Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises a zero or positive hardness gradient center that is hard relative to an intermediate core layer.

Multi-piece golf balls containing a multi-layered core structure having layers with different hardness gradients and specific gravities are provided. The core structure includes a small, heavy inner core (center) having a relatively high specific gravity with metal material preferably dispersed in a first thermoset composition. The intermediate core layer is preferably formed from a thermoplastic composition such as an ethylene acid copolymer ionomer resin; and the outer core layer is preferably formed from a second thermoset composition. The resulting ball has high resiliency and good spin control.

An object of the present invention is to provide a golf ball striking a good balance between flight distance on driver shots and spin rate on approach shots, and excellent in stain resistance and shot feeling. The present invention provides a golf ball comprising a paint film, wherein a base resin of the paint film contains a polyurethane obtained by a reaction between a polyisocyanate composition and a polyol composition containing a urethane polyol having a polyether diol with a number average molecular weight in a range from 800 to 3,000 as a constituent component, and the following requirements are satisfied:
Mp≦200×X−75
Mp≦100
Minm−Moum>40
Moum−Mc<5
Tinm≧Toum>Tc>Tp
(Tinm×Minm)/(Toum×Moum)>2.0
(Toum×Moum)/(Tc×Mc)<3.0
(Tc×Mc)/(Tp×Mp)>10.0
[where Mp, Minm, Moum, and Mc represent a 10% elastic modulus (kgf/cm.sup.2) of the paint film, inner intermediate layer, outer intermediate layer and cover, respectively; Tp, Tinm, Toum, and Tc represent a thicknesses (mm) of the paint film, inner intermediate layer, outer intermediate layer and cover, respectively; and X represents a molar ratio (NCO/OH) of a NCO group in the polyisocyanate composition to a OH group in the polyol composition.].

An object of the present invention is to provide a golf ball having excellent durability and good shot feeling. The present invention provides a golf ball comprising a core, wherein a difference (crosslinking density at surface of core−crosslinking density at center of core) between a crosslinking density at a surface of the core and a crosslinking density at a center of the core is more than 1.0×10.sup.2 mol/m.sup.3 and less than 9.0×10.sup.2 mol/m.sup.3, and a hardness difference (Hs−Ho) between Hs and Ho is 13.0 or more and 30.0 or less, and the core satisfies H50−Ho>Hs−H50, wherein Hs (Shore C hardness) is a hardness at the surface of the core, Ho (Shore C hardness) is a hardness at the center of the core, and H50 (Shore C hardness) is a hardness at a midpoint between the center of the core and the surface of the core.

In a golf ball having a core, envelope layer, intermediate layer and cover, the (core diameter)/(ball diameter) value falls within a particular range, the core has a specific hardness profile, the intermediate layer is formed primarily of an ionomer resin material including a high-acid ionomer resin, and the Shore C hardness relationships among the core center and surface hardnesses and the surface hardnesses of the envelope layer-encased sphere, intermediate layer-encased sphere and ball satisfy the following conditions: (1) core surface hardness<surface hardness of envelope layer-encased sphere<surface hardness of intermediate layer-encased sphere>ball surface hardness, (2) (surface hardness of envelope layer-encased sphere)−(core center hardness)≥28.

Also, the intermediate layer and cover have respective thicknesses which satisfy the condition: (3) cover thickness<intermediate layer thickness.

This ball enables mid-level and skilled amateur golfers to achieve superior distances on driver shots and on iron shots, and moreover has a soil yet good feel at impact.

A golf ball is provided that achieves a satisfactory distance on full shots with an iron, is superior in the short game, and has a good feel at impact and a good durability. The golf ball has a core formed of a rubber composition as one or more layer, an envelope layer formed of a resin material as one or more layer, an intermediate layer formed of a resin material as one layer, and a cover formed of a resin material as one layer having a thickness of not more than 1.0 mm. The layers of the ball have Shore C hardnesses at the respective surfaces thereof which together satisfy certain conditions, and the core and the ball have respective deflections which satisfy certain other conditions.

A golf ball is provided that achieves a satisfactory distance on full shots with a driver and an iron, is superior in the short game, and has a good feel at impact and a good durability. The golf ball has a core formed of a rubber composition as one or more layer, an inner envelope layer formed of a resin material as one or more layer, an outer envelope layer and intermediate layer which are each formed of a resin material as one layer, and a cover formed of a resin material as one layer having a thickness of not more than 1.0 mm. The inner envelope layer-encased sphere, outer envelope layer-encased sphere, intermediate layer-encased sphere and ball have Shore C hardnesses at the respective surfaces thereof which together satisfy certain conditions, and the ball has at least a given deflection under specific loading conditions.

The invention provides a golf ball having a core and a cover of one layer or a plurality of layers, wherein the core is formed of a material molded under heat from a rubber composition containing (A) a base rubber, (B) an organic peroxide, and (C) water and/or a metal monocarboxylate, and has a hysteresis loss of 50% or less when compressed at a load cell speed of 500 mm/min and under a constant load of 5,000 N.

Multi-piece golf balls having a solid core made of a foamed silicone composition and a cover are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core structures can be made. Preferably, a dual-core having has a silicone foam inner core (center) and surrounding silicone foam outer core layer is made. The core layers can have different hardness gradients. The silicone foam center and outer core layer have good thermal stability and durability and provide the ball with good resiliency.

Golf balls having a multi-layered core made of a foamed composition are provided. The core preferably has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition is used to form the foam center. The foam inner core preferably includes a fully-foamed center region and a partially or completely-collapsed foam outer region. The hardness of the fully-foamed region is different than the hardness of the collapsed foam region. Non-foamed thermoset or thermoplastic materials such as polybutadiene rubbers or ethylene acid copolymer ionomer may be used to form the outer core layer. The ball further includes a cover that may be multi-layered. The foam cores have good resiliency.