Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises a center, an intermediate core layer, and an outer core layer. At least one layer of the multi-layer core is a high specific gravity layer.

An object of the present invention is to provide a golf ball having a decreased spin rate on driver shots. The present invention provides a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) a base rubber, (b) a compound represented by the formula (1) as a co-crosslinking agent, and (c) a crosslinking initiator,

(R.sup.1COO)M(OCOR.sup.2)m(1) in the formula (1), M represents a metal atom, m represents 1 or 2, R.sup.1 and R.sup.2 are different from each other, represent an alkenyl group having 2 to 30 carbon atoms or an alkynyl group having 2 to 30 carbon atoms and have a carbon-carbon double bond or a carbon-carbon triple bond at an -position carbon atom bonding to the carbonyl group, and when m is 2, two of R.sup.2 may be identical to or different from each other.

An object of the present invention is to provide a golf ball having a decreased spin rate on driver shots. The present invention provides a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) a base rubber, (b) two or more ,-unsaturated carboxylic acids having 3 to 14 carbon atoms and having no substituent group at a carbon atom bonding to the carboxy group, and/or a metal salt thereof, and (c) a crosslinking initiator.

In a multi-piece solid golf ball having a core, a cover and an intermediate layer therebetween, the core, an intermediate layer-encased sphere and the ball have surface hardnesses which satisfy a specific relationship, and the intermediate layer and the cover have thicknesses which satisfy a specific relationship. Also, the core has a hardness profile in which the hardnesses at the core surface, core center, a position 5 mm from the core center, and a position midway between the surface and center of the core satisfy specific relationships. This golf ball, when used by mid- and high-level amateurs, enables the golfer to maintain an adequate distance on shots with a driver and achieve a good distance on iron shots, has a good spin performance on approach shots and has a good feel on impact. In addition, the ball has an excellent scuff resistance when struck with a grooved wedge.

A golf ball for amateur golfers exhibits excellent flight characteristics when hit by the average golfer and also has a good feel at impact that is both soft and solid. The golf ball includes a core, an intermediate layer and a cover, and has coefficient of restitution and compressive deformation relationships that satisfy specific conditions.

In a golf ball having a core, an intermediate layer and a cover, the intermediate layer-encased sphere has a higher surface hardness than the ball. The core hardness profile in the ball is designed such that the core surface has a Shore C hardness value which is at least 27 higher than the Shore C hardness value at the core center, and the surface areas A to F calculated from hardness differences between positions located at specific distances in the core and differences between the specific distances satisfy a specific formula. This golf ball has an excellent flight performance when struck by skilled amateur golfers and professionals, and also has a good controllability on shots with an iron.

In a golf ball having a two-layer core which includes an inner core layer and an outer core layer and having a cover of one or more layer, the outer core layer is formed of an elastomer composition that includes specific amounts of (A) polybutadiene having a 1,2-bond content of 50 to 95%, (B) a photocurable monomer, oligomer or polymer, and (C) a photopolymerizable initiator. The outer core layer has a thickness of from 1.0 to 4.0 mm, and the two-layer core has a surface hardness on the JIS-C scale of from 75 to 95. The ball is provided with a hardness gradient at the core interior, which lowers the spin rate of the ball, has an improved durability to cracking, and production costs for the outer core layer are kept relatively low.

In a multi-piece solid golf ball having a core, an envelope layer, an intermediate layer and a cover, the core is formed primarily of a base rubber and has a diameter set in a specific range, the envelope layer, intermediate layer and cover are each formed of resin materials, and the envelope layer is formed into two layersan inner layer and an outer layer. The center and surface hardnesses of the core, the surface hardness of the inner envelope layer-encased sphere, the surface hardness of the outer envelope layer-encased sphere, the surface hardness of the intermediate layer-encased sphere and the surface hardness of the ball together satisfy a specific relationship. This ball achieves a satisfactory distance on full shots both with a driver and with irons, in addition to which it is superior in the short game and has a good feel at impact and an excellent scuff resistance.

In a multi-piece solid golf ball having a core formed of a rubber composition, an intermediate layer formed of a polyurethane material and a cover, the ball satisfies the following condition: surface hardness of ballsurface hardness of intermediate layer-encased sphere. When the ball is struck with a driver at a head speed of 40 m/s, the sum of the time t1 required from contact initiation between the driver and ball for deformation of the ball to reach a maximum value and the time t2 required from the state of maximum ball deformation for the ball and driver clubface to separate is at least 685 microseconds, and the ratio t2/t1 is at least 1.35, and the core has a specific hardness profile. This ball has an excellent flight performance when hit by low or moderate head-speed golfers, is receptive to spin on approach shots and has a good, soft feel at impact.