Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and epoxy compound. Mixtures of multi-functional amines and imines, and multi-functional isocyanates, and epoxy curing agents; and solvent, can be applied to the outer cover. The resulting coating may contain polyurethanes, polyureas, and hybrids, copolymers, and blends thereof. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.

A resin composition for golf balls is made of (A) polyurethane or polyurea and (B) a styrene resin material, component (B) being included in an amount of 0.5 to 50 parts by weight per 100 parts by weight of component (A). In a golf ball having a core and a cover of one or more layer encasing the core, at least one cover layer is formed of this resin composition. The resin composition is especially useful as a golf ball cover material because the ball does not fly too far and is easier to control on approach shots, yet does not sacrifice distance on shots with a driver.

Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and epoxy compound. Mixtures of multi-functional amines and imines, and multi-functional isocyanates, and epoxy curing agents; and solvent, can be applied to the outer cover. The resulting coating may contain polyurethanes, polyureas, and hybrids, copolymers, and blends thereof. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.

In a golf ball having a core of at least one layer and a cover of one or more layer encasing the core, at least one layer of the cover is formed of a resin composition that includes (I) a polyurethane or a polyurea and (II) an aromatic vinyl elastomer which together satisfy certain specific conditions. The golf ball has an excellent controllability on approach shots and is also able to maintain a good scuff resistance.

An object of the present invention is to provide a golf ball comprising a paint film having improved abrasion resistance without substantially lowering the spin performance. The present invention provides a golf ball comprising a golf ball body and a paint film formed on a surface of the golf ball body, wherein the paint film contains a resin fine particle in an amount of less than 10 parts by mass with respect to 100 parts by mass of a base resin thereof, the base resin of the paint film is a polyurethane, and the resin fine particle contains a polyrotaxane component having a cyclodextrin, a linear molecule penetrating the cyclic structure of the cyclodextrin in a skewering manner, and a blocking group located at both terminals of the linear molecule to prevent disassociation of the cyclodextrin, wherein at least a part of hydroxyl groups of the cyclodextrin is modified with a caprolactone chain via a OC.sub.3H.sub.6O group.

In a golf ball having a two-layer core consisting of an inner core layer and an outer core layer and a cover of one or more layer, the inner core layer and outer core layer are each formed of a rubber composition made up primarily of a base rubber, the inner core layer has a diameter of not more than 30 mm; and the core has specific hardness ratios (JIS-C hardness/Shore D hardness) at specific points on the cross-section thereof. This golf ball has a reduced spin rate on full shots with a driver and middle irons, thus imparting to an excellent flight performance, and moreover has a good controllability in the short game on approach shots, making it ideal as a golf ball for professional golfers and mid- and high-level amateur golfers.

A golf ball 2 includes a core 4 and a cover 6 positioned outside the core 4. The cover 6 is formed in a mold having support pins by injection molding. A ratio (V/S) of a volume V (mm.sup.3) of the cover 6 to an amount of compressive deformation S (mm) of the core 4 is not less than 1000 and not greater than 1900. The cover 6 has a shore D hardness of not greater than 62. The golf ball 2 has a plurality of dimples 8 on a surface thereof. A total volume W of these dimples is not less than 490 mm.sup.3 and not greater than 620 mm.sup.3. A ratio (/P) of a latitude (degree) of each support pin to a total cross-sectional area P (mm.sup.2) of the support pins is not less than 0.35 and not greater than 0.60.

A resin composition for golf balls is made of (A) polyurethane or polyurea and (B) an acrylic resin or a methacrylic resin, component (B) being included in an amount of from 0.5 to 50 parts by weight per 100 parts by weight of component (A). In a golf ball having a core and a cover of one or more layer encasing the core, at least one cover layer is formed of this resin composition. The resin composition is especially useful as a golf ball cover material because it makes it possible to achieve a higher ball initial velocity on shots with a driver and a lower ball initial velocity on approach shots.

In a golf ball having a core and a cover of at least one layer, the outermost layer of the cover is formed of a resin composition that includes (A) 100 parts by weight of a thermoplastic resin, and (B) 1 to 30 parts by weight of a compound having a fluorene skeleton, or a derivative thereof, and the resin composition has a melt flow rate of at least 3.0 g/10 min. This resin composition for golf balls has an improved injection-moldability and thus enables the ball to achieve both a reduced spin rate and a good durability (scuff resistance).

In a golf ball having a core of at least one layer and a cover encasing the core, the cover is formed of a resin composition composed primarily of a polyurethane or a polyurea. Letting HMa (N/mm.sup.2) be the Martens hardness of the cover measured at a position 0.3 mm toward the center of the ball from the cover surface and Ita (%) be the elastic recovery of the cover, HMa and Ita satisfy the following conditions: (1) Ita1.16HMa+79, (2) 10.0HMa38.0, and (3) 40Ita80. The ball has an excellent spin performance on approach shots and an excellent scuff resistance.