogeneous composition are provided. The heterogeneous composition comprises a mixture of Compounds A and B. For example, the compounds can be different polyurethanes, ethylene acid copolymer ionomers, polyesters, polyamides, or any other suitable materials for making golf ball layers. Compounds having different hardness levels can be used. For example, the composition can comprise a mixture of hard and soft materials. The invention also encompasses golf balls made from such methods. The golf balls have good resiliency and impact durability along with other optimum playing performance properties.

A golf ball a core, one or more intermediate layers, and one or more cover layers. The core may comprise an inner portion and an outer portion. One or more layers of the golf ball may be formed by the application of ultrasonic welding on two half shells to form. One or more of the layers may be formed by a number of different chemical compositions, and may have varying thicknesses, hardnesses, coefficients of restitution, and PGA compression. The golf ball itself may have varying coefficient of restitution and PGA compression, depending on the layers.

A golf ball comprising at least one layer consisting of a non-isocyanate-containing polyurethane composition comprising the reaction product of: at least one amine or polyamine, having an average functionality of 2.0 or greater, and at least one cyclo-carbonate. The amine may be selected for example from the group consisting of: ethylenediamine, hexamethylenediamine, or tris(2-aimnoethyl)amine, or blends thereof; and the polyamine may be selected for example from the group consisting of polyoxypropylene diamines, polyoxypropylene triamines, and combinations thereof. The cyclo-carbonate may comprise for example bis(cyclo-carbonate). Other possible reaction products include: (i) the at least one amine or polyamine and at least one epoxy-cyclo-carbonate oligomer, wherein the non-isocyanate-containing polyurethane composition can be modified with at least one of acrylic or siloxane; or (ii) the at least one amine or polyamine and at least one cyclo-carbonated soybean oil; or (iii) at least one lignin-based polyamine and at least one cyclo-carbonated soybean oil.

Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

A golf ball comprising a core comprising an inner core center and an outer core layer disposed over the inner core center. The inner core center has a deflection of greater than 0.210 inch under a load of 100 kilograms, and the entire the core has a deflection ranging from 0.130 inch to 0.105 inch under a load of 100 kilograms. A mantle layer is disposed over the core and a cover is disposed over the mantle.

A cured elastomer golf ball component is made by heating an elastomer compound containing an ethylenically unsaturated elastomer, an ethylenically unsaturated monomer, and first and second free radical initiators to a first crosslinking temperature T.sub.1 in a compression mold and partially crosslinking the elastomer, then heating to a second crosslinking temperature T.sub.2 and curing the elastomer component of the golf ball. Either: (i) the first initiator has a half-life of about 0.2-5 minutes at T.sub.1, the second initiator has a half-life of about 0.2-5 minutes at T.sub.2, and T.sub.2 is higher T.sub.1 by at least about 30° C.; or (ii) the second initiator's one-minute half-life temperature is at least about 30° C. higher than the first initiator's one-minute half-life temperature, T.sub.1 is within about 20° C. of the first initiator's one-minute half-life temperature, and T.sub.2 is within about 20° C. of the second initiator's one-minute half-life temperature.

A golf ball is provided that has a spherical core exhibiting a stiffness from 400 MPa to 200 GPa. The stiffness of the core may be controlled by adjusting the materials of construction and the ratio of the materials. This results in a golf ball that is legal for play and capable of drive distances essentially equivalent to those of currently-available high performance golf balls, but also provides a golf ball that has less hook and slice during play.

A golf ball a core, one or more intermediate layers, and one or more cover layers. The core may comprise an inner portion and an outer portion. One or more layers of the golf ball may be formed by the application of ultrasonic welding on two half shells to form. One or more of the layers may be formed by a number of different chemical compositions, and may have varying thicknesses, hardnesses, coefficients of restitution, and PGA compression. The golf ball itself may have varying coefficient of restitution and PGA compression, depending on the layers.

Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and epoxy compound. Mixtures of multi-functional amines and imines, and multi-functional isocyanates, and epoxy curing agents; and solvent, can be applied to the outer cover. The resulting coating may contain polyurethanes, polyureas, and hybrids, copolymers, and blends thereof. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.

A golf ball comprising layers that have from 0.05% to 70% by weight of a radio-opaque filler, and wherein the concentration of the radio-opaque filler is measurably different in each layer is disclosed herein. The radio-opaque filler is preferably a compound based on barium, bismuth, tungsten, iodine, or reduced iron.