An object of the present invention is to provide a golf ball having excellent durability. The present invention provides a golf ball comprising a core and at least one cover layer covering the core, wherein the core is formed from a core rubber composition containing (a) a base rubber, (b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator, and (d) a hindered phenol compound, and (b) the co-crosslinking agent and (d) the hindered phenol compound are blended in the core rubber composition such that the following expression (1) is satisfied:
0.04≤HF/B≤0.35  (1) in the formula (1), HF=a number of OH functional group in one molecule of (d) the hindered phenol compound×an amount of (d) the hindered phenol compound (mole) with respect to 100 parts by mass of (a) the base rubber, and B=an amount of (b) the co-crosslinking agent (mole) with respect to 100 parts by mass of (a) the base rubber.

In a multi-piece solid golf ball having a core formed of a rubber composition, an intermediate layer formed of a polyurethane material and a cover, the ball satisfies the following condition: surface hardness of ball≤surface hardness of intermediate layer-encased sphere. When the ball is struck with a driver at a head speed of 40 m/s, the sum of the time t1 required from contact initiation between the driver and ball for deformation of the ball to reach a maximum value and the time t2 required from the state of maximum ball deformation for the ball and driver clubface to separate is at least 685 microseconds, and the ratio t2/t1 is at least 1.35, and the core has a specific hardness profile. This ball has an excellent flight performance when hit by low or moderate head-speed golfers, is receptive to spin on approach shots and has a good, soft feel at impact.

Golf balls having a single or dual-layered solid core are provided. In one embodiment, the golf ball has dimensions and properties that do not conform to the rules of the United States Golf Association (USGA). For example, the ball weight; ball size; ball spherical symmetry; ball initial velocity; and/or ball overall distance may fall outside of the USGA standards. The dual-layered core can have an inner core comprising a thermoplastic composition and surrounding outer core comprising a thermoset composition. In another embodiment, the dual-layered core has an inner core comprising a thermoplastic composition and outer core comprising a thermoset composition. The thermoplastic composition preferably comprises an ethylene acid copolymer ionomer and plasticizer. The thermoset composition preferably comprises polybutadiene rubber. The ball further includes a cover of at least one layer.

In a golf ball having a core composed of one or more layer, the outermost layer of the core is formed of a rubber composition containing a base rubber and an α,β-unsaturated metal carboxylate, an envelope layer directly encasing the core is formed of a resin composition containing a thermoplastic resin having a structure that includes α,β-ethylenically unsaturated carboxylic acid copolymerization units, and a surface of the core outermost layer and the envelope layer adjoin each other through an intervening oxazoline group-containing substance. The golf ball has improved adhesion between the rubber-based core and the cover layer that directly encases the core and is formed of an ionomer resin or other α,β-ethylenically unsaturated carboxylic acid copolymer-containing resin material.

In a golf ball having a core and a cover of one or more layer, at least one layer of the cover is formed of a resin composition which includes in a specific weight ratio: (I) a thermoplastic polyurethane resin that uses polytetramethylene glycol having a number-average molecular weight of from 1,900 to 2,100 as the polyol component, (II) a thermoplastic polyurethane resin that uses polytetramethylene glycol having a number-average molecular weight of from 900 to 1,100 as the polyol component, and (III) an aromatic vinyl elastomer. The cover layer formed of this resin composition has a Martens hardness and an elastic work recovery which together satisfy a specific formula. The golf ball has an excellent controllability on approach shots without losing distance on driver shots. In addition, the scuff resistance and moldability are good.

In a golf ball having a core, an envelope layer, an intermediate layer and a cover, the difference between the center hardness and the surface hardness of the core is set in a specific range, the intermediate layer is formed of a resin material that includes a high-acid ionomer, the Shore C hardness relationships among the core center and the surfaces of the envelope-encased layer and the intermediate layer-encased sphere satisfy specific conditions; and the ball has a deflection when compressed under a given load which is at least 2.7 mm. This ball achieves a good distance on shots with a driver, utility club or iron, is receptive to spin in the short game, and has a soft feel at impact on all shots, making it useful to amateur golfers.

Multi-layered golf balls having an inner core with a relatively large diameter are provided. In one embodiment, the golf ball comprises an inner core, outer core, and cover. The inner core comprises a thermoset or thermoplastic composition. For example, a blend of polybutadiene rubbers can be used to form the inner core. The outer core layer is relatively thin and comprises a thermoset or thermoplastic composition. The dimensions and compressions of the core layers have specific relationships referred to as the Core Profile. The golf ball further comprises a cover having at least one layer. Ethylene acid copolymer ionomers and polyurethanes, particularly thermoplastic polyurethane, can be used to form the cover.

Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and polydimethylsiloxane compound. Functionalized polydimethylsiloxane compounds also can be used to treat thermoplastic polyurethane golf ball covers. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls with thermoplastic polyurethane covers have good physical properties.

A method for forming a golf ball with a graphene core disclosed herein. The method includes mixing a graphene masterbatch material with a polybutadiene material to form a core mixture, wherein the graphene masterbatch material comprises graphene in an amount from 0.1 to 80.0 weight percent of the graphene masterbatch material mixed with a carrier polymer in an amount from 99.9 to 20 weight percent of the graphene masterbatch material.

An object of the present disclosure is to provide a golf ball having an increased spin rate when being hit with an 8-iron while suppressing rise in a spin rate when being hit with a driver. The present disclosure provides a golf ball comprising a spherical core having an inner core and an outer core, and a cover positioned outside the spherical core, wherein A×a is 12,200 or less and B×b is 20,400 or more, where “a” represents an average hardness (Shore C) of a hardness (H2.5) at a point of 2.5 mm from a center of the spherical core and a hardness (H5) at a point of 5 mm from the center of the spherical core, “b” represents an average hardness (Shore C) of a hardness (H7.5) at a point of 7.5 mm from the center of the spherical core and a hardness (H9) at a point of 9 mm from the center of the spherical core, “A” represents an impulse difference (kN.Math..Math.s) between a back spin impulse and a top spin impulse measured using a contact force tester under a condition corresponding to a condition when the golf ball is hit with a driver, and “B” represents an impulse difference (kN.Math..Math.s) between a back spin impulse and a top spin impulse measured using a contact force tester under a condition corresponding to a condition when the golf ball is hit with an 8-iron.