Golf ball incorporating polyurethane mixture having wt. % NCO content of 4-20 and including a prepolymer polyol portion comprised of trans--Farnesene diol(s) in an amount of about 3-70 wt. % of total weight of prepolymer. Trans--Farnesene diol may be 15 carbon, long chain, branched, unsaturated 3,4-vinyl-containing bio-hydrocarbon having the formula: ##STR00001## Prepolymer can include a 1:99 to 99:1 blend (wt. % ratio) of Trans--Farnesene diol(s) and polybutadiene-based polyol(s) in an amount of about 35-85 wt. %, along with about 15 wt. %-65 wt. % of diisocyanate(s). Curative may be combined with prepolymer in amount of about 3-25 wt. % of total weight of curative and prepolymer combined, and may be mixture of aromatic diamine(s) and white dispersion in a wt. % ratio of about 90:10 to 50:50, plus catalyst. Hardness of polyurethane mixture can be from 75. Shore A to 75 Shore D or a material hardness can be from about 40 Shore D to about 65 Shore D.

The invention provides a golf ball having a core and a cover of one or more layer encasing the core, wherein the core has a center core and a foamed outer layer that directly, or indirectly through another layer, envelops the center core. The foamed outer layer is made of a rubber composition that includes a base rubber, a co-crosslinking agent and an organic peroxide. The foamed outer layer has an inside portion facing the ball center and an outside portion facing the outside of the ball that are unfoamed regions, and contains a foamed region in an intermediate portion therebetween. A method of manufacturing such a golf ball is also provided.

Golf ball incorporating polyurethane mixture having wt. % NCO content of 4-20 and including a prepolymer polyol portion comprised of trans--Farnesene diol(s) in an amount of about 3-70 wt. % of total weight of prepolymer. Trans--Farnesene diol may be 15 carbon, long chain, branched, unsaturated 3,4-vinyl-containing bio-hydrocarbon having the formula:

##STR00001##

Prepolymer can include a 1:99 to 99:1 blend (wt. % ratio) of Trans--Farnesene diol(s) and polybutadiene-based polyol(s) in an amount of about 35-85 wt. %, along with about 15 wt. %-65 wt. % of diisocyanate(s). Curative may be combined with prepolymer in amount of about 3-25 wt. % of total weight of curative and prepolymer combined, and may be mixture of aromatic diamine(s) and white dispersion in a wt. % ratio of about 90:10 to 50:50, plus catalyst. Hardness of polyurethane mixture can be from 75 Shore A to 75 Shore D or a material hardness can be from about 40 Shore D to about 65 Shore D.

A golf ball comprising a core composed of a fully neutralized polymer material is disclosed herein. The golf ball also preferably has multiple mantle layers and a cover.

Golf ball having CoR of at least 0.810, specific gravity SG.sub.B of less than 1.00 g/cc, and initial velocity of at least 250 ft/s and comprising a first layer L.sub.1, a second layer L.sub.2 surrounding L.sub.1, and a third layer L.sub.3 surrounding L.sub.2. L.sub.1 is formed from at least one highly neutralized polymer and has first specific gravity SG.sub.1; L.sub.2 is formed from at least one partially neutralized polymer and has second specific gravity SG.sub.2; and L.sub.3 is formed from at least one of a thermoset or thermoplastic composition and has third specific gravity SG.sub.3. At least two of SG.sub.1, SG.sub.2, and SG.sub.3 is less than 1.13 g/cc. SG.sub.1 may be less than 1.13 g/cc, or less than 1.0 g/cc. The thermoset or thermoplastic composition may comprise polyurethane(s), polyurea(s), polyurethane(s)/polyurea(s) hybrids, and/or ionomers such as at least partially neutralized polymers and/or HNPs.

Golf ball having CoR of at least 0.700 and Atti compression of at least about 50 and comprising layer comprising a mixture of ionomer composition and a plurality of particulates, at least some being surface-treated with alkoxylated siloxanes and/or polyether-modified siloxanes, and selected from titanium dioxide particles, barium sulfate particles, zinc sulfide particles, and/or zinc oxide particulates. At least some particulates may be contacted with compound having the formula:

##STR00001##

Compound (I) may be included in amount of 0.01 to 2% by weight based on total weight of portion of plurality being contacted. The plurality may be included in mixture in amount such that the layer has specific gravity of from 0.5 to about 5.0, tensile strength of from about 300 psi to about 50,000 psi, and elongation at break of from about 20% to about 1000%, each being greater than that of the ionomer composition portion of the mixture.

The golf ball includes a core having an inner layer core and an outer layer core, a single-layered intermediate layer and cover, wherein the inner layer core is formed of a rubber composition, the intermediate layer and the cover are formed of a resin composition, and a relationship between an initial velocity of the inner layer core, an initial velocity of the entire core, an initial velocity of an intermediate layer-encased sphere, and an initial velocity of a ball satisfies the following conditions:

(initial velocity of ball)<(initial velocity of intermediate layer-encased sphere)

(initial velocity of intermediate layer-encased sphere)?(initial velocity of entire core)?0.70 (m/s)

(initial velocity of entire core)?(initial velocity of inner layer core)?0.20 (m/s) and a specific gravity of the intermediate layer and a deflection of the golf ball when compressed under a predetermined load are set within specific ranges.

Golf ball having CoR of at least 0.700 and Atti compression of at least about 50 and comprising layer consisting of mixture of thermoset or thermoplastic composition and plurality of particulates, at least a portion surface-treated with alkoxylated siloxanes and/or polyether-modified siloxanes, and may be selected from titanium dioxide particles, barium sulfate particles, zinc sulfide particles, and/or zinc oxide particulates. At least some particulates are contacted with compound having the formula: ##STR00001## Compound (I) may be included in amount of 0.01 to 2% by weight based on total weight of portion of plurality being contacted. The plurality may be included in mixture in amount such that layer has specific gravity of from 0.5 to about 10.0, tensile strength of from about 300 psi to about 50,000 psi, and elongation at break of from about 20% to about 1000%, each being greater than that of the thermoset or thermoplastic composition portion of the mixture.

Golf ball having CoR of at least 0.700 and compression of at least 50 and comprising a layer of a mixture of thermoset or thermoplastic composition and a plurality of conductive nanoshelled structures such as conductive hollow nanoshells and/or nanorice particles. Conductive nanoshelled structures may be included in amount of from about 2 wt % to greater than 50 wt. % of total weight of mixture. Diameter of each conductive nano shelled structure at widest cross-section may be up to 1000 nm. Each conductive hollow nanoshell may have shell thickness to longitudinal diameter ratio of from about 1:3 to about 1:100. Each nanorice particle may have longitudinal diameter of up to 1000 nm. Shell thickness can be from 1 nm to 100 nm and may be controlled. A layer consisting of mixture may have specific gravity that differs from specific gravity of a layer consisting of the thermoset or thermoplastic composition portion of mixture.

Buoyant dimpled golf ball having CoR ?0.810, specific gravity <1.00 g/cc, initial velocity ?250 ft/s, first aerodynamic coefficient magnitude between about 0.25 and about 0.30 and first aerodynamic force angle between about 29 degrees and 34 degrees at Reynolds Number of 230000 and spin ratio of 0.085; and second aerodynamic coefficient magnitude between about 0.26 and about 0.31 and second aerodynamic force angle between about 31 degrees and 36 degrees at Reynolds Number of 180000 and spin ratio of 0.101. Golf ball may additionally have third aerodynamic coefficient magnitude between about 0.27 and about 0.32 and third aerodynamic force angle between about 34 degrees and 39 degrees at Reynolds Number of 133000 and spin ratio of 0.133; and fourth aerodynamic coefficient magnitude between about 0.33 and about 0.38 and fourth aerodynamic force angle between about 38 degrees and 43 degrees at Reynolds Number of 89000 and spin ratio of 0.183.