Multi-layer golf balls comprising a single- or dual-layer core, an intermediate layer, and an outer cover layer are disclosed. The intermediate layer is formed from a thermoplastic elastomer composition and has a surface hardness which is greater than the center hardness of the core and less than the outer surface hardness of the core. The outer surface hardness of the outer cover layer is greater than the outer surface hardness of the core.

Golf balls having a single or dual-layered solid core are provided. In one embodiment, the golf ball has dimensions and properties that do not conform to the rules of the United States Golf Association (USGA). For example, the ball weight; ball size; ball spherical symmetry; ball initial velocity; and/or ball overall distance may fall outside of the USGA standards. The dual-layered core can have an inner core comprising a thermoplastic composition and surrounding outer core comprising a thermoset composition. In another embodiment, the dual-layered core has an inner core comprising a thermoplastic composition and outer core comprising a thermoset composition. The thermoplastic composition preferably comprises an ethylene acid copolymer ionomer and plasticizer. The thermoset composition preferably comprises polybutadiene rubber. The ball further includes a cover of at least one layer.

Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and polydimethylsiloxane compound. Functionalized polydimethylsiloxane compounds also can be used to treat thermoplastic polyurethane golf ball covers. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls with thermoplastic polyurethane covers have good physical properties.

Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

A golf ball is provided that achieves a satisfactory distance on full shots with an iron, is superior in the short game, and has a good feel at impact and a good durability. The golf ball has a core formed of a rubber composition as one or more layer, an envelope layer formed of a resin material as one or more layer, an intermediate layer formed of a resin material as one layer, and a cover formed of a resin material as one layer having a thickness of not more than 1.0 mm. The layers of the ball have Shore C hardnesses at the respective surfaces thereof which together satisfy certain specific conditions, the core and the ball have respective deflections which satisfy certain conditions and the core has a specific internal hardness profile.

Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

A golf ball a core, one or more intermediate layers, and one or more cover layers. The core may comprise an inner portion and an outer portion. One or more layers of the golf ball may be formed by the application of ultrasonic welding on two half shells to form. One or more of the layers may be formed by a number of different chemical compositions, and may have varying thicknesses, hardnesses, coefficients of restitution, and PGA compression. The golf ball itself may have varying coefficient of restitution and PGA compression, depending on the layers.

Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

Golf ball incorporating core consisting of: a solid inner core layer consisting of a peroxide cured polybutadiene rubber composition and having a diameter of 1.25 inches or less and a center Shore C hardness (H.sub.center) of 50 or less; and an outer core layer consisting of a thermoplastic composition Tc as defined herein and having a thickness of 0.400 inches or greater and an outer surface Shore C hardness (H.sub.outer surface) of 70 or greater, wherein H.sub.outer surface>H.sub.center, and H.sub.outer surface−H.sub.center≧40. The peroxide cured polybutadiene rubber composition may comprise a reaction product of polybutadiene and a sufficient amount of peroxide to form the solid inner layer having the center Shore C hardness (H.sub.center) of 50 or less. In one embodiment, 100 phr polybutadiene and from about 0.05 phr to about 3.0 phr of peroxide are mixed with at least one of 5 phr or less of a metal oxide; 5 phr or less of a metal coagent; or 5 phr or less of a metal carbonate. Alternatively, the solid inner core layer has a diameter of 1.10 inches or less or less than 1.0 inches.

In a golf ball having a core, envelope layer, intermediate layer and cover, the (core diameter)/(ball diameter) value falls within a particular range, the core has a specific hardness profile, the intermediate layer is formed primarily of an ionomer resin material including a high-acid ionomer resin, and the Shore C hardness relationships among the core center and surface hardnesses and the surface hardnesses of the envelope layer-encased sphere, intermediate layer-encased sphere and ball satisfy the following conditions: (1) core surface hardness<surface hardness of envelope layer-encased sphere<surface hardness of intermediate layer-encased sphere>ball surface hardness, (2) (surface hardness of envelope layer-encased sphere)−(core center hardness)≥28.

Also, the intermediate layer and cover have respective thicknesses which satisfy the condition: (3) cover thickness<intermediate layer thickness.

This ball enables mid-level and skilled amateur golfers to achieve superior distances on driver shots and on iron shots, and moreover has a soil yet good feel at impact.