Golf balls having cores with increased hardness gradients are provided. The cores have an increased positive hardness gradient (or a hard-to-soft hardness) where the outer surface of the core is harder than the center. The increased positive hardness gradient can be achieved by introducing a water-releasing agent into the core rubber formulation during the curing process. The resulting golf balls have reduced spin and sufficient impact durability.

In a golf ball having a core, envelope layer, intermediate layer and cover, the core has a specific hardness profile, the resin materials making up either or both of the envelope layer and the intermediate layer has a material hardness on the Shore D hardness scale of at least 65 and has a specific gravity of at least 1.05, and the Shore C hardness relationships among the core center, surface of the envelope-encased layer and surface of the intermediate layer-encased sphere satisfy the following conditions:
surface hardness of envelope layer-encased sphere<surface hardness of intermediate layer-encased sphere,(1)
surface hardness of intermediate layer-encased sphere?center hardness of core?40.(2)
This ball achieves a good distance on shots with utility and iron clubs, is receptive to spin in the short game, and has a soft feel at impact on all shots, making it useful to amateur golfers.

In a golf ball having a core, an intermediate layer and a cover, the ball and the sphere obtained by encasing the core with the intermediate layer have respective surface hardnesses such that (surface hardness of ball)<(surface hardness of intermediate layer-encased sphere); the ball has an initial velocity of ?75.0 m/s; and the core has a hardness profile in which the center hardness, the hardness at a midpoint between the core center and core surface, and the hardnesses at specific positions inward from the midpoint and at specific positions outward from the midpoint are optimized. Given the possibility that the rules limiting the distance traveled by a golf ball on shots by long hitters will change, this ball reduces the drop-off in distance on driver shots and iron shots taken by average hitters while increasing the drop-off in distance on driver shots taken by long hitters.

A golf ball with improved durability is disclosed herein. The golf ball has a core comprising a polybutadiene material and methyl methacrylate, butadiene, styrene (MBS) with a weight percentage of MBS ranging from 0.5 to 5 weight percent of the core.

In a multi-piece solid golf ball having a core, an intermediate layer encasing the core and a cover which encases the intermediate layer and has numerous dimples on an outside surface thereof, the intermediate layer is formed of a resin material comprising an ionomer resin as a base resin and an inorganic granular filler, the cover is formed of a urethane resin material, the core has a diameter of at least 38.0 mm, the core has specific deflection, the sphere obtained by encasing the core with the intermediate layer (intermediate layer-encased sphere) has a surface hardness on the Shore D hardness scale of at least 69, the ball has a surface hardness on the Shore D hardness scale of 62 or less, and the (intermediate layer thickness)/(core diameter) value is from 0.025 to 0.043, the (cover thickness)/(core diameter) value is from 0.014 to 0.027.

A golf ball comprising: (a) a core; (b) at least one mantle layer adjacent to the core; (c) an inner cover layer adjacent to the mantle layer; and (d) an outer cover layer adjacent to the inner cover layer, wherein the inner cover layer has a material Shore D hardness that is at least 3 less than the material Shore D hardness of the outer cover layer, and the inner cover layer has a thickness of less than 0.050 in.

The golf ball includes a core, an intermediate layer, and a cover, in which the core is formed of a rubber composition into a single layer or a plurality of layers, the intermediate layer and the cover are both formed of a single-layer resin composition, and a relationship between an initial velocity of the core, an initial velocity of a sphere (intermediate layer-encased sphere) in which the core is encased with the intermediate layer, and an initial velocity of a sphere (ball) in which the intermediate layer-encased sphere is encased with the cover satisfies the following two conditions:

(initial velocity of ball)<(initial velocity of intermediate layer-encased sphere)

0.60?(initial velocity of intermediate layer-encased sphere)?(initial velocity of core)?1.00 (m/s). and the specific deflection is 3.00 mm or less, and a specific gravity of the intermediate layer is 1.05 or more.

A method for forming a golf ball with a graphene core disclosed herein. The method includes mixing a graphene masterbatch material with a polybutadiene material to form a core mixture, wherein the graphene masterbatch material comprises graphene in an amount from 0.1 to 80.0 weight percent of the graphene masterbatch material mixed with a carrier polymer in an amount from 99.9 to 20 weight percent of the graphene masterbatch material.

A golf ball with a core comprising polybutadiene and graphene, and a soft cover is disclosed herein. The golf ball has a dual core with an outer core comprising polybutadiene and graphene. The soft cover is preferably composed of a highly neutralized polymer, a first ionomer, a second ionomer, and a paraloid impact modifier.

Multi-layered golf balls having a core, intermediate layer, and cover are provided. The ball includes a non-foamed inner core (center) made of a thermoplastic or thermoset composition such as polybutadiene rubber. An intermediate layer comprising a foamed composition, such as polyurethane foam, is disposed about the inner core. The foamed intermediate layer may have a specific gravity gradient within the layer, wherein the outer surface specific gravity is greater than the midpoint specific gravity. Ball constructions having two intermediate layers, wherein at least one layer is a foamed layer can be made. A cover having at least one layer is disposed about the intermediate layer.